journal article·2021-04-30Open access

RETRACTED: Lanthanum-Zinc Binary Oxide Nanocomposite with Promising Heterogeneous Catalysis Performance for the Active Conversion of 4-Nitrophenol into 4-Aminophenol

Ikram Ahmad, Muhammad Jamal, Miara Iftikhar, Awais Ahmad, Shahid Hussain, Humaira Asghar, Muhammad Saeed, Ammar Yousaf, Rama Karri, Nada Al-kadhi, Mohamed Ouladsmane, Ayman Ghfar, Safia Khan

Coatings· Volume 11· Issue 5
This record is marked as retracted by the source. Review the publisher’s notice before using its findings.

Abstract

This work intended to enhance the unique and outstanding properties of lanthanum by synthesizing its nanocomposite. A lanthanum-based nanocomposite was prepared by a simple and cost-effective “co-precipitation” method. Lanthanum nitrate (La (NO3)3) and zinc nitrate (Zn (NO3)2) were used as precursors. The lanthanum/zinc oxide nano composite formed was then calcined at 450 °C for 4 h in order to obtain a fine powder with size in the nano range of 1–100 nm. Characterization of the prepared catalyst was done by ultraviolet/visible spectroscopy, Fourier transform infrared spectroscopy, and photoluminescence. Crystallinity and morphology were found by X-ray diffraction and scanning electron microscopy. The synthesized nanocomposite material was also tested for heterogeneous catalytic applications of 4-nitrophenol (4-NP) reduction into 4-aminophenol (4-AP). It was found to be successful in complete reduction of 4-NP with enhanced catalytic performance.
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Research context

OpenAlex topics: Nanomaterials for catalytic reactions · Copper-based nanomaterials and applications · Advanced Photocatalysis Techniques

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

Affiliations

Department of Chemistry, University of Sahiwal, Sahiwal 54000, Pakistan

Department of Chemistry, Government College University, Faisalabad 38000, Pakistan

Department of Chemistry, The University of Lahore, Lahore 54590, Pakistan

School of Materials Science and Engineering, Jiangsu University, Zhenjiang 212013, China

Centre for Advanced Materials, Qatar University, Doha 2713, Qatar

Petroleum and Chemical Engineering, Faculty of Engineering, Universiti Teknologi Brunei, Mukim Gadong 1410, Brunei

Department of Chemistry, College of Science, Princess Nourah Bint Abdulrahman University, Riyadh 11671, Saudi Arabia

Advanced Materials Research Chair, Chemistry Department College of Science, King Saud University, P.O. Box 2455, Riyadh 11451, Saudi Arabia

Department of Chemistry, Quaid-i-Azam University Islamabad, Islamabad 45320, Pakistan

References (75)

