journal article·2018-09-18Open access

Influence of Particle Velocity When Propelled Using N2 or N2-He Mixed Gas on the Properties of Cold-Sprayed Ti6Al4V Coatings

Adrian Wei-Yee Tan, Jun Yan Lek, Wen Sun, Ayan Bhowmik, Iulian Marinescu, Xu Song, Wei Zhai, Feng Li, Zhili Dong, Chris B. Boothroyd, Erjia Liu

Coatings· Volume 8· Issue 9

Abstract

Cold-spraying is a relatively new low-temperature coating technology which produces coatings by the deposition of metallic micro-particles at supersonic speed onto target substrate surfaces. This technology has the potential to enhance or restore damaged parts made of light metal alloys, such as Ti6Al4V (Ti64). Particle deposition velocity is one of the most crucial parameters for achieving high-quality coatings because it is the main driving force for particle bonding and coating formation. In this work, studies were conducted on the evolution of the properties of cold-sprayed Ti64 coatings deposited on Ti64 substrates with particle velocities ranging from 730 to 855 m/s using pure N2 and N2-He mixture as the propellant gases. It was observed that the increase in particle velocity significantly reduced the porosity level from about 11 to 1.6% due to greater densification. The coatings’ hardness was also improved with increased particle velocity due to the intensified grain refinement within the particles. Interestingly, despite the significant differences in the coating porosities, all the coatings deposited within the velocity range (below and above critical velocity) achieved a high adhesion strength exceeding 60 MPa. The fractography also showed changes in the degree of dimple fractures on the particles across the deposition velocities. Finite element modelling was carried out to understand the deformation behaviour of the impacting particles and the evolutions of strain and temperature in the formed coatings during the spraying process. This work also showed that the N2-He gas mixture was a cost-effective propellant gas (up to 3-times cheaper than pure He) to deliver the high-quality Ti64 coatings.
Source: crossref · Quality: baseline

Research context

OpenAlex topics: High-Temperature Coating Behaviors · Advanced materials and composites · Metal and Thin Film Mechanics

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

Affiliations

Rolls-Royce@NTU Corporate Lab, Nanyang Technological University, 50 Nanyang Avenue, Singapore 639798, Singapore

School of Mechanical & Aerospace Engineering, Nanyang Technological University, 50 Nanyang Avenue, Singapore 639798, Singapore

Facility for Analysis, Characterisation, Testing and Simulation (FACTS), Nanyang Technological University, 50 Nanyang Avenue, Singapore 639798, Singapore

Advanced Technology Centre, Rolls-Royce Singapore Pte Ltd., 1 Seletar Aerospace Crescent, Singapore 797575, Singapore

Singapore Institute of Manufacturing Technology (SIMTech), 73 Nanyang Drive, Singapore 637662, Singapore

School of Materials Science and Engineering, Nanyang Technological University, 50 Nanyang Avenue, Singapore 639798, Singapore

Funding

National Research Foundation (NRF), Rolls-Royce (RR) and Nanyang Technological University (NTU), Singapore

References (86)

