journal article·2019-10-30Open access

Enhancement of Polyvinyl Acetate (PVAc) Adhesion Performance by SiO2 and TiO2 Nanoparticles

Gorana Petković, Marina Vukoje, Josip Bota, Suzana Pasanec Preprotić

Coatings· Volume 9· Issue 11

Abstract

Post press processes include various types of bonding and adhesives, depending upon the nature of adherends, the end use performance requirements and the adhesive bonding processes. Polyvinyl acetate (PVAc) adhesive is a widely used adhesive in the graphic industry for paper, board, leather and cloth. In this study, the enhancement of PVAc adhesion performance by adding different concentrations (1%, 2% and 3%) of silica (SiO2) and titanium dioxide (TiO2) nanoparticles was investigated. The morphology of investigated paper-adhesive samples was analyzed by SEM microscopy and FTIR spectroscopy. In addition, the optimal adhesion at the interface of paper and adhesive was found according to calculated adhesion parameters by contact angle measurements (work of adhesion, surface free energy of interphase, wetting coefficient). According to obtained surface free energy (SFE) results, optimum nanoparticles concentration was 1%. The wettability of the paper-adhesive surface and low SFE of interphase turned out as a key for a good adhesion performance. The end use T-peel resistance test of adhesive joints confirmed enhancement of adhesion performance. The highest strength improvement was achieved with 1% of SiO2 nanoparticles in PVAc adhesive.
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Research context

OpenAlex topics: Surface Modification and Superhydrophobicity · Material Properties and Processing · Advanced Sensor and Energy Harvesting Materials

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

Affiliations

Faculty of Graphic Arts, University of Zagreb, Getaldićeva 2, 10000 Zagreb, Croatia

Funding

University of Zagreb

References (63)

