journal article·2019-01-15Open access

Preparation and Corrosion Resistance of ETEO Modified Graphene Oxide/Epoxy Resin Coating

Chunling Zhang, Xueyan Dai, Yingnan Wang, Guoen Sun, Peihong Li, Lijie Qu, Yanlong Sui, Yanli Dou

Coatings· Volume 9· Issue 1

Abstract

Improving the corrosion resistance of epoxy resin coatings has become the focus of current research. This study focuses on synthesizing a functionalized silane coupling agent (2-(3,4-epoxycyclohexyl)ethyl triethoxysilane) to modify the surface of graphene oxide to address nanomaterial agglomeration and enhance the coating resistance of the epoxy resin coating to corrosion by filling the coating with functionalized graphene oxide. Functionalized graphene oxide and coatings filled with functionalized graphene oxide were characterized by Fourier transform infrared spectroscopy, X-ray diffraction, X-ray photoelectron spectroscopy, scanning electron microscopy, and transmission electron microscopy. The corrosion performance of each coating was studied by electrochemical impedance spectroscopy and a salt spray test. Results showed that the incorporation of functionalized graphene oxide enhances the corrosion protection performance of the epoxy composite coating, and the composite coating exhibited the best anticorrosion performance when the amount of functionalized graphene oxide was 0.7 wt %.
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Research context

OpenAlex topics: Corrosion Behavior and Inhibition · Graphene research and applications · Fiber-reinforced polymer composites

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

Affiliations

Key Laboratory of Automobile Materials, Ministry of Education, College of Materials Science and Engineering, Jilin University, Changchun 130022, China

Funding

the Development Project of Jilin provincial Science and Technology of China

References (42)

