journal article·2022-05-08Open access

Mechanical Performances of Phenolic Modified Epoxy Resins at Room and High Temperatures

Yixin Zhao, Rui Xu, Yao Xiao, Hailou Wang, Wei Zhang, Guangyu Zhang

Coatings· Volume 12· Issue 5

Abstract

Epoxy is an important resin matrix and has been widely applied in laminated composites as a coating or adhesive material. In this article, the phenolic was applied to modify the mechanical properties of epoxy resin. The phenolic modified epoxy resins with various phenolic content were prepared via a polytetrafluoroethylene mould, and the phenolic modified epoxy-based plain woven laminated composites (PWLCs) were manufactured via vacuum assisted resin transfer method for further study of phenolic modified epoxy resins’ mechanical properties. The compression tests were performed perpendicularly to thickness at 2 mm/min to investigate the mechanical performances of phenolic modified epoxy resins and epoxy-based PWLCs. The results showed that the addition of phenolic into epoxy could improve the mechanical performances of epoxy resins and epoxy-based composites at room temperature, and the phenolic influenced epoxy-based PWLC more than epoxy matrix at room temperature. However, at high temperatures, the addition of phenolic decreased the mechanical performances of epoxy resins and epoxy-based composites, and the adverse effect of phenolic became more serious with the increase of phenolic content at high temperature. In addition, the thermogravimetric analyses were also conducted from 30 °C to 800 °C on phenolic modified epoxy resins and the results showed that the phenolic modified epoxy resin had an earlier loss in weight than unmodified epoxy resin. The earlier loss in weight meant that the addition of phenolic into epoxy resin led to the formation of unstable molecules at high temperature.
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Research context

OpenAlex topics: Epoxy Resin Curing Processes · Mechanical Behavior of Composites · Polymer composites and self-healing

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

Affiliations

School of Textile and Clothing, Nantong University, Nantong 226019, China

National and Local Joint Engineering Research Center of Technical Fiber Composites for Safety and Protection, Nantong University, Nantong 226019, China

Funding

National Natural Science Foundation of China · Major Program of Basic Science (Natural Science) of Higher Education of Jiangsu Province · Jiangsu University “Qinglan Project” · Advanced Textile Engineering Technology Center of Jiangsu Province · National College Students’ Innovation and Entrepreneurship Training Program · Research Innovation Program for College Graduates of Jiangsu Province

References (30)

