Corrosion of Anodized Titanium Alloys
Source abstract
Abstract
Ti and Ti alloys are employed in demanding industries such as aerospace, automotive, biomedical, aeronautic, structural, naval, and chemical, thanks to their resistance to corrosion due to the formation of the TiO2 film on the surface. Diverse research has established that different corrosive media could attack the oxide layer. One way to generate a stable, compact, and continuous oxide film is through anodizing treatment. The efficiency of anodization depends on diverse factors such as the microstructure, chemical composition of alloys, pH of electrolyte, time, and temperature of anodizing. This review aims to examine the corrosion resistance of the anodized layer on Ti and Ti alloys, with different parameters. The discussion is centered on the influence of the different parameters and alloy properties in the effectivity of anodizing when they are characterized by electrochemical techniques while studying the behavior of oxide.
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Research context
OpenAlex topics: Corrosion Behavior and Inhibition · Anodic Oxide Films and Nanostructures · Hydrogen embrittlement and corrosion behaviors in metals
SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.
Affiliations
Instituto de Ingeniería y Tecnología, Universidad Autónoma de Ciudad Juárez, Ciudad Juárez 66455, Mexico
Universidad Autónoma de Nuevo León, FIME, Centro de Investigación e Innovación en Ingeniería Aeronáutica (CIIIA), San Nicolás de los Garza 66455, Mexico
Facultad de Ingeniería Civil, Universidad Veracruzana, Xalapa 91000, Mexico
Facultad de Ingeniería Civil, Universidad Autónoma de Coahuila, Torreón 27276, Mexico
Funding
Universidad Autónoma de Nuevo León (UANL)
References (100+)
Show source-provided references
1. Sam Froes, F.H., Qian, M., and Niinomi, M. (2019). An Introduction to Titanium in Consumer Applications. Titanium for Consumer Applications, Elsevier.10.1016/B978-0-12-815820-3.00001-0 ↗
2. Sha, W., and Malinov, S. (2009). Titanium Alloys: Modelling of Microstructure, Properties and Applications, Elsevier Ltd.10.1533/9781845695866 ↗
3. Gialanella, S., and Malandruccolo, A. (2020). Aerospace Alloys. Topics in Mining, Metallurgy and Materials Engineering, Springer International Publishing.10.1007/978-3-030-24440-8 ↗
4. Mouritz, A.P. (2012). Introduction to Aerospace Materials, Elsevier Inc.10.2514/4.869198 ↗
5. Leyens, C., and Peters, M. (2003). Titanium and Titanium Alloys, Wiley. [1st ed.].10.1002/3527602119 ↗
6. Jáquez-Muñoz, J.M., Gaona-Tiburcio, C., Cabral-Miramontes, J., Nieves-Mendoza, D., Maldonado-Bandala, E., Olguín-Coca, J., López-Léon, L.D., De Los Rios, J.P.F., and Almeraya-Calderón, F. (2021). Electrochemical Noise Analysis of the Corrosion of Titanium Alloys in NaCl and H2SO4 Solutions. Metals, 11.10.3390/met11010105 ↗
7. Preparation and Characterization of Porous Bioceramic Layers on Pure Titanium Surfaces Obtained by Micro-Arc Oxidation Process10.1007/s00339-017-0765-0 ↗
8. Machining Titanium and Its Alloys10.1080/10940349908945686 ↗
9. The Thermomechanical Processing of Alpha/Beta Titanium Alloys10.1007/BF02914711 ↗
10. A Study of the Potentials Achieved during Mechanical Abrasion and the Repassivation Rate of Titanium and Ti6Al4V in Inorganic Buffer Solutions and Bovine Serum10.1016/j.electacta.2004.07.024 ↗
11. Surface Damage of Dental Implant Systems and Ions Release after Exposure to Fluoride and Hydrogen Peroxide10.1111/jre.12603 ↗