Show source-provided references
1. Protonation sites and fragmentations of para-aminophenol10.1016/j.ijms.2012.12.007 ↗
2. Effects of the analgesic acetaminophen (paracetamol) and its para-aminophenol metabolite on viability of mouse-cultured cortical10.1111/j.1742-7843.2011.00767.x ↗
3. Conversion of chicken feather waste to N-doped carbon nanotubes for the catalytic reduction of 4-nitrophenol10.1021/es5021839 ↗
4. Gold nanoparticles supported by amino groups on the surface of magnetite microspheres for the catalytic reduction of 4-nitrophenol10.1007/s10853-018-2868-1 ↗
5. Hierarchical synthesis of silver monoliths and their efficient catalytic activity for the reduction of 4-nitrophenol to 4-aminophenol10.1039/C5NJ03710G ↗
6. Au/graphene hydrogel: Synthesis, characterization and its use for catalytic reduction of 4-nitrophenol10.1039/c2jm16386a ↗
7. Serrà, A., Artal, R., Pozo, M., Garcia-Amorós, J., and Gómez, E. (2020). Simple environmentally-friendly reduction of 4-nitrophenol. Catalysts, 10.10.3390/catal10040458 ↗
8. One-pot synthesis of porous P-Au nanodendrites supported on reduced graphene oxide nanosheets toward catalytic reduction of 4-nitrophenol10.1039/C4TA05034G ↗
9. Highly active PtAu alloy nanoparticle catalysts for the reduction of 4-nitrophenol10.1039/C3NR04715F ↗
10. Controlled synthesis of rare earth nanostructures10.1039/b810586c ↗
11. Rare-earth-compound nanowires, nanotubes, and fullerene-like nanoparticles: Synthesis, characterization, and properties10.1002/chem.200304785 ↗
12. Synthesis of rare earth (Pr, Nd, Sm, Eu and Gd) hydroxide and oxide nanorods (nanobundles) by a widely applicable precipitation route10.1016/j.jallcom.2010.07.109 ↗
13. Synthesis of lanthanum oxide nanosheets by a green carbonation process10.1007/s11434-014-0233-6 ↗
14. Synthesis of La2O3/MWCNT nanocomposite as the sensing element for electrochemical determination of theophylline10.1039/D0AY01336F ↗
15. The role of lanthanum in a nickel oxide-based inverted perovskite solar cell for efficiency and stability improvement10.1002/cssc.201802231 ↗
16. Spray deposited lanthanum doped TiO2 compact layers as electron selective contact for perovskite solar cells10.1016/j.solmat.2017.04.027 ↗
17. Influence of lanthanum-doping on photocatalytic properties of BiFeO3 for phenol degradation10.1016/S1872-2067(16)62449-X ↗
18. The role of lanthanum in the enhancement of photocatalytic properties of TiO2 nanomaterials obtained by calcination of hydrogenotitanate nanotubes10.1016/j.apcatb.2015.08.037 ↗
19. Novel route to prepare lanthanum oxide nanoparticles for optoelectronic devices10.1142/S0217979220501349 ↗
20. Surti, S., Karp, J., Muehllehner, G., and Raby, P. (2002, January 10–16). Investigation of lanthanum scintillators for 3D PET. Proceedings of the 2002 IEEE Nuclear Science Symposium Conference Record, Norfolk, VA, USA.
21. NUV/blue LED excitable intense green emitting terbium doped lanthanum molybdate nanophosphors for white LED applications10.1007/s10854-017-7708-6 ↗
22. Enhancing quantum yield of CsPb (BrxCl1−x) 3 nanocrystals through lanthanum doping for efficient blue light-emitting diodes10.1016/j.nanoen.2020.105302 ↗
23. White light emission of dysprosium doped lanthanum calcium phosphate oxide and oxyfluoride glasses10.1016/j.optmat.2017.02.049 ↗
24. Nd3+-doped lanthanum lead boro-tellurite glass for lasing and amplification applications10.1016/j.optmat.2017.10.037 ↗
25. Development of lanthanum strontium cobalt ferrite perovskite electrodes of solid oxide fuel cells-A review10.1016/j.ijhydene.2019.01.212 ↗
26. Synthesis of lanthanum tungsten oxynitride perovskite thin films10.1002/aelm.201900214 ↗
