journal article·2021-01-22Open access

Exchange Bias in Thin Films—An Update

Tomasz Blachowicz, Andrea Ehrmann

Coatings· Volume 11· Issue 2

Abstract

The exchange bias (EB) is an effect occurring in coupled ferromagnetic/antiferromagnetic materials of diverse shapes, from core–shell nanoparticles to stacked nanostructures and thin films. The interface coupling typically results in a horizontal—often also vertical—shift of the hysteresis loop, combined with an increased coercivity, as compared to the pure ferromagnet, and the possibility of asymmetric hysteresis loops. Several models have been developed since its discovery in 1956 which still have some drawbacks and some unexplained points, while exchange bias systems are at the same time being used in hard drive read heads and are part of highly important elements for spintronics applications. Here, we give an update of new theoretical models and experimental findings regarding exchange bias phenomena in thin films during the last years, including new material combinations in which an exchange bias was found.
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Research context

OpenAlex topics: Magnetic properties of thin films · Magnetic Properties and Applications · Theoretical and Computational Physics

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

Affiliations

Institute of Physics—Center for Science and Education, Silesian University of Technology, ul. Konarskiego 22B, 44-100 Gliwice, Poland

Faculty of Engineering and Mathematics, Bielefeld University of Applied Sciences, Interaktion 1, 33619 Bielefeld, Germany

Funding

Bielefeld University of Applied Sciences

References (100+)

