Thin Benzotriazole Films for Inhibition of Carbon Steel Corrosion in Neutral Electrolytes
Source abstract
Abstract
This article investigates the modification of a carbon steel surface by benzotriazole (BTA), and the structure and properties of the formed layers. Adsorption was studied by surface analytical methods such as X-ray photoelectron spectroscopy (XPS) and reflecting infrared microscopy (FTIR). It has been established that a polymer-like film containing iron-azole complexes that are 2 nm thick and strongly bonded to the metal is formed on the surface as a result of the azole interacting with a steel surface. This film is capable to inhibit uniform and localized corrosion of steel in neutral aqueous electrolytes containing chloride ions. It is shown that the iron-azole layer located at the interface acts as a promotor of adhesion, increasing the interaction of polymeric coatings with the steel surface. Taking into account these properties, the steel pretreatments can be used for improving the anticorrosion properties of polymeric coatings applied for the protection of steel constructions.
Source: crossref · Quality: baseline
Research context
OpenAlex topics: Corrosion Behavior and Inhibition · Material Properties and Failure Mechanisms · Inorganic and Organometallic Chemistry
SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.
Affiliations
Frumkin Institute of Physical Chemistry and Electrochemistry of the Russian Academy of Sciences, 119991 Moscow, Russia
References (35)
Show source-provided references
1. McCafferty, E. (2010). Introduction to Corrosion Science, Springer.10.1007/978-1-4419-0455-3 ↗
2. Leygraf, C., Wallinder, I.O., Tidblad, J., and Graedel, T. (2016). Atmospheric Corrosion, John Wiley & Sons, Inc.. [2nd ed.].10.1002/9781118762134 ↗
3. Modelling and mapping of copper runoff for Europe10.1039/B612041E ↗
4. Anticorrosive coatings: A review10.1007/s11998-008-9144-2 ↗
5. Kutz, M. (2012). Corrosion Prevention and Control of Chemical Processing Equipment. Handbook of Environmental Degradation of Materials, William Andrew Publishing. [2nd ed.].
6. Octadecylamine, 1,2,3-benzotriazole and a mixture there of as chamber inhibitors of steel corrosion
7. Triazoles as a class of multifunctional corrosion inhibitors. A review. Part I. 1,2,3-Benzotriazole and its derivatives. Copper, zinc and their alloys
8. Adsorption of 5-Phenyltetrazole on Iron and Its Inhibition of the Dissolution of Low-Carbon Steel in a Neutral Solution10.1134/S2070205109070107 ↗
9. Physicochemical aspects of metal protection by azoles as corrosion inhibitors10.1070/RC2008v077n03ABEH003753 ↗
10. Environmental factors affecting the corrosion behaviour of reinforcing steel. VI. Benzotriazole and its derivatives as corrosion inhibitors of steel10.1016/j.corsci.2014.06.043 ↗
11. XPES of 1,2,3_Benzotriazole Nanolayers Formed on Iron Surface10.1134/S2070205110070117 ↗
12. Kompleksoobrazovaniye zheleza (II) i zheleza (III) S 1,2,4-triazoltiolom v srede 1 mol’/L HCL pri 273-318K
13. Mononuclear, oligonuclear and polynuclear metal coordination compounds with 1,2,4-triazole derivatives as ligands10.1016/S0010-8545(00)00266-6 ↗
14. Iron(II) and Nickel(II) Complexes of N-Alkylimidazoles and 1-Methyl-1H-1,2,4-Triazole: X-ray Studies, Magnetic Characterization, and DFT Calculations10.1002/zaac.201200117 ↗
15. Sastri, V.S. (2011). Green Corrosion Inhibitors, Theory and Practice, John Wiley & Sons, Inc.10.1002/9781118015438 ↗
16. Finley, K.T. (1980). Triazoles: 1,2,3, John Wiley & Sons Inc.
17. Kuznetsov, Y.I. (1996). Organic Inhibitors of Corrosion of Metals, Springer US.10.1007/978-1-4899-1956-4 ↗
18. Structure of a spin-crossover Fe(II)-l,2,4-triazole polymer complex dispersed in an isotactic polystyrene matrix10.1016/j.eurpolymj.2010.10.029 ↗
19. Spin State Crossover, Vibrational, Computational, and Structural Studies of FeII 1-Isopropyl-1H-tetrazole Derivatives10.1002/ejic.201700981 ↗
20. Kelly, R.J., Scully, J.R., Shoesmith, D.W., and Buchheit, R.G. (2003). Electrochemical Techniques in Corrosion Science and Engineering, Marcel Dekker Inc.10.1201/9780203909133 ↗
21. Szklarska-Smialowska, Z. (2005). Pitting and Crevice Corrosion, NACE International.
22. GOST 380-2005 (2015). Сталь углерoдистая oбыкнoвеннoгo качества. Common quality carbon steel. Grades. Russian State Standard, GOST 380-2005.
23. Improving steel passivation with aqueous solutions of [3-(2-Aminoethylamino)propyl]trimethoxysilane10.1134/S0036024415120262 ↗
24. ASTM D610-08 (2019). Standard Practice for Evaluating Degree of Rusting on Painted Steel Surfaces, ASTM INTERNATIONAL.
25. ASTM D 3330/D 3330M—02 (2018). Standard Test Method for Peel Adhesion of Pressure-Sensitive Tape.
26. ISO 4624:2003 (2003). Paints and Varnishes—Pull-off Test for Adhesion, European Committee for Standardization.
27. Kramers-Kronig Relations in Representation of Modulation Polarimetry by an Example of Transmission Spectra of GaAs Crystal10.1134/S0030400X17120098 ↗
28. Adsorption of 2-mercaptobenzothiazole on copper surface from phosphate10.1016/j.apsusc.2012.03.097 ↗
29. Effect of 1, 2, 3-Benzotriazole on the Corrosion Properties of 316L Stainless Steel in Synthetic Tap Water10.1007/s12540-015-5299-4 ↗
30. A density functional theory and resonance Raman study of a benzotriazoledye used in surface enhanced resonance Raman scattering10.1016/j.molstruc.2005.12.021 ↗
31. Phosphoric acid-doped poly (ether sulfone benzotriazole) for high temperature proton exchange membrane fuel cell applications10.1016/j.memsci.2017.11.067 ↗
32. Langmuir-Blodgett Films of Spin Transition Iron (II) Metalorganic Polymers, 1. Iron (II) Complexes of Octadecyl-1,2,4-triazole10.1021/la00009a032 ↗
33. Manners, I. (2004). Synthetic Metal-Containing Polymers, WILEY-VCH: Verlag, GmbH & Co. KGaA.
34. Synergistic effect of silanes and azole for enhanced corrosion protection of carbon steel by polymeric coatings
35. Physicochemical aspects of metal corrosion inhibition in aqueous solutions10.1070/RC2004v073n01ABEH000864 ↗