12. Investigation of Electrochemical Corrosion Behavior of Additive Manufactured Ti–6Al–4V Alloy for Medical Implants in Different Electrolytes10.1016/j.jallcom.2020.154620 ↗
13. Is There Scientific Evidence Favoring the Substitution of Commercially Pure Titanium with Titanium Alloys for the Manufacture of Dental Implants?10.1016/j.msec.2016.10.025 ↗
14. Study of the Tribocorrosion Occurring at the Implant and Implant Alloy Interface: Dental Implant Materials10.1016/j.matpr.2020.08.550 ↗
15. Synergistic Interactions between Corrosion and Wear at Titanium-Based Dental Implant Connections: A Scoping Review10.1111/jre.12469 ↗
16. Dini, C., Costa, R.C., Sukotjo, C., Takoudis, C.G., Mathew, M.T., and Barão, V.A.R. (2020). Progression of Bio-Tribocorrosion in Implant Dentistry. Front. Mech. Eng., 6.10.3389/fmech.2020.00001 ↗
17. Alloying and Impurity Effects in Vanadium-Base Alloys10.1016/0022-3115(86)90152-2 ↗
18. Effect of Vanadium on the Microstructures and Mechanical Properties of an Al–Mg–Si–Cu–Cr–Ti Alloy of 6XXX Series10.1016/j.jallcom.2013.03.239 ↗
19. Effects of Titanium Concentration on Microstructure and Mechanical Properties of High-Purity Vanadium Alloys10.1016/j.matdes.2022.111390 ↗
20. Effects of Vanadium and Titanium on Mechanical Properties of Low Carbon as Cast Microalloyed Steels10.1179/136404606X163505 ↗
21. Corrosion of Titanium and Its Alloys in Sulfuric Acid in the Presence of Chlorides10.1149/1.2126580 ↗
22. Characterisation of Passive Film and Corrosion Behaviour of a New Ti-Ta-Zr Alloy in Artificial Oral Media: In Time Influence of pH and Fluoride Ion Content10.1002/maco.201408025 ↗
23. Classification and Applications of Titanium and Its Alloys10.1016/j.matpr.2022.01.008 ↗
24. Effect of Heat-Treatment on Microstructure and Mechanical Properties of Ti Alloys: An Overview10.1016/j.matpr.2020.02.541 ↗
25. Tendero Lozano, I. (2018). Desarrollo de Aleaciones de Titanio-Manganeso Pulvimetalúrgicas Para Aplicaciones Biomédicas, Universitat Politècnica de València.
26. Loureiro Properties and Applications of Titanium Alloys: A Brief Review
27. Lütjering, G., and Williams, J.C. (2007). Titanium, Springer. Engineering Materials, Processes.
28. Influence of Varied Process Parameters on the Microstructure, Densification and Microhardness of Spark Plasma Sintered Ti-6Al-4V/h-BN Binary Composite10.1088/1757-899X/689/1/012005 ↗
29. Titanium and Its Alloy
30. Donachie, M.J. (2000). Titanium—A Technical Guide, ASM International.10.31399/asm.tb.ttg2.9781627082693 ↗
31. Electrochemical Corrosion of Titanium and Titanium-Based Alloys10.1067/mpr.2001.113029 ↗
32. Reclamation of Titanium Alloy Based Aerospace Parts Using Laser Based Metal Deposition Methodology10.1016/j.matpr.2021.01.354 ↗
33. Peel, C.J., and Gregson, P.J. (1995). Design Requirements for Aerospace Structural Materials. High Performance Materials in Aerospace, Springer.10.1007/978-94-011-0685-6_1 ↗
34. Aerospace Materials and Manufacturing Processes at the Millennium
35. Dutta Majumdar, J., and Manna, I. (2015). Laser Surface Engineering of Titanium and Its Alloys for Improved Wear, Corrosion and High-Temperature Oxidation Resistance. Laser Surface Engineering: Processes and Applications, Woodhead Publishing.10.1016/B978-1-78242-074-3.00021-0 ↗
36. Perspectives on Titanium Science and Technology10.1016/j.actamat.2012.10.043 ↗
37. Sankaran, K.K., and Mishra, R.S. (2017). Metallurgy and Design of Alloys with Hierarchical Microstructures, Elsevier Inc.
