journal article·2017-02-22Open access

SnS Thin Film Solar Cells: Perspectives and Limitations

Simone Di Mare, Daniele Menossi, Andrei Salavei, Elisa Artegiani, Fabio Piccinelli, Arun Kumar, Gino Mariotto, Alessandro Romeo

Coatings· Volume 7· Issue 2

Abstract

Thin film solar cells have reached commercial maturity and extraordinarily high efficiency that make them competitive even with the cheaper Chinese crystalline silicon modules. However, some issues (connected with presence of toxic and/or rare elements) are still limiting their market diffusion. For this reason new thin film materials, such as Cu2ZnSnS4 or SnS, have been introduced so that expensive In and Te, and toxic elements Se and Cd, are substituted, respectively, in CuInGaSe2 and CdTe. To overcome the abundance limitation of Te and In, in recent times new thin film materials, such as Cu2ZnSnS4 or SnS, have been investigated. In this paper we analyze the limitations of SnS deposition in terms of reproducibility and reliability. SnS deposited by thermal evaporation is analyzed by X-ray diffraction, Raman spectroscopy, scanning electron microscopy, and atomic force microscopy. The raw material is also analyzed and a different composition is observed according to the different number of evaporation (runs). The sulfur loss represents one of the major challenges of SnS solar cell technology.
Source: crossref · Quality: baseline

Research context

OpenAlex topics: Chalcogenide Semiconductor Thin Films · Quantum Dots Synthesis And Properties · Copper-based nanomaterials and applications

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

Affiliations

Laboratory for Applied Physics (LAPS), Department of Computer Science, University of Verona, 37134 Verona, Italy

Solid State Chemistry Laboratory, Department of Biotechnology; University of Verona, 37134 Verona, Italy

Raman Laboratory, Department of Computer Science, University of Verona, 37134 Verona, Italy

Funding

Fondazione Cassa di Risparmio di Trento e Rovereto · Università di Verona, Joint Project

References (57)