Show source-provided references
1. An overview on the use of titanium in the aerospace industry10.1016/0921-5093(96)10233-1 ↗
2. CO2-laser beam welding of structural steel with a thickness up to 20 mm10.1051/metal/199693101303 ↗
3. Temperature distribution in adiabatic shear band for ductile metal based on Johnson-Cook and gradient plasticity models10.1016/S1003-6326(06)60057-5 ↗
4. Introduction into the electron beam welding of austenitic 321-type stainless steel10.1016/S0924-0136(97)00485-8 ↗
5. Champagne, V.K. (2007). The Cold Spray Materials Deposition Process: Fundamentals and Applications, CRC Press.10.1201/9781439824122 ↗
6. Papyrin, A., Kosarev, V., Klinkov, S., Alkhimov, A., and Fomin, V.M. (2007). Cold Spray Technology, Elsevier. [1st ed.].
7. Impact of high velocity cold spray particles10.1361/105996399770350250 ↗
8. A systematic approach to material eligibility for the cold-spray process10.1361/10599630522738 ↗
9. McCune, R.C., Papyrin, A.N., Hall, J.N., Riggs, W.L.I., and Zajchowski, P.H. (1995, January 11–15). An exploration of the cold gas-dynamic spray method for several materials systems. Proceedings of the 8th National Thermal Spray Conference, Houston, TX, USA.
10. On some aspects of gas dynamics of the cold spray process10.1361/105996303770348384 ↗
11. New developments in cold spray based on higher gas and particle temperatures10.1361/105996306X147144 ↗
12. Adiabatic shear instability based mechanism for particles/substrate bonding in the cold-gas dynamic-spray process10.1016/j.matdes.2004.03.008 ↗
13. Bonding features and associated mechanisms in kinetic sprayed titanium coatings10.1016/j.actamat.2009.07.061 ↗
14. General aspects of interface bonding in kinetic sprayed coatings10.1016/j.actamat.2008.06.003 ↗
15. Gas-dynamic spraying study of a plane supersonic two-phase jet10.1007/BF02467920 ↗
16. Gas dynamic principles of cold spray10.1361/105996398770350945 ↗
17. Particle velocity and deposition efficiency in the cold spray process10.1361/105996399770350278 ↗
18. Bonding mechanism in cold gas spraying10.1016/S1359-6454(03)00274-X ↗
19. Grain refinement in a single titanium powder particle impacted at high velocity10.1016/j.scriptamat.2008.06.020 ↗
20. High velocity impact induced microstructure evolution during deposition of cold spray coatings: A review10.1016/j.surfcoat.2014.06.006 ↗
21. Processing parameters affecting cold spay coatings performances10.1007/s00170-013-5465-0 ↗
22. Effect of pulsed laser ablation and continuous laser heating on the adhesion and cohesion of cold sprayed Ti-6Al-4V coatings10.1007/s11666-012-9812-8 ↗
23. Deposition characteristics of cold sprayed Inconel 718 particles on Inconel 718 substrates with different surface conditions10.1016/j.msea.2018.02.059 ↗
24. Effect of substrate surface condition on fatigue behavior of cold sprayed Ti6Al4V coatings10.1016/j.surfcoat.2016.11.093 ↗
25. Influence of feedstock powder and cold spray processing parameters on microstructure and mechanical properties of Ti-6Al-4V cold spray depositions10.1016/j.surfcoat.2017.12.014 ↗
26. Influence of impact angle and gas temperature on mechanical properties of titanium cold spray deposits10.1007/s11666-010-9557-1 ↗
27. Development of a generalized parameter window for cold spray deposition10.1016/j.actamat.2005.10.005 ↗
28. From particle acceleration to impact and bonding in cold spraying10.1007/s11666-009-9357-7 ↗
29. Study of the influence of particle velocity on adhesive strength of cold spray deposits10.1007/s11666-011-9707-0 ↗
30. Cold spraying of amorphous Cu50Zr50 alloys
31. Effect of powder state on the deposition behaviour and coating development in kinetic spray process10.1088/0022-3727/42/7/075305 ↗
32. Production of titanium deposits by cold-gas dynamic spray: Numerical modeling and experimental characterization10.1361/105996306X108219 ↗
33. Influence of helium and nitrogen gases on the properties of cold gas dynamic sprayed pure titanium coatings10.1007/s11666-010-9568-y ↗
34. Examination of the critical velocity for deposition of particles in cold spraying10.1361/105996306X108093 ↗
35. Particle in-flight velocity and dispersion measurements at increasing particle feed rates in cold spray10.1007/s11666-016-0496-3 ↗
36. Effect of injection pressure on particle acceleration, dispersion and deposition in cold spray10.1016/j.commatsci.2014.03.055 ↗
37. Characterization of cold spray titanium supersonic jet10.1007/s11666-008-9278-x ↗
38. Optimal design of a cold spray nozzle by numerical analysis of particle velocity and experimental validation with 316L stainless steel powder10.1016/j.matdes.2006.05.016 ↗
39. Estimating the effect of helium and nitrogen mixing on deposition efficiency in cold spray10.1007/s11666-016-0394-8 ↗
40. Numerical investigation on acceleration of gaseous mixture of nitrogen and helium on particles during cold spraying
41. Irissou, E., Ilinca, F., Wong, W., Legoux, J., and Yue, S. (2011, January 27–29). Investigation on the effect of helium-to-nitrogen ratio as propellent gas mixture on the processing of titanium coating using cold gas dynamic spray. Proceedings of the International Thermal Spray Conference (ITSC 2011), Hamburg, Germany.10.31399/asm.cp.itsc2011p0066 ↗
42. Effects of working gas on wear and corrosion resistances of cold sprayed Ti-6Al-4V coatings10.1016/j.surfcoat.2016.05.052 ↗
43. Adhesion, tribological and corrosion properties of cold-sprayed CoCrMo and Ti6Al4V coatings on 6061-T651 Al alloy10.1016/j.surfcoat.2017.07.062 ↗