38. Promoting the Columnar to Equiaxed Transition and Grain Refinement of Titanium Alloys during Additive Manufacturing10.1016/j.actamat.2019.02.020 ↗
39. Kolli, R.P., and Devaraj, A. (2018). A Review of Metastable Beta Titanium Alloys. Metals, 8.10.3390/met8070506 ↗
40. Intensive Forming of Grade 5 Titanium Bars with Increased Performance for Aerospace Applications10.1016/j.promfg.2020.04.229 ↗
41. High Strength Heat-Treatable β-Titanium Alloy for Additive Manufacturing10.1016/j.msea.2020.139646 ↗
42. Corrosion Behavior of Titanium Alloys in Acidic and Saline Media: Role of Alloy Design, Passivation Integrity, and Electrolyte Modification10.1515/corrrev-2019-0029 ↗
43. Jáquez-Muñoz, J.M., Gaona-Tiburcio, C., Méndez-Ramírez, C.T., Baltazar-Zamora, M.Á., Estupinán-López, F., Bautista-Margulis, R.G., Cuevas-Rodríguez, J., Flores-De los Rios, J.P., and Almeraya-Calderón, F. (2023). Corrosion of Titanium Alloys Anodized Using Electrochemical Techniques. Metals, 13.10.3390/met13030476 ↗
44. Surface Analysis and Corrosion Resistance of a New Titanium Base Alloy in Simulated Body Fluids10.1016/j.corsci.2012.08.042 ↗
45. Deformation Mechanisms and Biocompatibility of the Superelastic Ti–23Nb–0.7Ta–2Zr–0.5N Alloy10.1007/s40830-016-0057-0 ↗
46. Microstructure, Surface Characterization, and Electrochemical Behavior of New Ti-Zr-Ta-Ag Alloy in Simulated Human Electrolyte10.1007/s11661-016-3774-2 ↗
47. Nanoprecipitation in a Beta-Titanium Alloy10.1016/j.jallcom.2014.10.038 ↗
48. Wandelt, K. (2018). Encyclopedia of Interfacial Chemistry, Elsevier.
49. Brandoli, B., de Geus, A.R., Souza, J.R., Spadon, G., Soares, A., Rodrigues, J.F., Komorowski, J., and Matwin, S. (2021). Aircraft Fuselage Corrosion Detection Using Artificial Intelligence. Sensors, 21.10.3390/s21124026 ↗
50. Microstructural Evolution in a Superelastic Metastable Beta-Ti Alloy10.1016/j.scriptamat.2016.09.035 ↗
51. Bocchetta, P., Chen, L.Y., Tardelli, J.D.C., Dos Reis, A.C., Almeraya-Calderón, F., and Leo, P. (2021). Passive Layers and Corrosion Resistance of Biomedical Ti-6Al-4V and β-Ti Alloys. Coatings, 11.10.3390/coatings11050487 ↗
52. Schweitzer, P.E. (2005). Paint and Coatings, CRC Press.10.1201/9781420027211 ↗
53. Schweitzer, P.E.P.A. (2018). Corrosion Engineering Handbook—3 Volume Set, CRC Press.10.1201/NOF0849396472 ↗
54. Revie, R.W., and Uhlig, H.H. (2008). Corrosion and Corrosion Control: An Introduction to Corrosion Science and Engineering, John Wiley and Sons. [4th ed.].10.1002/9780470277270 ↗
55. Dissolved Metal Species Mechanism for Initiation of Crevice Corrosion of Aluminum: II10.1149/1.2119875 ↗
56. Rashidi, N., Alavi-Soltani, S.R., and Asmatulu, R. (2007). Crevice Corrosion Theory, Mechanisms and Prevention Methods, Wichita State University, Graduate School.
