journal article·2021-05-27Open access

Biodegradable Chitosan Films with ZnO Nanoparticles Synthesized Using Food Industry By-Products—Production and Characterization

Victor Souza, Marta Alves, Catarina Santos, Isabel Ribeiro, Carolina Rodrigues, Isabel Coelhoso, Ana Fernando

Coatings· Volume 11· Issue 6

Abstract

This work aimed to produce bionanocomposites of chitosan incorporated with zinc oxide nanoparticles (ZnO NPs) synthesized using food industry by-products and to characterize them. Such nanoparticles are highlighted due to their low cost, antimicrobial activity, accessibility, and sustainability synthesis. Four different levels of ZnO NPs (0, 0.5, 1.0, and 2.0% w/w of chitosan) were tested, and the bionanocomposites were characterized in terms of their hydrophobicity, mechanical, optical, and barrier properties. Overall, the incorporation of ZnO NPs changed the composites from brittle to ductile, with enhanced elongation at break and reduced Young Modulus and tensile strength. Thus, ZnO NPs acted as plasticizer, turning the films more flexible, due to the presence of organic compounds on the NPs. This also favored permeability of oxygen and of water vapor, but the good barrier properties were maintained. Optical properties did not change statistically with the ZnO NPs incorporation. Thus, the characterization presented in this paper may contribute to support a decision on the choice of the material’s final application.
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Research context

OpenAlex topics: Nanocomposite Films for Food Packaging · Nanoparticles: synthesis and applications · Conducting polymers and applications

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

Affiliations

MEtRICs, Departamento de Ciências e Tecnologia da Biomassa, NOVA School of Science and Technology|FCT NOVA, Campus de Caparica, Universidade NOVA de Lisboa, 2829-516 Caparica, Portugal

CQE Centro de Química Estrutural, Instituto Superior Técnico, Universidade de Lisboa, Av. Rovisco Pais, 1049-001 Lisboa, Portugal

EST Setúbal, CDP2T, Instituto Politécnico de Setúbal, Campus IPS, 2910 Setúbal, Portugal

Research Institute for Medicines (iMed.ULisboa), Faculty of Pharmacy, Universidade de Lisboa, Avenida Prof. Gama Pinto, 1649-003 Lisboa, Portugal

LAQV-REQUIMTE, Departamento de Química, NOVA School of Science and Technology|FCT NOVA, Campus de Caparica, Universidade NOVA de Lisboa, 2829-516 Caparica, Portugal

Funding

Foundation for Science and Technology

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