journal article·2020-04-09Open access

Microstructure Evolution and Properties of Laser Cladding CoCrFeNiTiAlx High-Entropy Alloy Coatings

Yiku Xu, Zhiyuan Li, Jianru Liu, Yongnan Chen, Fengying Zhang, Lei Wu, Jianmin Hao, Lin Liu

Coatings· Volume 10· Issue 4

Abstract

High-entropy alloy (HEA) coatings of CoCrFeNiTiAlx (x = 0, 0.5, 1, 1.5, 2) were prepared on the surface of AISI1045 steel by laser cladding. The effects of the Al content on the microstructure, composition, phase constitution, and wear and corrosion resistance of the coatings were investigated. The results showed that when increasing the Al element content from 0 to 0.5, the phase constitution of the CoCrFeNiTiAlx coating changed from a single Face-centered cubic (FCC) phase to Body-centered cubic 1 (BCC1) and Body-centered cubic 2 (BCC2) phases, with a small amount of Laves phase, which obviously improved the friction and corrosion resistance of the coating. With further enhancing of the Al content, the amount of BCC1 phase increased, while the BCC2 phase and the Laves phase decreased. The CoCrFeNiTiAl2 HEA coating transformed into a single BCC1 phase, with retrogressive wear and corrosion resistance. It was found that the Al0.5 alloy coating exhibits excellent wear resistance, high hardness, and corrosion resistance in a 3.5 wt.% NaCl solution. Furthermore, the effect of the Al content on the microstructure, phase, and the relating properties of the CoCrFeNiTiAlx HEA coatings is also discussed.
Source: crossref · Quality: baseline

Research context

OpenAlex topics: High Entropy Alloys Studies · High-Temperature Coating Behaviors · Additive Manufacturing Materials and Processes

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

Affiliations

School of Material Science and Engineering, Chang’an University, Xi’an 710064, China

State Key Laboratory of Solidification and Processing, Northwestern Polytechnical University, Xi’an 710072, China

Funding

National Key Research and Development Program of China · Program of Study Abroad for Young Scholar sponsored by CSC (China Scholarship Council) · National Natural Science Foundation of China · Fundamental Research Funds for the Central Universities · Innovation and Entrepreneurship Training Program of Chang’ an University · Key projects of Shaanxi Natural Science Foundation · Shaanxi Natural Science Basic Research Program-Shaanxi Coal

References (27)

Show source-provided references
1. Nanostructured high-entropy alloys with multiple principal elements: Novel alloy design concepts and outcomes10.1002/adem.200300567 ↗
2. Microstructures and properties of high-entropy alloys10.1016/j.pmatsci.2013.10.001 ↗
3. Solid-solution phase formation rules for multi-component alloys10.1002/adem.200700240 ↗
4. Effect of alloying elements on microstructure and properties of multiprincipal elements high-entropy alloys10.1016/j.jallcom.2008.07.124 ↗
5. Microstructure and wear behavior of AlxCo1.5CrFeNi1.5Tiy high-entropy alloys10.1016/j.actamat.2011.06.041 ↗
6. High-entropy alloy coatings with excellent mechanical, corrosion resistance and magnetic properties prepared by mechanical alloying and hot pressing sintering10.1016/j.surfin.2017.06.012 ↗
7. Microstructure and enhanced strength of laser aided additive manufactured CoCrFeNiMn high entropy alloy10.1016/j.msea.2018.12.005 ↗
8. Microstructure and mechanical properties of Al0.7CoCrFeNi high-entropy-alloy prepared by directional solidification10.1016/j.intermet.2017.11.019 ↗
9. Microstructural characteristics of high-velocity oxygen-fuel (HVOF) sprayed nickel-based alloy coating10.1016/j.jallcom.2013.07.109 ↗
10. Phase evolution and solidification cracking sensibility in laser remelting treatment of the plasma-sprayed CrMnFeCoNi high entropy alloy coating10.1016/j.matdes.2019.108040 ↗
11. Understanding the microstructural evolution of high entropy alloy coatings manufactured by atmospheric plasma spray processing10.1016/j.apsusc.2019.144117 ↗
12. Microstructural characterization and corrosion behaviour of AlCoCrFeNiTix high-entropy alloy coatings fabricated by laser cladding10.1016/j.surfcoat.2019.01.044 ↗
13. Laser surface alloying of FeCoCrAlNi high-entropy alloy on 304 stainless steel to enhance corrosion and cavitation erosion resistance10.1016/j.optlastec.2016.04.011 ↗
14. Characterization of process efficiency improvement in laser additive manufacturing10.1016/j.phpro.2014.08.177 ↗
15. Additive Manufacturing of High-Entropy Alloys by Laser Processing10.1007/s11837-016-1888-z ↗
16. Effect of Al content on high temperature oxidation resistance of AlxCoCrCuFeNi high entropy alloys (x = 0, 0.5, 1, 1.5, 2)10.1016/j.vacuum.2019.108837 ↗
17. Effects of annealing treatment on phase composition and microstructure of CoCrFeNiTiAlx high-entropy alloys10.1016/j.intermet.2011.10.010 ↗
18. The effect of Al content on microstructures and comprehensive properties in AlxCoCrCuFeNi high entropy alloys10.1016/j.vacuum.2018.12.009 ↗
19. Studies on the microstructure and properties of AlxCoCrFeNiTi1−x high entropy alloys10.1016/j.jallcom.2018.01.247 ↗
20. Electrochemical passive properties of AlxCoCrFeNi (x = 0, 0.25, 0.50, 1.00) alloys in sulfuric acids10.1016/j.corsci.2009.11.028 ↗
21. Phase stability in high entropy alloys: Formation of solid-solution phase or amorphous phase10.1016/S1002-0071(12)60080-X ↗
22. Contact and Rubbing of Flat Surfaces10.1063/1.1721448 ↗
23. Phase transformation induced by lattice distortion in multiprincipal component CoCrFeNiCuXAl1−x solid-solution alloys10.1063/1.2938690 ↗
24. Courtney, T. (1990). Mechanical Behavior of Materials, McGraw-Hill.
25. Mechanical performance of the AlxCoCrCuFeNi high-entropy alloy system with multiprincipal elements10.1007/s11661-005-0218-9 ↗
26. Sha, M., Jia, C., Qiao, J., Feng, W., Ai, X., Jing, Y.-A., Shen, M., and Li, S. (2019). Microstructure and Properties of High-Entropy AlxCoCrFe2.7MoNi Alloy Coatings Prepared by Laser Cladding. Metals, 9.10.3390/met9121243 ↗
27. Microbeam plasma arc remanufacturing: Effects of Al on microstructure, wear resistance, corrosion resistance and high temperature oxidation resistance of AlxCoCrFeMnNi high-entropy alloy cladding layer10.1016/j.vacuum.2020.109178 ↗