57. Corrosion Mechanisms in Titanium Oxide-Based Films Produced by Anodic Treatment10.1016/j.electacta.2017.03.011 ↗
58. Titanium Corrosion Mechanisms in the Oral Environment: A Retrieval Study10.3390/ma6115258 ↗
59. Corrosion of Titanium Biomaterials, Mechanisms, Effects and Modelisation10.1515/corrrev.2008.1 ↗
60. Atlas D-Equilibres Electrochimiques10.1149/1.2426051 ↗
61. Demo, J., and Friedersdorf, F. (2015, January 8). Aircraft Corrosion Monitoring and Data Visualization Techniques for Condition Based Maintenance. Proceedings of the 2015 IEEE Aerospace Conference, Big Sky, MT, USA.10.1109/AERO.2015.7119048 ↗
62. Schenk, R. (2001). The Corrosion Properties of Titanium and Titanium Alloys, Springer.10.1007/978-3-642-56486-4_6 ↗
63. In Vivo Severe Corrosion and Hydrogen Embrittlement of Retrieved Modular Body Titanium Alloy Hip-Implants10.1002/jbm.b.31171 ↗
64. Incorporation of Ca and P on Anodized Titanium Surface: Effect of High Current Density10.1016/j.msec.2014.01.006 ↗
65. An Overview of the Corrosion Aspect of Dental Implants (Titanium and Its Alloys)10.4103/0970-9290.49068 ↗
66. Crevice Corrosion: Review of Mechanisms, Modelling, and Mitigation10.1179/000705993799156299 ↗
67. Makhlouf, A.S.H., and Botello, M.A. (2018). Failure of the Metallic Structures Due to Microbiologically Induced Corrosion and the Techniques for Protection. Handbook of Materials Failure Analysis, Butterworth-Heinemann.10.1016/B978-0-08-101928-3.00001-X ↗
68. Strehblow, H.H., and Marcus, P. (2011). Mechanisms of Pitting Corrosion. Corrosion Mechanisms in Theory and Practice, CRC Press. [3rd ed.].
69. The Anodic Oxide Film on Iron in Neutral Solution10.1016/0013-4686(71)85146-0 ↗
70. A Theory for Breakdown of Anodic Oxide Films on Metals10.1016/0013-4686(71)85079-X ↗
71. 1-Pitting Corrosion10.1016/B978-0-12-633670-2.50006-1 ↗
72. Passivity Breakdown, Pit Initiation and Propagation of Pits in Metallic Materials—Review10.1016/j.corsci.2014.10.006 ↗
73. Pitting Corrosion of Metals: A Review of the Critical Factors10.1149/1.1838615 ↗
74. The Localized Breakdown and Repair of Passive Surfaces during Pitting10.1016/0010-938X(89)90038-3 ↗
75. A Point Defect Model for Anodic Passive Films: III. Impedance Response10.1149/1.2124318 ↗
76. The Point Defect Model for the Passive State10.1149/1.2069096 ↗
77. Review of Mechanistic Analysis by Electrochemical Impedance Spectroscopy10.1016/0013-4686(90)80005-9 ↗
78. Monte-Carlo Simulation of Pitting Corrosion with a Deterministic Model for Repassivation10.1149/1945-7111/ab67a0 ↗
79. Preparation and Characterization of TiO2 Thin Films by Sol-Gel Method10.1023/A:1019912312654 ↗
80. Effect of Thermal Oxidation on Titanium Oxides’ Characteristics10.1080/17458080902769937 ↗
81. Nucleation and Growth in TiO2 Films Prepared by Sputtering and Evaporation10.1016/0040-6090(94)90843-5 ↗
82. Deposition of Thin TiO2 Layers on Platinum by Means of Cyclic Voltammetry of Selected Complex Ti(IV) Media Leading to Anatase10.1016/j.electacta.2009.02.036 ↗
83. Oxidation Mechanism of Biomedical Titanium Alloy Surface and Experiment10.1155/2020/1678615 ↗
