journal article·2018-10-29Open access

Mechanical Properties of Hydrogen Free Diamond-Like Carbon Thin Films Deposited by High Power Impulse Magnetron Sputtering with Ne

Asim Aijaz, Fabio Ferreira, Joao Oliveira, Tomas Kubart

Coatings· Volume 8· Issue 11

Abstract

Hydrogen-free diamond-like carbon (DLC) thin films are attractive for a wide range of industrial applications. One of the challenges related to the use of hard DLC lies in the high intrinsic compressive stresses that limit the film adhesion. Here, we report on the mechanical and tribological properties of DLC films deposited by High Power Impulse Magnetron Sputtering (HiPIMS) with Ne as the process gas. In contrast to standard magnetron sputtering as well as standard Ar-based HiPIMS process, the Ne-HiPIMS lead to dense DLC films with increased mass density (up to 2.65 g/cm3) and a hardness of 23 GPa when deposited on steel with a Cr + CrN adhesion interlayer. Tribological testing by the pin-on-disk method revealed a friction coefficient of 0.22 against steel and a wear rate of 2 × 10−17 m3/Nm. The wear rate is about an order of magnitude lower than that of the films deposited using Ar. The differences in the film properties are attributed to an enhanced C ionization in the Ne-HiPIMS discharge.
Source: crossref · Quality: baseline

Research context

OpenAlex topics: Diamond and Carbon-based Materials Research · Metal and Thin Film Mechanics · Lubricants and Their Additives

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

Affiliations

Solid State Electronics, The Ångström Laboratory, Uppsala University, SE-75121 Uppsala, Sweden

SEG-CEMMPRE-Department of Mechanical Engineering, University of Coimbra, Rua Luis Reis Santos, 3030-788 Coimbra, Portugal

Funding

Fundação para a Ciência e a Tecnologia · VINNOVA

References (28)

Show source-provided references
1. Tribology of diamond-like carbon films: Recent progress and future prospects10.1088/0022-3727/39/18/R01 ↗
2. Microstructure, mechanical and tribological characterization of CrN/DLC/Cr-DLC multilayer coating with improved adhesive wear resistance10.1016/j.apsusc.2017.12.266 ↗
3. Investigation of Cr(N)/DLC multilayer coatings elaborated by PVD for high wear resistance and low friction applications10.1016/j.surfcoat.2018.01.052 ↗
4. Thick, well-adhered, highly stressed tetrahedral amorphous carbon10.1016/S0925-9635(00)00530-6 ↗
5. Preparation of tetrahedral amorphous carbon films by filtered cathodic vacuum arc deposition10.1016/S0925-9635(99)00339-8 ↗
6. Pulsed laser deposition of diamond-like carbon wear protective coatings: A review10.1016/S0257-8972(97)00007-8 ↗
7. Effect of film thickness on the stress and adhesion of diamond-like carbon coatings10.1016/S0925-9635(02)00109-7 ↗
8. Density, sp3 fraction, and cross-sectional structure of amorphous carbon films determined by X-ray reflectivity and electron energy-loss spectroscopy10.1103/PhysRevB.62.11089 ↗
9. Diamond-like carbon: State of the art10.1016/S0925-9635(98)00262-3 ↗
10. Antiwear material criteria
11. Diamond-like amorphous carbon10.1016/S0927-796X(02)00005-0 ↗
12. A simple model for the formation of compressive stress in thin films by ion bombardment10.1016/0040-6090(93)90201-Y ↗
13. Molecular-dynamics study of compressive stress generation10.1103/PhysRevB.53.4117 ↗
14. Stress reduction and bond stability during thermal annealing of tetrahedral amorphous carbon10.1063/1.370531 ↗
15. Ion induced stress relaxation in dense sputter-deposited DLC thin films10.1063/1.4997324 ↗
16. A strategy for increased carbon ionization in magnetron sputtering discharges10.1016/j.diamond.2011.12.043 ↗
17. Synthesis of hydrogenated diamondlike carbon thin films using neon-acetylene based high power impulse magnetron sputtering discharges10.1116/1.4964749 ↗
18. Celebrating the 100th anniversary of the stoney equation for film stress: Developments from polycrystalline steel strips to single crystal silicon wafers10.1016/j.tsf.2008.07.014 ↗
20. Interpretation of Raman spectra of disordered and amorphous carbon10.1103/PhysRevB.61.14095 ↗
21. Surface roughness evolution and growth mechanism of carbon films from hyperthermal species10.1016/j.diamond.2007.07.019 ↗
22. Diamond-like carbon—Present status10.1016/S0925-9635(99)00087-4 ↗
23. Donnet, C., and Erdemir, A. (2008). Tribology of Diamond-Like Carbon Films: Fundamentals and Applications, Springer.10.1007/978-0-387-49891-1 ↗
24. Study of the mechanical properties of tetrahedral amorphous carbon films by nanoindentation and nanowear measurements10.1016/S0925-9635(00)00461-1 ↗
25. Friction induced phase transformation of pulsed laser deposited diamond-like carbon10.1016/0925-9635(96)00538-9 ↗
26. Structure, mechanical and tribological properties of Ti-doped amorphous carbon films simultaneously deposited by magnetron sputtering and pulse cathodic arc10.1016/j.diamond.2017.05.010 ↗
27. Thermal stability and oxidation resistance of Ti–Al–N coatings10.1016/j.surfcoat.2011.12.028 ↗
28. Tribological behavior of thick CrN coatings deposited by modulated pulsed power magnetron sputtering10.1016/j.surfcoat.2011.10.053 ↗