Corrosion Inhibition of Aluminum in Acidic Solution by Ilex paraguariensis (Yerba Mate) Extract as a Green Inhibitor
Source abstract
Abstract
In the present work, the inhibitory effect of Ilex paraguariensis (Yerba Mate) extract on the corrosion of aluminum in 0.1 M HCl solution, in the temperature range of 298–323 K, was studied by using weight loss tests, potentiodynamic polarization measurements and electrochemical impedance spectroscopy (EIS). The extract of Ilex paraguariensis exhibits improved inhibitory action as its concentration increases while its performance is maintained despite an increase in temperature. EIS theoretical data according to a suitable proposed equivalent circuit were successfully fitted to the experimental data. The adsorption of organic compounds followed a modified Langmuir isotherm behaviour. Derived thermodynamic parameters indicate the occurrence of both chemical and physical adsorption.
Source: crossref · Quality: baseline
Research context
OpenAlex topics: Corrosion Behavior and Inhibition · Electrochemical Analysis and Applications · Metal Extraction and Bioleaching
SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.
Affiliations
Programa de Materiales y Fisicoquímica, Facultad de Ciencias Exactas, Químicas y Naturales, Universidad Nacional de Misiones, Félix de Azara 1552, Posadas 3300, Argentina
Instituto de Materiales de Misiones—Consejo Nacional de Investigaciones Científicas y Técnicas, Facultad de Ciencias Exactas, Químicas y Naturales, Universidad Nacional de Misiones, Félix de Azara 1552, Posadas 3300, Argentina
Instituto de Investigaciones Fisicoquímicas Teóricas y Aplicadas—Consejo Nacional de Investigaciones Científicas y Técnicas, Facultad de Ciencias Exactas, Universidad Nacional de La Plata, Diagonal 113 y 64 S/N, La Plata 1900, Argentina
Area Electroquímica, Facultad de Ingeniería, Universidad Nacional de La Plata, Av. 1 750, La Plata 1900, Argentina
Funding
Consejo Nacional de Investigaciones Científicas y Técnicas (CONICET) · Agencia Nacional de Promoción Científica y Tecnológica
References (55)
Show source-provided references
1. The substituted 1,3,4-oxadiazoles: A new class of corrosion inhibitors of mild steel in acidic media10.1016/S0010-938X(99)00049-9 ↗
2. The inhibition of mild steel corrosion in phosphoric acid solutions by some N-heterocyclic compounds in the salt form10.1016/j.corsci.2004.05.026 ↗
3. Investigation of the inhibitive effect of substituted oxadiazoles on the corrosion of mild steel in Cl medium10.1016/S0010-938X(00)00076-7 ↗
4. Lathanide compounds as environmentally friendly corrosion inhibitors of aluminium alloys—A review10.1016/S0010-938X(98)00077-8 ↗
5. Cerium: A suitable green corrosión inhibitor for tinplate10.1016/S0010-938X(01)00053-1 ↗
6. Copper corrosion inhibition by fast green, fuchsin acid and basic compounds in citric acid solution10.1002/maco.200390050 ↗
7. Fostering green inhibitors for corrosion prevention10.1007/978-94-017-7540-3_6 ↗
8. Sharmin, E., Ahmad, S., Zafar, F., and Islamia, J.M. (2012). Corrosion Resistance, InTech. [1st ed.].
9. Tryptamine as a green iron corrosion inhibitor in 0.5 M deaerated sulphuric acid10.1016/S0010-938X(03)00150-1 ↗
10. Adsorption behavior of caffeine as a green corrosion inhibitor for copper
11. Natural products as corrosion inhibitor for metals in corrosive media—A review10.1016/j.matlet.2007.04.079 ↗
12. Green Corrosion Inhibitors: An Overview of Recent Research
13. Rollinia occidentalis extract as green corrosion inhibitor for carbon steel in HCl solution10.1016/j.jiec.2017.09.012 ↗
14. Inhibition of Cor-Ten steel corrosion by “green” extracts of Brassica campestris10.1016/j.corsci.2018.02.059 ↗
15. Musa paradisica peel extract as green corrosion inhibitor for mild steel in HCl solution10.1016/j.corsci.2014.10.002 ↗
16. Unravelling the mechanisms of corrosion inhibition of iron by henna extract: A density functional theory study10.1016/j.corsci.2018.07.011 ↗
17. Corrosion Inhibition of Aluminum in Hydrochloric Acid Medium by Essential Oil of Eucalyptus camaldulensis and Myrtus Communis
18. Corrosion Inhibitive Behaviour of Camellia Sinensis on Aluminium Alloy in H2SO410.1016/S1452-3981(23)07790-8 ↗
19. Corrosion Inhibition of Aluminium in Acidic Media by Different Extracts of Trigonellafoenum-graecum L Seeds10.4152/pea.201705279 ↗
20. Pectin as promising green corrosion inhibitor of aluminum in hydrochloric acid solution Mohammad10.1016/j.corsci.2012.04.002 ↗
21. Artemisia Herba Alba Essential Oil as Green Corrosion Inhibitor for Aluminum in Hydrochloric Acid Solution