84. Reactivity of Porous Titanium Oxide Film and Chitosan Layer Electrochemically Formed on Ti-6Al-4V Alloy in Biological Solution10.1016/j.surfcoat.2018.09.015 ↗
85. Li, Q., Zhang, Y., Cheng, Y., Zuo, X., Wang, Y., Yuan, X., and Huang, H. (2022). Effect of Temperature on the Corrosion Behavior and Corrosion Resistance of Copper–Aluminum Laminated Composite Plate. Materials, 15.10.3390/ma15041621 ↗
86. Galvanic Corrosion of Titanium Coupled to Welded Titanium in LiBr Solutions at Different Temperatures10.1016/j.corsci.2009.02.023 ↗
87. Corrosion Behavior and Surface Characterization of Titanium in Solution Containing Fluoride and Albumin10.1016/j.biomaterials.2004.03.025 ↗
88. Almeraya-Calderon, F., Villegas-Tovar, M., Maldonado-Bandala, E., Lara-Banda, M., Baltazar-Zamora, M.A., Santiago-Hurtado, G., Nieves-Mendoza, D., Lopez-Leon, L.D., Jaquez-Muñoz, J.M., and Estupiñán-López, F. (2024). Use of Electrochemical Noise for the Study of Corrosion by Passivated CUSTOM 450 and AM 350 Stainless Steels. Metals, 14.10.3390/met14030341 ↗
89. Michalska-Domańska, M., Łazińska, M., Łukasiewicz, J., Mol, J.M.C., and Durejko, T. (2020). Self-Organized Anodic Oxides on Titanium Alloys Prepared from Glycol- and Glycerol-Based Electrolytes. Materials, 13.10.3390/ma13214743 ↗
90. Fresh or Aged: Short Time Anodization of Titanium to Understand the Influence of Electrolyte Aging on Titania Nanopores10.1016/j.jmst.2021.11.050 ↗
91. Local Drug Delivery to the Bone by Drug-Releasing Implants: Perspectives of Nano-Engineered Titania Nanotube Arrays10.4155/tde.12.66 ↗
92. Characterization of the Morphology, Structure and Wettability of Phase Dependent Lamellar and Nanotube Oxides on Anodized Ti-10Nb Alloy10.1016/j.apsusc.2018.04.079 ↗
93. Characterization and Photocatalytic Properties of Nanoporous Titanium Dioxide Layer Fabricated on Pure Titanium Substrates by the Anodic Oxidation Process10.1016/j.ceramint.2013.07.046 ↗
94. Montoya-Rangel, M., Garza-Montes-de-Oca, N., Gaona-Tiburcio, C., and Almeraya-Calderón, F. (2023). Corrosion mechanism of advanced high strength dual-phase steels by electrochemical noise analysis in chloride solutions. Mater. Today Commun., 35.10.1016/j.mtcomm.2023.105663 ↗
95. Porous Anodic Alumina: Fabrication, Characterization and Applications10.1016/S0040-6090(96)09440-0 ↗
96. Anion Incorporation and Migration during Barrier Film Formation on Aluminium10.1016/0010-938X(87)90121-1 ↗
97. The Behaviour of Second Phase Particles during Anodizing of Aluminium Alloys10.1016/j.corsci.2010.03.029 ↗
98. Modelling the Anodizing Behaviour of Aluminium Alloys in Sulphuric Acid through Alloy Analogues10.1016/j.corsci.2008.09.019 ↗
99. Martínez-Viademonte, M.P., Abrahami, S.T., Hack, T., Burchardt, M., and Terryn, H. (2020). A Review on Anodizing of Aerospace Aluminum Alloys for Corrosion Protection. Coatings, 10.10.3390/coatings10111106 ↗
100. Anodic Growth of Titanium Oxide: Electrochemical Behaviour and Morphological Evolution10.1016/j.electacta.2012.04.114 ↗