44. The effect of deposition conditions on adhesion strength of Ti and Ti6Al4V cold spray splats10.1007/s11666-011-9720-3 ↗
45. Single impact bonding of cold sprayed Ti-6Al-4V powders on different substrates10.1007/s11666-014-0200-4 ↗
46. Mechanical and microstructural characterization of cold-sprayed Ti-6Al-4V after heat treatment10.1007/s11666-013-9945-4 ↗
47. Microstructure and mechanical property of Ti and Ti6Al4V prepared by an in situ shot peening assisted cold spraying10.1016/j.matdes.2015.07.015 ↗
48. Microstructural analysis of cold-sprayed Ti-6Al-4V at the micro- and nano-scale10.1007/s11666-015-0288-1 ↗
49. Ti and Ti-6Al-4V coatings by cold spraying and microstructure modification by heat treatment10.1002/adem.200700022 ↗
50. Cold sprayability of mixed commercial purity Ti plus Ti6Al4V metal powders10.1007/s11666-017-0528-7 ↗
51. Evaluation of mechanical properties of Ti6Al4V cold sprayed coatings10.1080/02670844.2017.1398442 ↗
52. (2010). ASTM B822-10 Standard Test Method for Particle Size Distribution of Metal Powders and Related Compounds by Light Scattering, ASTM International.
53. Effects of traverse scanning speed of spray nozzle on the microstructure and mechanical properties of cold-sprayed Ti6Al4V coatings10.1007/s11666-017-0619-5 ↗
54. (2018, January 19). Kinetic Spray Solutions. Available online: https://kinetic-spray-solutions.com/.
55. Effect of cold work, second phase precipitation and heat treatments on the mechanical properties of copper-silver alloys manufactured by cold spray10.1016/j.msea.2015.04.008 ↗
56. (2013). ASTM C633-13 Standard Test Method for Adhesion or Cohesion Strength of Thermal Spray Coatings, ASTM International.
57. The use of particle/substrate material models in simulation of cold-gas dynamic-spray process10.1007/s11666-013-0051-4 ↗
58. Adiabatic shear instability is not necessary for adhesion in cold spray10.1016/j.actamat.2018.07.065 ↗
59. Correlation of particle impact conditions with bonding, nanocrystal formation and mechanical properties in kinetic sprayed nickel10.1016/j.actamat.2012.03.001 ↗
60. Residual stresses in single particle splat of metal cold spray process – Numerical simulation and direct measurement10.1016/j.matlet.2018.07.117 ↗
61. Understanding the microstructural evolution of cold sprayed Ti-6Al-4V coatings on Ti-6Al-4V substrates10.1016/j.apsusc.2018.07.175 ↗
62. Influence of particle velocity on adhesion of cold-sprayed splats10.1007/s11666-009-9327-0 ↗
63. Analysis of the residual stress and bonding mechanism in the cold spray technique using experimental and numerical methods10.1016/j.surfcoat.2014.04.059 ↗
64. Particle bonding mechanism in cold gas dynamic spray: A three-dimensional approach10.1007/s11666-017-0652-4 ↗
65. Dynamics and extreme plasticity of metallic microparticles in supersonic collisions10.1038/s41598-017-05104-7 ↗
66. Quantitative prediction of critical velocity and deposition efficiency in cold-spray: A finite-element study10.1016/j.scriptamat.2015.05.026 ↗
67. Modeling aspects of high velocity impact of particles in cold spraying by explicit finite element analysis10.1007/s11666-009-9325-2 ↗
68. Numerical simulation of cold spray coating10.1016/j.surfcoat.2011.05.038 ↗
69. Numerical simulation of Taylor impact tests10.1016/j.ijplas.2007.01.012 ↗
70. An experimental–numerical investigation on aluminium tubes subjected to ballistic impact with soft core 7.62 ball projectiles10.1016/j.tws.2013.07.015 ↗
71. Lesuer, D. (2000). Experimental investigation of material models for Ti-6Al-4V and 2024-T3, Lawrence Livermore National Laboratory.10.2172/11977 ↗
72. Maev, R.G., and Leshchynsky, V. (2016). Cold gas dynamic spray, CRC Press. [1st ed.].10.1201/b19486 ↗
73. The features of cold spray nozzle design10.1361/105996301770349466 ↗
74. Haynes, W.M. (2011). Handbook of Chemistry and Physics, CRC Press. [92nd ed.].
75. (2012). Mineral Commodity Summaries 2012.
76. New opportunities to use cold spray process for applying additive features to titanium alloys10.1016/S0026-0657(06)70713-5 ↗
77. Wear and corrosion resistance of thick Ti-6Al-4V coating deposited on Ti-6Al-4V substrate via high-pressure cold spray10.1007/s11666-017-0588-8 ↗
78. Tan, A.W.Y., Sun, W., Khun, N.W., Marinescu, I., Dong, Z., and Liu, E. (2016, January 16–19). Potential of cold spray as additive manufacturing for Ti6Al4V. Proceedings of the 2nd International Conference on Progress in Additive Manufacturing (Pro-AM 2016), Nanyang, Singapore.
79. Effect of the expansion ratio and length ratio on a gas-particle flow in a converging-diverging cold spray nozzle10.1007/s12540-009-0967-x ↗
80. Analysis of cold gas dynamically sprayed aluminium deposits10.1016/j.matlet.2003.09.048 ↗
81. Microstructure and mechanical properties of Ti cold-spray splats determined by electron channeling contrast imaging and nanoindentation mapping10.1017/S1431927615000240 ↗
82. Hall-Petch relationship in nanocrystalline titanium produced by ball-milling10.1007/BF00539997 ↗
83. Pawlowski, L. (2008). Chapter 8: Properties of coatings. The Science and Engineering of Thermal Spray Coatings, John Wiley & Sons. [2nd ed.].10.1002/9780470754085 ↗
84. Effect of coating thickness on microstructure, mechanical properties and fracture behaviour of cold sprayed Ti6Al4V coatings on Ti6Al4V substrates10.1016/j.surfcoat.2018.05.060 ↗
85. Dodd, B., and Bai, Y. (2012). Adiabatic shear localization: Frontiers and Advances, Elsevier. [2nd ed.].
86. Development of ultra-strong adhesive strength coatings using cold spray10.1016/j.surfcoat.2014.07.074 ↗