journal article·2023-04-15Open access

Structural Properties of Zn-Fe Alloy Coatings and Their Corrosion Resistance

Ramesh Sooryanarayana Bhat, Manjunatha Krishna Balakrishna, Poornesh Parthasarathy, Ampar Chitharanjan Hegde

Coatings· Volume 13· Issue 4

Abstract

Single-layer and multilayer alloy deposits were coated onto a mild steel substrate by a single-bath electroplating process. The developed coating consists of Zn and Fe alloys having different compositions with different layers. The anticorrosion behavior of single-layer and multilayer deposits was evaluated by the potentiodynamic polarization method. The surface morphology of the deposits was studied with a scanning electron microscope. The crystal structure of the deposits was analyzed with the X-ray diffraction technique. The Fe content in the deposit was analyzed by a colorimeter and verified with energy-dispersive X-ray spectroscopy. The micro-hardness tester with a Vickers indenter was used to evaluate the microhardness of the developed single-layer and multilayer coatings. It was found that the microhardness increased with applied current densities. The Zn-Fe multilayer coatings with 300 layers deposited with square and triangular pulses at the applied current density of 2.0/3.0 A dm−2 were five and four times more corrosion-resistant, respectively, than the single-layer coating of the same thickness. The development of Zn-Fe coatings that are resistant to corrosion is particularly important for the automotive industry and steel-based vehicle parts.
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Research context

OpenAlex topics: Electrodeposition and Electroless Coatings · Corrosion Behavior and Inhibition · Metal and Thin Film Mechanics

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

Affiliations

Department of Chemistry, NMAM Institute of Technology, NITTE (Deemed to be University), Nitte 574110, India

Department of Physics, NMAM Institute of Technology, NITTE (Deemed to be University), Nitte 574110, India

Nonlinear Optics Research Laboratory, Department of Physics, Manipal Institute of Technology, Manipal Academy of Higher Education, Manipal 576104, India

Electrochemistry Laboratory, Department of Chemistry, National Institute of Technology Karnataka, Srinivasnagar, Surathkal 575025, India

References (36)