Show source-provided references
1. New magnetic anisotropy10.1103/PhysRev.102.1413 ↗
2. Role of interfacial structure on exchange-biased FeF2-Fe10.1103/PhysRevB.59.6984 ↗
3. Exchange-bias in (110)-oriented CoO/Co bilayers with different magnetocrystalline anisotropies10.1103/PhysRevB.75.054425 ↗
4. Structural and Magnetic Properties of Ni/NiOxide and Co/CoOxide Core/Shell Nanoparticles and their possible Use for Ferrofluids10.1524/zpch.2006.220.2.173 ↗
5. Angular dependence and origin of asymmetric magnetization reversal in exchange-biased Fe/FeF2(110)10.1103/PhysRevB.78.012401 ↗
6. Exchange bias and asymmetric reversal in nanostructures dot arrays10.1103/PhysRevLett.94.057203 ↗
7. Changes in ferromagnetic spin structure induced by exchange bias in Fe/MnF2 films10.1103/PhysRevB.70.224414 ↗
8. Magneto-optical study of magnetization reversal asymmetry in exchange bias10.1063/1.2392283 ↗
9. Exchange bias effect in Fe/LaAlO3: An interface induced effect10.1016/j.jallcom.2020.156484 ↗
10. Correlation of microstructure with magnetic properties in Pr0.67Sr0.33MnO3 thin films10.1007/s10854-020-04510-4 ↗
11. Exchange bias in nanostructures10.1016/j.physrep.2005.08.004 ↗
12. Size dependence of exchange bias in Co/CoO nanostructures10.1103/PhysRevLett.108.077205 ↗
13. Enhanced exchange bias and improved ferromagnetic properties in Permalloy–BiFe0.95Co0.05O3 core–shell nanostructures10.1038/srep18203 ↗
14. Ferromagnetic resonance study of the misalignment between anisotropy axes in exchange-biased NiFe/FeMn/Co trilayers10.1063/1.4875929 ↗
15. In-situ study of exchange-bias in interlayer coupled Co/CoO/Co trilayer structure10.1016/j.jmmm.2020.167186 ↗
17. Effect of shell thickness on the exchange bias blocking temperature and coercivity in Co-CoO core-shell nanoparticles10.1063/1.4997883 ↗
18. Exchange bias using a spin glass10.1038/nmat1809 ↗
19. Effects of cooling field strength on exchange anisotropy at permalloy/CoO interfaces10.1063/1.361317 ↗
20. Positive exchange bias in Fe–Fe2 bilayers10.1103/PhysRevLett.76.4624 ↗
21. Correlation between antiferromagnetic interface coupling and positive exchange bias10.1103/PhysRevB.61.1315 ↗
22. Dependence of exchange field and coercitivity on cooling field in NiFe/CoO bilayers10.1063/1.367823 ↗
23. Competing interfacial exchange and Zeeman energies in exchange biases bilayers10.1103/PhysRevB.60.12837 ↗
24. Effect of roughness slope on exchange biasing in NiO spinvalves10.1063/1.121308 ↗
25. Increased exchange anisotropy due to disorder at permalloy/CoO interfaces10.1063/1.360225 ↗
26. Scaling behavior of the exchange-bias training effect10.1103/PhysRevB.76.184423 ↗
27. Rotation of the pinning direction in the exchange bias training effect in polycrystalline NiFe/FeMn bilayers10.1103/PhysRevLett.101.147207 ↗
28. Origin of the training effect and asymmetry of the magnetization in polycrystalline exchange bias systems10.1103/PhysRevLett.99.067201 ↗
29. Exchange bias training effect in coupled all ferromagnetic bilayer structures10.1103/PhysRevLett.96.067201 ↗
30. Uncompensated moments in the MnPd/Fe exchange bias system10.1103/PhysRevLett.101.126402 ↗
31. Exchange anisotropy—A review10.1063/1.1728716 ↗
32. Étude théorique du couplage ferro-antiferromagnétique dans les couches minces10.1051/anphys/19671402061 ↗
33. Exchange bias theory10.1016/S0304-8853(01)00421-8 ↗
34. Random-field model of exchange bias anisotropy at rough ferromagnetic-antiferromagnetic interfaces10.1103/PhysRevB.35.3679 ↗
35. Mechanisms of exchange anisotropy10.1063/1.340591 ↗
36. Heisenberg to Ising crossover in a random-field model with uniaxial anisotropy10.1103/PhysRevB.37.7673 ↗
37. Simple model for thin ferromagnetic films exchange coupled to an antiferromagnetic substrate10.1063/1.339367 ↗
38. New magnetic anisotropy10.1103/PhysRev.105.904 ↗
39. Consequences of spin-flop coupling in exchange biased films10.1103/PhysRevLett.81.4516 ↗
40. Coupling mechanisms in exchange biased films10.1063/1.369878 ↗
41. Interfacial uncompensated antiferromagnetic spins: Role in unidirectional anisotropy in polycrystalline Ni81F19/CoO bilayers10.1103/PhysRevLett.79.1130 ↗
42. Role of interfacial uncompensated antiferromagnetic spins in unidirectional anisotropy in Ni81F19/CoO bilayers10.1063/1.367721 ↗
43. Model for exchange bias in polycrystalline ferromagnet-antiferromagnet bilayers10.1103/PhysRevB.59.3722 ↗
44. Diluted antiferromagnets in exchange bias: Proof of the domain state model10.1103/PhysRevLett.84.4224 ↗
45. Domain state model for exchange bias. I. Theory10.1103/PhysRevB.66.014430 ↗
46. Domain state model for exchange bias. II. Experiments10.1103/PhysRevB.66.014431 ↗