Show source-provided references
1. “Smart” coatings for active corrosion protection based on multi-functional micro and nanocontainers10.1016/j.electacta.2012.04.095 ↗
2. Electroactive conducting polymers for corrosion control10.1007/s100080100212 ↗
3. Mathematical model for the cathodic blistering of organic coatings on steel immersed in electrolytes
4. Corrosion protection by organic coatings: Electrochemical mechanism and novel methods of investigation10.1016/S0013-4686(00)00348-0 ↗
5. The study of coal tar epoxy protective coatings by impedance spectroscopy10.1016/0033-0655(94)80004-9 ↗
6. Relationships between glass-transition temperature and conversion-analyses of limiting cases10.1007/BF00298330 ↗
7. Epoxy compositions cured with aluminosilsesquioxanes: Thermomechanical properties10.1002/app.40672 ↗
8. Application of the electrochemical noise to investigate the corrosion resistance of an epoxy zinc-rich coating loaded with lamellar aluminum and micaceous iron oxide particles10.1016/j.corsci.2013.07.034 ↗
9. Synthesize and characterization of a novel anticorrosive cobalt ferrite nanoparticles dispersed in silica matrix (CoFe2O4-SiO2) to improve the corrosion protection performance of epoxy coating10.1016/j.apsusc.2016.03.129 ↗
10. Chromium toxicity in plants10.1016/j.envint.2005.02.003 ↗
11. Thermoplastic toughening of epoxy resins: A critical review10.1002/(SICI)1099-1581(199801)9:1<3::AID-PAT727>3.0.CO;2-I ↗
12. Enhanced thermal conductivity of fluorinated epoxy resins by incorporating inorganic filler10.1016/j.reactfunctpolym.2018.05.004 ↗
13. Synthesis and properties of novel fluorinated epoxy resins based on 1,1-bis(4-glycidylesterphenyl)-1-(3′-trifluoromethylphenyl)-2,2,2-trifluoroethane10.1016/j.eurpolymj.2006.10.030 ↗
14. Modification of epoxy resin using reactive liquid (ATBN) rubber10.1016/S0014-3057(01)00194-X ↗
15. Amine-functionalized poly(styrene) microspheres as thermoplastic toughener for epoxy resin10.1002/pc.22927 ↗
16. Polymeric sol–gel coatings as protective layers of aluminium alloys10.1016/S0300-9440(03)00014-6 ↗
17. Effect of nano-Fe2O3 particles on the corrosion behavior of alkyd based waterborne coatings10.1016/j.corsci.2008.09.028 ↗
18. Influence of various surface treated silica nanoparticles on the electrochemical properties of SiO2/polyurethane nanocoatings10.1016/j.corsci.2011.08.036 ↗
19. Corrosion protection properties of composite hybrid coatings with involved nanoparticles of zirconia and ceria
20. Conducting polyaniline–nano-TiO2 composites for smart corrosion resistant coatings10.1016/j.electacta.2008.08.069 ↗
21. Studying the corrosion resistance and hydrolytic degradation of an epoxy coating containing zno nanoparticles10.1016/j.matchemphys.2011.08.065 ↗
22. CeO2-filled sol–gel coatings for corrosion protection of AA2024-T3 aluminium alloy10.1016/j.corsci.2009.06.007 ↗
23. Study on nano-CaCO3 modified epoxy powder coatings10.1016/j.porgcoat.2006.01.007 ↗
24. Grafting of epoxy chains onto graphene oxide for epoxy composites with improved mechanical and thermal properties10.1016/j.carbon.2013.12.050 ↗
25. Preparation of aluminum oxide-coated carbon nanotubes and the properties of composite epoxy coatings research10.1177/0954008313509390 ↗
26. Properties of surface-treated mica in anticorrosive coatings10.1016/j.porgcoat.2003.09.003 ↗
27. Self-healing capability of inhibitor-encapsulating polyvinyl alcohol/polyvinylidene fluoride coaxial nanofibers loaded in epoxy resin coatings10.1016/j.porgcoat.2018.03.010 ↗
28. Corrosion process and abatement in reinforced concrete wrapped by fiber reinforced polymer10.1016/j.cemconcomp.2008.02.004 ↗
29. Effect of nanoparticles on the anticorrosion and mechanical properties of epoxy coating10.1016/j.surfcoat.2009.06.048 ↗
30. Graphene-based composite materials10.1038/nature04969 ↗
31. Molecular-level dispersion of graphene into poly(vinyl alcohol) and effective reinforcement of their nanocomposites10.1002/adfm.200801776 ↗
32. The chemistry of graphene oxide10.1039/B917103G ↗
33. Control of the functionality of graphene oxide for its application in epoxy nanocomposites10.1016/j.polymer.2013.09.054 ↗
34. Preparation and anticorrosion properties of silane grafted nano-silica/epoxy composite coating
35. Preparation of graphitic oxide10.1021/ja01539a017 ↗
36. (2006). GB/T 6739-2006 Paints and Varnishes–Determination of Film Hardness by Pencil Test, Standardization Administration of China. (In Chinese).
37. (2010). ASTM D2794-93 Standard Test Method for Resistance of Organic Coatings to the Effects of Rapid Deformation (Impact), ASTM International.
38. (2006). GB/T 10125-1997 Corrosion Tests in Artificial Atmospheres–Salt Spray Tests, Standardization Administration of China. (In Chinese).
39. Enhancement of the corrosion protection performance and cathodic delamination resistance of epoxy coating through treatment of steel substrate by a novel nanometric sol-gel based silane composite film filled with functionalized graphene oxide nanosheets10.1016/j.corsci.2016.04.004 ↗
40. Fabricating an epoxy composite coating with enhanced corrosion resistance through impregnation of functionalized graphene oxide-co-montmorillonite nanoplatelet10.1016/j.corsci.2017.09.024 ↗
41. Superhydrophobic surfaces for corrosion protection: A review of recent progresses and future directions10.1007/s11998-015-9744-6 ↗
42. Influence of surface energetics of graphene oxide on fracture toughness of epoxy nanocomposites10.1016/j.compositesb.2017.01.032 ↗