Show source-provided references
1. Kanani, N. (2006). Electroplating: Basic Principles, Processes and Practice, Elsevier Ltd.
2. Zn-Ni compositionally modulated multilayered alloy coatings for improved corrosion resistance10.1080/02670844.2020.1812479 ↗
3. Hardness in Ag/Ni, Au/Ni and Cu/Ni multilayers10.1080/01418610108216650 ↗
4. Electrodeposition of single gamma phased Zn–Ni alloy coatings from the additive-free acidic bath10.1016/j.apsusc.2014.05.127 ↗
5. Optimization of deposition conditions for bright Zn-Fe coatings and its characterization10.1134/S2070205111050030 ↗
6. Morphology and properties of electrodeposited Zn-Ni alloy coatings on mild steel10.3329/jme.v40i1.3468 ↗
7. Fabrication of Zn-Ni alloy coatings from acid chloride bath and its corrosion performance
8. Influence of electrodeposition conditions on the microstructure and corrosion resistance of Zn-Ni alloy coatings from a deep eutectic solvent10.1016/j.surfcoat.2014.01.014 ↗
9. Research of the shielding effect and radiation resistance of composite CuBi2O4 films as well as their practical applications10.1007/s10854-020-03724-w ↗
10. Sharko, S.A., Serokurova, A.I., Novitskii, N.N., Ketsko, V.A., Smirnova, M.N., Almuqrin, A.H., Sayyed, M.I., Trukhanov, S.V., and Trukhanov, A.V. (2022). A new approach to the formation of nanosized gold and beryllium films by ion-beam sputtering deposition. Nanomaterials, 12.10.3390/nano12030470 ↗
11. Synthesis, structural, strength and corrosion properties of thin films of the type CuX (X = Bi, Mg, Ni)10.1007/s10854-019-01556-x ↗
12. Zubar, T.I., Usovich, T.I., Tishkevich, D.I., Kanafyev, O.D., Fedkin, V.A., Kotelnikova, A.N., Panasyuk, M.I., Kurochka, A.S., Nuriev, A.V., and Idris, A.M. (2022). Features of galvanostatic electrodeposition of NiFe films with composition gradient: Influence of substrate characteristics. Nanomaterials, 12.10.3390/nano12172926 ↗
13. Effects of deflection on bulge test measurements of enhanced modulus in multilayered films
14. Ni–P–W multilayered alloy coatings produced by pulse plating10.1016/S1359-6462(00)00446-2 ↗
15. Compositionally Modulated Multilayered Zn-Co Deposits for Better Corrosion Resistance10.1007/s11665-020-05137-6 ↗
16. Development of Nano-structured Zn-Ni Multilayers and their Corrosion Behaviors10.1080/15533174.2010.522881 ↗
17. Failure analysis of drill pipe: A review10.1016/j.engfailanal.2015.10.012 ↗
18. Oxidation behavior of Ru–Al multilayer coatings10.1016/j.apsusc.2017.02.096 ↗
19. The Development of Electrodeposited Multilayer Coatings: Fabrication, Microstructure, Properties and Applications10.1016/j.apsadv.2021.100141 ↗
20. The Continued Development of Multilayered and Compositionally Modulated Electrodeposits10.1080/00202967.2022.2094078 ↗
21. Electrochemical Characterisation of Porosity and Corrosion Resistance in Electrodeposited Metal Coatings10.1016/j.surfcoat.2008.05.008 ↗
22. Brenner, A. (1963). Electrodeposition of Alloys: Principles and Practice, Academic Press.10.1016/B978-1-4831-9807-1.50016-7 ↗
23. Composition modulated multilayer Zn–Fe alloy coatings on mild steel for better corrosion resistance10.1080/10426914.2010.501192 ↗
24. Electrodeposition of cyclic multi-layer Zn-Co films using square current pulses and investigations on their corrosion behaviors
25. Eliaz, N., and Gileadi, E. (2008). Modern Aspects of Electrochemistry, Springer.
26. Bhat, R.S. (2021). Liquid Metals, Open Tech.
27. Magnetic state of the structural separated anion-deficient La0.70Sr0.30MnO2.85 manganite10.1134/S1063776111130127 ↗
28. Kozlovskiy, A., Egizbek, K., Zdorovets, M.V., Ibragimova, M., Shumskaya, A., Rogachev, A.A., Ignatovich, Z.V., and Kadyrzhanov, K. (2020). Evaluation of the efficiency of detection and capture of manganese in aqueous solutions of FeCeOx nanocomposites doped with Nb2O5. Sensors, 20.10.3390/s20174851 ↗
29. Electroplating of Zn-Ni Alloy Coating on Mild Steel and Its Electrochemical Studies10.1007/s11665-021-06051-1 ↗
30. Development of compositionally modulated multilayer Zn–Ni deposits as replacement for cadmium10.1016/j.surfcoat.2007.03.033 ↗
31. Electrodeposition of Zn–Ni, Zn–Fe and Zn–Ni–Fe alloys10.1016/j.surfcoat.2010.08.102 ↗
32. Production of layer-by-layer Zn-Fe compositional multilayer alloy coatings using triangular current pulses for better corrosion protection10.1179/0020296715Z.000000000236 ↗
33. Surface modification by multi-layered Zn–Co alloy coatings10.1179/1743294411Y.0000000009 ↗
34. Surface modification with zinc and Zn-Ni alloy compositionally modulated multilayer coatings10.1016/S1006-706X(06)60080-0 ↗
35. Different approaches in evaluating organic paint coatings with electrochemical impedance spectroscopy10.1179/174329408X326524 ↗
36. Electrodeposition of zinc-nickel compositionally modulated multilayer coatings and their corrosion behaviors10.1016/j.surfcoat.2004.08.183 ↗