27. Lanthanum oxide nanoparticles immobilized reduced graphene oxide polymer brush nanohybrid for environmental vitiation of organic dyes10.1016/j.arabjc.2017.11.008 ↗
28. Highly dispersive lanthanum oxide fabricated in confined space of SBA-15 for adsorptive desulfurization10.1016/j.cej.2019.123271 ↗
29. Fabrication of oxidized graphite supported La2O3/ZrO2 nanocomposite for the photoremediation of toxic fast green dye10.1016/j.molliq.2018.12.126 ↗
30. Photocatalytic Degradation of Methylene Blue by ZnO Nanoparticles10.1166/jnn.2017.12579 ↗
31. Integrated adsorption-solar photocatalytic membrane reactor for degradation of hazardous Congo red using Fe-doped ZnO and Fe-doped ZnO/rGO nanocomposites10.1007/s11356-018-2557-2 ↗
32. Efficiency enhancement of ZnO/Cu2O solar cells with well oriented and micrometer grain sized Cu2O films10.1063/1.5017002 ↗
33. Perovskite solar cells with ZnO electron-transporting materials10.1002/adma.201703737 ↗
34. In situ formation of graphene/metal oxide composites for high-energy microsupercapacitors10.1038/s41427-020-0230-y ↗
35. ZnO nanorods array based field-effect transistor biosensor for phosphate detection10.1016/j.jcis.2017.03.069 ↗
36. Light-emission enhancement in a flexible and size-controllable ZnO nanowire/organic light-emitting diode array by the piezotronic effect10.1021/acsphotonics.7b00386 ↗
37. Zinc oxide light-emit
38. Room-temperature gas sensing of ZnO-based gas sensor: A review10.1016/j.sna.2017.10.021 ↗
39. ZnO-based nanocarriers for drug delivery application: From passive to smart strategies10.1016/j.ijpharm.2017.10.008 ↗
40. Biogenesis of ZnO nanoparticles using Pandanus odorifer leaf extract: Anticancer and antimicrobial activities10.1039/C9RA01659G ↗
41. Simultaneous determination of doxorubicin and dasatinib as two breast anticancer drugs uses an amplified sensor with ionic liquid and ZnO nanoparticle10.1016/j.jelechem.2018.01.034 ↗
42. Increased antibacterial activity of ZnO nanoparticles: Influence of size and surface modification10.1016/j.colsurfb.2019.02.013 ↗
43. Ultrasensitive room-temperature operable gas sensors using p-type Na: ZnO nanoflowers for diabetes detection10.1021/acsami.7b00673 ↗
44. Defect engineering of ZnO nanoparticles for bioimaging applications10.1021/acsami.9b01582 ↗
45. Visible active reduced graphene oxide-BiVO4-ZnO ternary photocatalyst for efficient removal of ciprofloxacin10.1016/j.seppur.2019.115996 ↗
46. Zhang, Q., Xu, M., You, B., Zhang, Q., Yuan, H., and Ostrikov, K.K. (2018). Oxygen vacancy-mediated ZnO nanoparticle photocatalyst for degradation of methylene blue. Appl. Sci., 8.10.3390/app8030353 ↗
47. Inverse stellation of CuAu-ZnO multimetallic-semiconductor nanostartube for plasmon-enhanced photocatalysis10.1021/acsnano.8b00770 ↗
48. Jeon, Y.-R., Yu, J., and Choi, S.-J. (2020). Fate determination of ZnO in commercial foods and human intestinal cells. Int. J. Mol. Sci., 21.10.3390/ijms21020433 ↗
49. A facile in situ method to fabricate transparent, flexible polyvinyl alcohol/ZnO film for UV-shielding10.1016/j.coco.2018.09.009 ↗
50. Preparation of UV-protective starch/kefiran/ZnO nanocomposite as a packaging film: Characterization10.1016/j.fpsl.2018.01.008 ↗
51. Defect luminescence and its mediated physical properties in ZnO10.1016/j.jlumin.2018.12.050 ↗
52. Mechanisms of ZnO luminescence in the visible spectral region10.1134/S0030400X18090205 ↗
53. Role of S, N co-doped graphene quantum dots as a green photosensitizer with Ag-doped ZnO nanorods for improved electrochemical solar energy conversion10.1016/j.materresbull.2017.05.004 ↗