Show source-provided references
1. Ebnesajjad, S. (2008). Adhesives Technology Handbook, William Andrew. [2nd ed.].
2. The Adhesive and Sealant Council (2006). Standard Definitions of Terms Relating to Adhesives, ASC. Available online: https://pharosproject.net/uploads/files/sources/1828/ASCouncil-AdhesiveGlossary.pdf.
3. Mehanizmi stvaranja lijepljenog spoja
4. Case studies in adhesives selection
5. (2018, November 03). PostPressMag. Available online: https://postpressmag.com/articles/2014/digital-printing-leads-to-print-finishing-opportunities/.
6. Analiza okolišne održivosti tehnologije adheziva
7. Roberts, M.T., and Etherington, D. (2018, September 10). Bookbinding and the Conservation of Books: A Dictionary of Descriptive Terminology, Available online: https://files.eric.ed.gov/fulltext/ED232698.pdf.
8. Pizzi, A., and Mittal, K.L. (2003). Polyvinyl and Ethylene–Vinyl Acetates. Handbook of Adhesive Technology, Marcel Dekker, Inc.. [2nd ed.].
9. Packham, D.E. (2005). Wood adhesives-basic. Handbook of Adhesion, John Wiley & Sons, Ltd.. [2nd ed.].10.1002/0470014229 ↗
10. Adhesives for paper, board and foils10.1016/S0143-7496(99)00052-4 ↗
11. Influence of Temperature on the Strength of Bonded Joints
12. (2018, August 09). IBookBinding. Available online: https://www.ibookbinding.com/blog/bookbinding-gluing-tips-techniques -types-info/.
13. Rebsamen, W. (1983). Adhesive Binding Library Books, The New Library Scene. Available online: http://mekatronicsinc.com/wp-content/uploads/2019/08/Adhesive-library-binding-books-Werner_1983.pdf.
14. Characteristics of non-plasticizer PVAc resin for wood products
15. A new methodology in the study of PVAc-based adhesive formulations10.1002/app.31032 ↗
16. The effect of nano-TiO2 and SiO2 on bonding strength and structural properties of poly (vinyl acetate) composites10.1016/j.measurement.2016.07.004 ↗
17. Synthesis of PVAc/SiO2 latices stabilized by silica nanoparticles10.1016/j.jcis.2007.11.059 ↗
18. The Effects of Poly(vinyl acetate) Filled with Nanoclay and Cellulose Nanofibrils on Adhesion Strength of Poplar and Scots Pine Wood10.5552/drind.2016.1441 ↗
19. Cellulose nanofibrils/polyvinyl acetate nanocomposite adhesives with improved mechanical properties10.1016/j.carbpol.2016.09.016 ↗
20. Surface Wettability of Wood Species from Tropical and Temperate Zones by Polar and Dispersive Liquids10.5552/drind.2017.1704 ↗
21. The effect of different nanoparticles and open time on bonding strength of poly (vinyl acetate) adhesive10.1016/j.measurement.2015.12.003 ↗
22. Influence of TiO2 Nanoparticles on the Morphological, Thermal and Solution Properties of PVA/TiO2 Nanocomposite Membranes10.1007/s13369-014-1287-0 ↗
23. Effect of the Incorporation of Modified Silicas on the Final Properties of Wood Adhesives10.1002/mren.201300117 ↗
24. Effects of adding nano-clay (montmorillonite) on performance of polyvinyl acetate (PVAc) and urea-formaldehyde (UF) adhesives in Carapa guianensis, a tropical species10.1016/j.ijadhadh.2015.02.004 ↗
25. Polymer nanocomposites for structural applications: Recent trends and new perspectives10.1080/15376494.2015.1068406 ↗
26. Prolongo, S., Gude, M., and Ureña, A. (2010). Nanoreinforced Adhesives, IntechOpen. Available online: http://www.intechopen.com/books/nanofibers/nanoreinforced-adhesives.
27. Nano-Enhanced Adhesives: A Critical Review10.7569/RAA.2014.097307 ↗
28. Hybrid silica-PVA nanofibers via sol-gel electrospinning10.1021/la300049j ↗
29. ISO 4287:1997 International Organization for Standardization: Geometrical Product Specifications (GPS) - Surface texture: Profile method - Terms, definitions and surface texture parameters.
30. TAPPI T 412 om-16 Moisture in Pulp, Paper and Paperboard, Test Method.
31. TAPPI T 553 om-15 Alkalinity of Paper as Calcium Carbonate (Alkaline Reserve of Paper).
32. TAPPI T 413 om-17 Ash in Wood, Pulp, Paper and Paperboard: Combustion at 900 °C.
33. TAPPI T 441 om-13 Water Absorptiveness of Sized (Non-Bibulous) Paper, Paperboard and Corrugated Fiberboard (Cobb Test).
34. ISO 1924-2:2008 Paper and Board-Determination of Tensile Properties-Part 2: Constant Rate of Elongation Method (20 mm/min).
35. Kovač, M. (2011). Sigurnosno-Tehnički List Za Kemijske Proizvode: Signokol L., Signoplast d.o.o.
36. Evonik Resource Efficiency GmbH (2019). Product Information AEROSIL R 8200, Evonik. Available online: https://products-re.evonik.com/www2/uploads/productfinder/AEROSIL-R-8200-EN.pdf.
37. (2019, October 29). AEROXID TiO2 P25. Available online: https://products-re.evonik.com/www2/uploads/productfinder/AEROXIDE-TiO2-P-25-EN.pdf.
38. ISO 187:1990 Paper, Board and Pulps-Standard Atmosphere for Conditioning and Testing and Procedure for Monitoring the Atmosphere and Conditioning of Samples.
39. ASTM D1876-08 (2015)e1 Standard Test Method for Peel Resistance of Adhesives (T-Peel Test).
40. Comparison of methods for the surface free energy determination of polimeric layers aligning liquid crystals
41. TAPPI T 558 om-15 Surface Wettability and Absorbency of Sheeted Materials Using an Automated Contact Angle Tester.
42. Roberts, J.C. (1996). The Chemistry of Paper, The Royal Society of Chemistry.10.1039/9781847552068 ↗
43. Interactions in polyvinyil acetate - paper adhesive joint and influence on its adhesion parameters
44. Interaction effects between cellulose and water in nanocrystalline and amorphous regions: A novel approach using molecular modeling
45. Holik, H. (2013). Mineral Fillers in Papermaking. Handbook of Paper and Board, Wiley-Vch. [2nd ed.].10.1002/9783527652495 ↗
46. Changes in the chemical and physical properties of paper documents due to natural ageing
47. Niskanen, K. (2008). Paper structure. Paper Physics, Finnish Paper Engineers Association. [2nd ed.].
48. Tensile properties of calcium carbonate-reinforced poly (vinyl acetate)10.1163/156856196X00247 ↗
49. (2018, December 12). Sappi Printer Tech Tips. Available online: https://www.sappi.com/files/sappi-printer-tech-tips-calcium-carbonate-cover0jpg.
50. Grönfors, J. (2010). Use of Fillers in Paper and Paperboard Grades. [Bachelor’s Thesis, Tampere University of Applied Sciences International].
51. Interfacial interaction between low energy surfaces10.1016/0927-796X(95)00185-9 ↗
52. Methods for the calculation of surface free energy of solids
53. (2018, February 10). Krüss Advancing Your Surface Science. Available online: https://www.kruss-scientific.com/services/education-theory/glossary/owens-wendt-rabel-and-kaelble-owrk-method/.
54. Contact angles and wettability of cellulosic surfaces: A review of proposed mechanisms and test strategies10.15376/biores.10.4.Hubbe_Gardner_Shen ↗
55. Surface characteristics and enhancement of water vapour properties of paperboard coated with polycaprolactone nanocomposites10.1080/01694243.2016.1218313 ↗
56. Effect of calcium carbonate particle size and surface pretreatment on polyurethane composite Part I: Interface and mechanical properties10.1179/143307508X270820 ↗
57. Effects of inorganic nanofillers on the thermal degradation and UV-absorbance properties of polyvinyl acetate10.1007/s10973-011-2153-x ↗
58. Molecular imprinting method for fabricating novel glucose sensor: Polyvinyl acetate electrode reinforced by MnO2/CuO loaded on graphene oxide nanoparticles10.1016/j.foodchem.2015.07.128 ↗
59. Photochemical degradation study of polyvinyl acetate paints used in artworks by Py-GC/MS10.1016/j.jaap.2012.05.004 ↗
60. A parametric study of the peel test10.1016/j.ijadhadh.2007.06.006 ↗
61. The effects of partial bonding in load carrying capacity of single lap joints10.1016/j.ijadhadh.2011.01.009 ↗
62. Duncan, B., and Crocker, L. (2001). Review of Tests for Adhesion Strength, NPL Materials Center. Available online: https://www.researchgate.net/profile/Louise_Crocker/publication/281283390_Review_of_Tests_for_Adhesion_Strength/links/55df2b8808ae7983897e8bce/Review-of-Tests-for-Adhesion-Strength.pdf.
63. A generalized cohesive zone model of the peel test for pressure-sensitive adhesives10.1016/j.ijadhadh.2008.05.002 ↗