Show source-provided references
1. Hussian Siyal, S., Jogi, S.A., Muhammadi, S., Laghari, Z.A., Khichi, S.A., Naseem, K., Algarni, T.S., Alothman, A., Hussain, S., and Javed, M.S. (2021). Mechanical Characteristics and Adhesion of Glass-Kevlar Hybrid Composites by Applying Different Ratios of Epoxy in Lamination. Coatings, 11.10.3390/coatings11010094 ↗
2. Zhou, H., Liu, H.-Y., Fu, K., Yuan, H., Du, X., and Mai, Y.-W. (2019). Numerical Simulation of Failure of Composite Coatings due to Thermal and Hygroscopic Stresses. Coatings, 9.10.3390/coatings9040243 ↗
3. Synthesis and application of epoxy resins: A review10.1016/j.jiec.2015.03.026 ↗
4. Experimental investigation of fiber orientation effect on mechanical and erosive wear performance of TiO2 filled woven jute fiber based epoxy composites10.1016/j.matpr.2020.12.660 ↗
5. Thermoplastic-epoxy interactions and their potential applications in joining composite structures—A review10.1016/j.compositesa.2014.09.027 ↗
6. Kumar, S., Prasad, L., Patel, V.K., Kumar, V., Kumar, A., Yadav, A., and Winczek, J. (2021). Physical and Mechanical Properties of Natural Leaf Fiber-Reinforced Epoxy Polyester Composites. Polymers, 13.10.3390/polym13091369 ↗
7. Recent advances in the study of structure and properties of fiber composites with an epoxy matrix10.1007/s10965-021-02783-9 ↗
8. Critical transition of epoxy resin from brittleness to toughness by incorporating CO2-sourced cyclic carbonate10.1016/j.jcou.2018.05.020 ↗
9. Curing process optimization and mechanical properties improvement of epoxy resin copolymer modified by epoxy-terminated hyperbranched polyether sulfone10.1016/j.polymer.2022.124535 ↗
10. Kim, T.H., Kim, M., Lee, W., Kim, H.-G., Lim, C.-S., and Seo, B. (2019). Synthesis and Characterization of a Polyurethane Phase Separated to Nano Size in an Epoxy Polymer. Coatings, 9.10.3390/coatings9050319 ↗
11. Yung, T.-Y., Lu, Y.-C., Chen, J.-S., Cheng, Y.-W., Liu, T.-Y., and Chen, P.-T. (2021). Reinforcement of Epoxy Resin by Additives of Amine-Functionalized Graphene Nanosheets. Coatings, 11.10.3390/coatings11010035 ↗
12. Study on thermal degradation mechanism of heat-resistant epoxy resin modified with carboranes10.1016/j.polymdegradstab.2020.109143 ↗
13. Kim, M., Kim, S., Kim, T., Lee, D.K., Seo, B., and Lim, C.-S. (2017). Mechanical and Thermal Properties of Epoxy Composites Containing Zirconium Oxide Impregnated Halloysite Nanotubes. Coatings, 7.10.3390/coatings7120231 ↗
14. Study on polyblending epoxy resin adhesive with lignin I-curing temperature10.1016/j.ijadhadh.2013.09.003 ↗
15. Zeng, D., Liu, Z., Zou, L., and Wu, H. (2021). Corrosion Resistance of Epoxy Coatings Modified by Bis-Silane Prepolymer on Aluminum Alloy. Coatings, 11.10.3390/coatings11070842 ↗
16. Fastener effects on mechanical behaviors of double-lap composite joints10.1016/j.compstruct.2013.01.008 ↗
17. Composite Materials Manufacturing Processes10.4028/www.scientific.net/AMM.110-116.1361 ↗
18. A hierarchical multiscale model for the elastic-plastic damage behavior of 3D braided composites at high temperature10.1016/j.compscitech.2020.108230 ↗
19. Coupling effect of temperature and braided angle on compressive behaviors of 3D braided carbon-epoxy composite at low temperature10.1177/0021998316674065 ↗
20. Zuo, H.-m., Li, D.-s., and Jiang, L. (2019). High Temperature Mechanical Response and Failure Analysis of 3D Five-Directional Braided Composites with Different Braiding Angles. Materials, 12.10.3390/ma12213506 ↗
21. Experimental and multiscale modeling investigations of cryo-thermal cycling effects on the mechanical behaviors of carbon fiber reinforced epoxy composites10.1016/j.compositesb.2021.109534 ↗
22. Tensile failure model of carbon fibre in unidirectionally reinforced epoxy composites with mean-field homogenisation10.1016/j.compstruct.2021.114270 ↗
23. A review on mechanical properties of epoxy nanocomposites10.1016/j.matpr.2020.09.742 ↗
24. Enhancing cryogenic mechanical properties of epoxy resins toughened by biscitraconimide resin10.1016/j.compscitech.2021.109252 ↗
25. Molecular dynamics study on mechanical properties of helical graphenes/epoxy nanocomposites10.1016/j.commatsci.2022.111408 ↗
26. Improvement of structural, thermal and mechanical properties of epoxy composites and bonded joints exposed to water environment by incorporating boron nanoparticles10.1016/j.ijadhadh.2022.103141 ↗
27. Multifunctional AgO/epoxy nanocomposites with enhanced mechanical, anticorrosion and bactericidal properties10.1016/j.porgcoat.2020.106130 ↗
28. El Gazzani, S., Nassiet, V., Habas, J.-P., Freydier, C., and Hilleshein, A. (2016). High Temperature Epoxy Foam: Optimization of Process Parameters. Polymers, 8.10.3390/polym8060215 ↗
29. High strain rate compressive behaviors and adiabatic shear band localization of 3-D carbon/epoxy angle-interlock woven composites at different loading directions10.1016/j.compstruct.2018.12.037 ↗
30. Simulation of the mechanical properties of fibrous composites by the bridging micromechanics model10.1016/S1359-835X(00)00142-1 ↗