Show source-provided references
1. Efficiency limitations of thermally evaporated thin-film SnS solar cells10.1088/0022-3727/46/30/305109 ↗
2. Development of CZTS-based thin film solar cells10.1016/j.tsf.2008.11.002 ↗
3. 15% efficient Cu(In,Ga)Se2 solar cells obtained by low-temperature pulsed electron deposition10.1063/1.4755772 ↗
4. High-efficiency solar cell with earth-abundant liquid-processed absorber10.1002/adma.200904155 ↗
5. Device characteristics of a 10.1% hydrazine-processed Cu2ZnSn(Se,S)4 solar cell10.1002/pip.1160 ↗
6. Device characteristics of CZTSSe thin-film solar cells with 12.6% efficiency10.1002/aenm.201301465 ↗
7. Cu2ZnSnS4 solar cells grown by sulphurisation of sputtered metal precursors10.1016/j.tsf.2013.06.084 ↗
8. Impact of growth temperature on the properties of SnS film prepared by thermal evaporation and its photovoltaic performance10.1016/j.cap.2015.03.026 ↗
9. 3.88% Efficient tin sulfide solar cells using congruent thermal evaporation10.1002/adma.201402219 ↗
10. Overcoming efficiency limitations of SnS-based solar cells10.1002/aenm.201400496 ↗
11. Kolbeckina, un nuevo mineral de estaño—Buenos Aires
12. Pressure-induced structural phase transition in the IV–VI semiconductor SnS10.1088/0953-8984/16/21/004 ↗
13. The preparation and the electrical and optical properties of SnS crystals10.1016/0022-3697(60)90253-5 ↗
14. Band-structure, optical properties, and defect physics of the photovoltaic semiconductor SnS10.1063/1.3675880 ↗
15. Physical properties of very thin SnS films deposited by thermal evaporation10.1016/j.tsf.2011.01.355 ↗
16. Influence of substrate temperature on surface structure and electrical resistivity of the evaporated tin sulphide films10.1016/j.apsusc.2006.03.005 ↗
17. Influence of annealing on physical properties of evaporated SnS films10.1088/0268-1242/21/8/025 ↗
18. The physical properties of SnS films grown on lattice-matched and amorphous substrates10.1002/pssa.200925379 ↗
19. Dieletectric Properties of Vacuum Evaporated SnS Thin Films
20. SnS films prepared by sulfuration of Sn precursor layers
21. SnS thin-films by RF sputtering at room temperature10.1016/j.tsf.2010.12.186 ↗
22. Optical properties of sputtered SnS thin films for photovoltaic absorbers10.1109/JPHOTOV.2013.2251758 ↗
23. Preparation and properties of SnS film grown by two-stage process10.1016/j.apsusc.2010.12.143 ↗
24. Annealing of RF-magnetron sputtered SnS2 precursors as a new route for single phase SnS thin films10.1016/j.jallcom.2013.12.200 ↗
25. Formation of polycrystalline SnS layers by a two-step process10.1016/S0040-6090(01)01520-6 ↗
26. Optical and photoconductive properties of SnS thin films prepared by electron beam evaporation10.1016/j.solmat.2003.06.002 ↗
27. Variation of lattice dimensions in epitaxial SnS films on MgO (001)10.1016/j.jssc.2004.11.031 ↗
28. Preparation and properties of zinc blende and orthorhombic SnS films by chemical bath deposition10.1016/j.apsusc.2011.02.116 ↗
29. Influence of the deposition parameters on the properties of orthorhombic SnS films by chemical bath deposition10.1016/j.tsf.2011.12.077 ↗
30. Effect of tri-sodium citrate concentration on structural, optical and electrical properties of chemically deposited tin sulfide films10.1016/j.apsusc.2014.04.128 ↗
31. Effect of precursor concentration and bath temperature on the growth of chemical bath deposited tin sulphide thin films10.1016/j.apsusc.2011.10.124 ↗
32. Structure and optical properties of SnS thin film prepared by pulse electrodeposition10.1016/j.jallcom.2008.01.047 ↗
33. Characterization of electrical properties and photosensitivity of SnS thin films prepared by the electrochemical deposition method10.1016/j.solmat.2004.04.014 ↗
34. Fabrication of vacuum-evaporated SnS/CdS heterojunction for PV applications10.1016/j.solmat.2008.03.016 ↗
35. Preparation of SnS films with zinc blende structure by successive ionic layer adsorption and reaction method10.1016/j.matlet.2010.07.002 ↗
36. Investigations on SnS films deposited by spray pyrolysis10.1016/S0925-3467(01)00052-0 ↗
37. Optimization of parameters of chemical spray pyrolysis technique to get n and p-type layers of SnS10.1016/j.tsf.2010.01.040 ↗
38. Deposition of tin(II) sulfide thin films by ultrasonic spray pyrolysis: Evidence of sulfur exo-diffusion10.1016/j.mssp.2013.08.004 ↗
39. Atomic Layer Deposition of Tin Monosulfide Thin Films10.1002/aenm.201100330 ↗
40. Tin Monosulfide Thin Films Grown by Atomic Layer Deposition Using Tin 2, 4-Pentanedionate and Hydrogen Sulfide
41. New directions in tin sulfide materials chemistry10.1039/a709054d ↗
42. Chemical deposition of TIN (II) sulphide films10.1016/0040-6090(89)90536-1 ↗
43. Fabrication of SnS2/SnS heterojunction thin film diodes by plasma-enhanced chemical vapor deposition
44. Photovoltaic properties of SnS based solar cells10.1016/j.solmat.2006.06.012 ↗
45. Fabrication and optical properties of SnS thin films by SILAR method10.1016/j.apsusc.2008.04.008 ↗
46. Assessment of the potential of tin sulphide thin films prepared by sulphurization of metallic precursors as cell absorbers10.1016/j.tsf.2011.01.393 ↗
47. Tin sulfide thin films and Mo/p-SnS/n-CdS/ZnO heterojunctions for photovoltaic applications10.1016/j.tsf.2012.04.030 ↗
48. Direct Synthesis of Single-Phase p-Type SnS by Electrodeposition from a Dicyanamide Ionic Liquid at High Temperature for Thin Film Solar Cells10.1021/jp311552g ↗
49. SnS thin film solar cells with Zn1−xMgxO buffer layers10.1063/1.4804603 ↗
50. Enhancing the efficiency of SnS solar cells via band-offset engineering with a zinc oxysulfide buffer layer10.1063/1.4789855 ↗
51. Co-optimization of SnS absorber and Zn(O,S) buffer materials for improved solar cells10.1002/pip.2504 ↗
52. Making Record-efficiency SnS Solar Cells by Thermal Evaporation and Atomic Layer Deposition
53. Schneikart, A. (2014). Herstellung und Charakterisierung von SnS-Dünnschichtsolarzellen. [Ph.D. Thesis, Technische Universitat Darmstadt]. (In German).
54. Characterization of vacuum-evaporated tin sulfide film for solar cell materials10.1016/0927-0248(94)90158-9 ↗
55. Infrared and Raman spectra of the IV-VI compounds SnS and SnSe10.1103/PhysRevB.15.2177 ↗
56. Development of sulphurized SnS thin film solar cells10.1016/j.cap.2015.01.022 ↗
57. Mare, S.D., Salavei, A., Piccinelli, F., and Romeo, A. (2015, January 14–18). Analysis of SnS Growth and Post Deposition Treatment by Congruent Physical Vapor Deposition. Proceedings of 31st European Photovoltaic Solar Energy Conference and Exhibition—EU PVSEC 2015, Hamburg, Germany.