22. Evaluation of Dryopteris cochleata leaf extracts as green inhibitor for corrosion of aluminium in 1 M H2SO4, Egypt
23. Shatavari (Asparagus Racemosus) as Green Corrosion Inhibitor of Aluminium in Acidic Medium10.4152/pea.201902083 ↗
24. A Green Approach to Corrosion Inhibition of Aluminium in Acid Medium Using Azwain Seed Extract10.1016/j.matpr.2017.05.026 ↗
25. Synergistic and Antagonistic Effects of Anions and Ipomoea invulcrata as Green Corrosion Inhibitor for Aluminium Dissolution in Acidic Medium10.1016/S1452-3981(23)15338-7 ↗
26. Green Inhibitor for Corrosion of Aluminium Alloy AA8011A in Acidic Environment
27. Application of Natural Product Extracts as Green Corrosion Inhibitors for Metals and Alloys in Acid Pickling Processes—A review10.1016/S1452-3981(23)06707-X ↗
28. Chemical Composition and Antioxidant Activity of Yerba-Mate (Ilex paraguariensis A.St.-Hil., Aquifoliaceae) Extract as Obtained by Spray Drying10.1021/jf2008343 ↗
29. Effects of Spray Drying Conditions on the Stability and Antioxidant Properties of Spray-Dried Soluble Mate10.1515/ijfe-2012-0124 ↗
30. High-Performance Capillary Electrophoresis Analysis of mate infusions prepared from stems and leaves of Ilex paraguariensis using Automated Micellar Electrokinetic Capillary Chromatography10.1002/pca.647 ↗
31. Yerba Mate Tea (Ilex paraguariensis): A Comprehensive Review on Chemistry, Health Implications, and Technological Considerations
32. The mechanism of corrosion inhibition of iron in acid solution by acetylenic alcohols10.1149/1.2085956 ↗
33. Corrosion inhibition of mild steel in acidic solution by Tagetes erecta (Marigold flower) extract as a green inhibitor10.1016/j.corsci.2014.04.036 ↗
34. Inhibitory Action of Ilex paraguariensis Extracts on the Corrosion of Carbon Steel in HCl Solution10.1016/S1452-3981(23)04972-6 ↗
35. Caffeic acid as a green corrosion inhibitor for mild steel10.1016/j.corsci.2008.12.013 ↗
36. Essential oil of Salvia aucheri mesatlantica as a green inhibitor for the corrosion of steel in 0.5 M H2SO410.1016/j.arabjc.2010.09.017 ↗
37. Thermodynamic study of metal corrosion and inhibitor adsorption processes in mild steel/1-methyl-4[4 (-X)-styryl pyridinium iodides/hydrochloric acid systems10.1016/j.matchemphys.2008.01.028 ↗
38. Green approach to corrosion inhibition of 304 stainless steel in hydrochloric acid solution by the extract of Salvia officinalis leaves10.1016/j.corsci.2012.05.003 ↗
39. The study of aluminium corrosion in acidic solution with nontoxic inhibitors10.1023/A:1014265407060 ↗
40. Factors affecting the corrosion behaviour of aluminium in acid solutions. I. Nitrogen and/or sulphur-containing organic compounds as corrosion inhibitors for Al in HCl solutions10.1016/j.corsci.2012.03.021 ↗
41. The application of electrochemical impedance techniques to aluminium corrosion in acidic chloride solution10.1007/BF01019579 ↗
42. Use of impedance measurements for the determination of the instant rate of metal corrosion10.1007/BF00615194 ↗
43. Interpretation of Faradaic Impedance for Corrosion Monitoring
44. Inhibition by Ginkgo leaves extract of the corrosion of steel in HCl and H2SO4 solutions10.1016/j.corsci.2011.11.005 ↗
45. Inhibitive Action of Anethum graveolens L. oil on Aluminium Corrosion in Acidic Media10.1016/S1452-3981(23)17999-5 ↗
46. Corrosion inhibition of carbon steel in hydrochloric acid solution by fruit peel aqueous extracts10.1016/j.corsci.2010.03.033 ↗
47. On electrochemical techniques for interface inhibitor research10.1016/S0010-938X(96)00034-0 ↗
48. The inhibition of low carbon steel corrosion in hydrochloric acid solutions by succinic acid. Part I. Weight loss, polarization, EIS, PZC, EDX and SEM studies10.1016/j.electacta.2006.10.019 ↗
49. Inhibition of Aluminium Corrosion in 1.0 M HCl by Caffeine: Experimental and DFT Studies10.1155/2017/6975248 ↗
50. Application of some ferrocene derivatives in the field of corrosion inhibition10.1016/j.corsci.2007.09.002 ↗
51. Effect of sodiumdodecylsulfate on copper corrosion in sulfuric acid media in the absence and presence of benzotriazole10.1016/S0022-0728(99)00267-3 ↗
52. Kinetic-Thermodynamic and Adsorption Isotherms Analyses for the Inhibition of the Acid Corrosion of Steel by Cyclic and Open-Chain Amines10.1149/1.2221193 ↗
53. Inhibition by Jasminum nudiflorum Lindl. leaves extract of the corrosión of aluminium in HCl solution10.1016/j.corsci.2012.07.017 ↗
54. Potential of aqueous extract of Hibiscus sabdariffa leaves for inhibiting the corrosion of aluminum in alkaline solutions10.1007/s10800-009-9826-1 ↗
55. Coconut coir dust extract: A novel eco-friendly corrosion inhibitor for Al in HCl solutions10.1080/17518253.2011.625980 ↗