journal article·2023-04-08Open access

Comparison of the Mechanical Properties and Corrosion Resistance of the Cr-CrN, Ti-TiN, Zr-ZrN, and Mo-MoN Coatings

He Tao, Valery Zhylinski, Alexey Vereschaka, Vadzim Chayeuski, Huo Yuanming, Filipp Milovich, Catherine Sotova, Anton Seleznev, Olga Salychits

Coatings· Volume 13· Issue 4

Abstract

In this work, the mechanical properties and corrosion resistance of Cr-CrN, Ti-TiN, Zr-ZrN, and Mo-MoN coatings deposited by the physical vapor deposition (PVD) method on Ti-6Al-4V alloy were compared. The phase composition of the coatings, their hardness and fracture resistance in scratch tests were determined, and their structural characteristics were also studied using a scanning electron microscope (SEM) and a transmission electron microscope (TEM). The diffraction spectra were made using an automatic X-ray diffractometer. The value of the adhesive component of the friction coefficient fadh of the pair “coated and uncoated Ti-6Al-4V alloy” was investigated in the temperature range of 20–900 °C. The lowest value of fadh was detected for the Zr-ZrN coating at temperatures below 400 °C, while for the Mo-MoN coating it was observed at temperatures above 700 °C. The polarization curves of the coated and uncoated samples were performed in a 3% aqueous NaCl solution. The level of corrosion of the Ti-6Al-4V alloy samples with Cr-CrN, Ti-TiN, Zr-ZrN, and Mo-MoN coatings was evaluated using the Tafel extrapolation method, the iteration method, and the polarization resistance method. The results obtained with these methods indicate that the Zr-ZrN coated sample has the best corrosion resistance in the 3 wt.% NaCl solution, with a corrosion current density of 0.123 μA/cm2.
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Research context

OpenAlex topics: Metal and Thin Film Mechanics · Diamond and Carbon-based Materials Research · Advanced materials and composites

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

Affiliations

School of Mechanical and Automotive Engineering, Shanghai University of Engineering Science, No. 333 Longteng Road, Shanghai 201620, China

Department of Chemistry, Technology of Electrochemical Production and Electronic Engineering Materials, Chemical Technology and Engineering Faculty, Belarusian State Technological University, 13a, Sverdlov Street, 220006 Minsk, Belarus

Institute of Design and Technological Informatics of the Russian Academy of Sciences (IDTI RAS), Vadkovsky per. 18-1a, 127994 Moscow, Russia

Department of Physics, Faculty of Information Technology, Belarusian State Technological University, 13a, Sverdlov Street, 220006 Minsk, Belarus

Materials Science and Metallurgy Shared Use Research and Development Center, National University of Science and Technology MISiS, Leninsky Prospect 4, 119049 Moscow, Russia

Department of High-Efficiency Machining Technologies, Moscow State Technological University STANKIN, Vadkovsky per. 1, 127994 Moscow, Russia

Funding

National Natural Science Foundation of China · Natural Science Foundation of Shanghai · International cooperative scientific research platform of SUES

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