54. Health hazards of nanoparticles: Understanding the toxicity mechanism of nanosized ZnO in cosmetic products10.1080/01480545.2018.1491987 ↗
55. ICP-MS based methods to characterize nanoparticles of TiO2 and ZnO in sunscreens with focus on regulatory and safety issues10.1016/j.scitotenv.2018.02.166 ↗
56. Preparation and characterization of ZnO, MgO and ZnO-MgO hybrid nanomaterials using green chemistry approach10.1016/j.rinma.2020.100104 ↗
57. Effect of yttrium (20%) doping on mechanical properties of rare earth nano lanthanum phosphate (LaPO4) synthesized by aqueous sol-gel process10.1016/j.ceramint.2019.06.033 ↗
58. Khan, M., Janjua, N.K., Khan, S., Qazi, I., Ali, S., and Saad Algarni, T. (2021). Electro-oxidation of ammonia at novel Ag2O−PrO2/γ-Al2O3 catalysts. Coatings, 11.10.3390/coatings11020257 ↗
59. Preferred orientations and microstructures of lanthanum phosphate films prepared via laser chemical vapor deposition10.1016/j.jcrysgro.2019.05.005 ↗
60. Hydrothermal synthesis of lanthanum-doped MgAl-layered double hydroxide/graphene oxide hybrid and its application as flame retardant for thermoplastic polyurethane10.1155/2020/1018093 ↗
61. Binder free lanthanum doped manganese oxide@ graphene oxide composite as high energy density electrode material for flexible symmetric solid state supercapacitor10.1016/j.electacta.2020.135613 ↗
62. A simple sonochemical synthesis of nanosized ZnO from zinc acetate and sodium hydroxide10.21272/jnep.10(5).05023 ↗
63. Synthesis of La2Ce2O7 nanoparticles by co-precipitation method and its characterization10.1166/jnn.2014.8834 ↗
64. Sescu, A.M., Harja, M., Favier, L., Berthou, L.O., De Castro, C.G., Pui, A., and Lutic, D. (2020). Zn/La mixed oxides prepared by coprecipitation: Synthesis, characterization and photocatalytic studies. Materials, 13.10.3390/ma13214916 ↗
65. Rare earth element (REE) lanthanum doped zinc oxide (La:ZnO) nanomaterials: Synthesis structural optical and antibacterial studies10.1016/j.jallcom.2017.06.336 ↗
66. Simultaneous transesterification and esterification of unrefined or waste oils over ZnO-La2O3 catalysts10.1016/j.apcata.2008.10.053 ↗
67. Khan, S., Shah, S.S., Anjum, M.A.R., Khan, M.R., and Janjua, N.K. (2021). Electro-oxidation of ammonia over copper oxide impregnated γ-Al2O3 nanocatalysts. Coatings, 11.10.3390/coatings11030313 ↗
68. Ashna, R., Yulizar, Y., and Apriandanu, D. (2020). Strobilanthes crispus (B.) leaf extract-assisted green synthesis of ZnO-La2O3 composite and preliminary study of its photocatalytic activity. IOP Conference Series: Materials Science and Engineering, IOP Publishing.10.1088/1757-899X/763/1/012004 ↗
69. Influence of pretreatment on lanthanum nitrate, carbonate, and oxide powders10.1021/cm9602555 ↗
70. Structural study, photoluminescence and photocatalytic properties of La2O3 Fe3O4 ZnO, AgO NiO ZnO and La2O3 AgO ZnO nanocomposites10.1016/j.nanoso.2017.03.001 ↗
71. Photo-induced self-cleaning and sterilizing activity of Sm3+ doped ZnO nanomaterials10.1016/j.chemosphere.2012.09.095 ↗
72. Synthesis, characterization, shape-preserved transformation, and optical properties of La(OH)3, La2O2CO3, and La2O3 nanorods10.1016/j.jallcom.2010.09.041 ↗
73. Catalytic activity of first row transition metal oxides in the conversion of p-nitrophenol to p-aminophenol10.1016/j.molcata.2011.08.009 ↗
74. Ecofriendly method to synthesize poly (o-aminophenol) based on solid state polymerization and fabrication of nanostructured semiconductor thin film10.1016/j.polymer.2017.05.048 ↗
75. PtNi nanoparticles embedded in porous silica microspheres as highly active catalysts for p-nitrophenol hydrogenation to p-aminophenol10.1007/s12039-016-1139-4 ↗