47. Domain state model for exchange bias: Training effect of diluted Co1-yO on exchange bias in Co/CoO10.1109/TMAG.2002.802866 ↗
48. Modeling exchange bias microscopically10.1016/S0304-8853(01)00813-7 ↗
49. Domain staate model for exchange bias10.1063/1.1358829 ↗
50. Exchange bias model for Fe/FeF2: Role of domains in the ferromagnet10.1209/epl/i1999-00522-9 ↗
51. Exchange-bias systems with compensated interfaces10.1063/1.125517 ↗
52. Positive exchange bias model: Fe/FeF2 and Fe/MnF2 bilayers10.1016/S0038-1098(00)00333-1 ↗
53. Direct observation of the alignment of ferromagnetic spins by antiferromagnetic spins10.1038/35015515 ↗
54. Microscopic imaging of Fe magnetic domains exchange coupled with those in a NiO(001) surface10.1103/PhysRevLett.85.646 ↗
55. Quantitative description of the azimuthal dependence of the exchange bias effect10.1088/0953-8984/18/3/L01 ↗
56. A polycrystalline model for magnetic exchange bias10.1088/0953-8984/24/32/326004 ↗
57. Large scale micromagnetic simulation for the exchange interaction between a polycrystalline antiferromagnet and a ferromagnet10.1103/PhysRevB.73.104433 ↗
58. A model of the magnetic properties of coupled ferromagnetic/antiferromagnetic bilayers10.1063/1.2713698 ↗
59. A new paradigm for exchange bias in polycrystalline thin films10.1016/j.jmmm.2009.12.011 ↗
60. Interface domain wall and exchange bias phenomena in ferrimagnetic/ferrimagnetic bilayers10.1103/PhysRevB.68.140404 ↗
61. Exchange-spring behavior in epitaxial hard/soft magnetic bilayers10.1103/PhysRevB.58.12193 ↗
62. Transitions of magnetic configuration at the interface of exchange-coupled bilayers: TbFe/GdFe as a model system10.1103/PhysRevB.67.144412 ↗
63. Mechanism of exchange bias: Partial wall pinning, and fluctuations10.1016/S0304-8853(01)01154-4 ↗
64. Exchange-bias phenomenon: The role of the ferromagnetic spin structure10.1103/PhysRevLett.114.097202 ↗
65. Shape-dependent exchange bias effect in magnetic nanoparticles with core-shell morphology10.1103/PhysRevB.92.064420 ↗
66. Exchange bias phenomenology and models of core/shell nanoparticles10.1166/jnn.2008.18306 ↗
67. Magnetism and exchange-bias effect at the MnN/Fe interface10.1103/PhysRevB.98.094415 ↗
68. Magnetic domain texture and the Dzyaloshinskii-Moriya interaction in Pt/Co/IrMn and Pt/Co/FeMn thin films with perpendicular exchange bias10.1103/PhysRevB.98.064413 ↗
69. Magnetic properties and the interfacial Dzyaloshinskii-Moriya interaction in exchange biased Pt/Co/NixOy films10.1016/j.apsusc.2020.148720 ↗
70. Reversed exchange-bias effect associated with magnetism reversal in the weak ferrimagnet LuFe0.5Cr0.5O310.1103/PhysRevB.97.104416 ↗
71. Voltage control of unidirectional anisotropy in ferromagnet-multiferroic system10.1126/sciadv.aat4229 ↗
72. Nanoscale spin-wave circuits based on engineered reconfigurable spin-textures10.1038/s42005-018-0056-x ↗
73. Maximizing exchange bias in Co/CoO core/shell nanoparticles by lattice matching between the shell and the embedding matrix10.1021/acs.chemmater.7b00868 ↗
74. Exchange bias of nanostructured films assembled with Co/CoO core–shell clusters10.1016/j.matlet.2016.11.057 ↗
75. Morphology dependence of low temperatures exchange bias Co/CoO core-shell nanoparticles/spheres by eco-friendly solvothermal route10.1063/1.5041017 ↗
76. Tunable high-field magnetization in strongly exchange-coupled freestanding Co/CoO core/shell coaxial nanowires10.1021/acsami.6b05588 ↗
77. Giant exchange bias and its angular dependence in Co/CoO core-shell nanowire assemblies10.1016/j.physleta.2017.04.025 ↗
78. Ultradense arrays of sub-100 nm Co/CoO nanodisks for spintronics applications10.1021/acsanm.0c00052 ↗
79. Exchange bias in Co/CoO thin films deposited onto self-assembled nanosphere arrays10.1016/j.jmmm.2020.166599 ↗
80. López Antón, R., González, J.A., Andrés, J.P., Normile, P., Canales-Vázquez, J., Muniz, P., Riveiro, J.M., and de Toro, J.A. (2017). Exchange Bias Optimization by Controlled Oxidation of Cobalt Nanoparticle Films Prepared by Sputter Gas Aggregation. Nanomaterials, 7.10.3390/nano7030061 ↗
81. Angle and rotational direction dependent horizontal loop shift in epitaxial Co/CoO bilayers on MgO(100)10.1063/1.4985032 ↗
82. Ehrmann, A., and Blachowicz, T. (2020). Asymmetric hysteresis loops in Co thin films. Condens. Matter, 5.10.3390/condmat5040071 ↗
83. Magnetic characterization of oblique angle deposited Co/CoO on gold nanoparticles10.1016/j.jmmm.2019.03.098 ↗
84. Exchange bias and two steps magnetization reversal in porous Co/CoO layer10.1016/j.matdes.2019.107691 ↗
85. Kerr microscopy study of thermal and athermal training effects in a C/CoO exchange bias system10.1063/1.4986415 ↗
86. Role of anti-ferromagnetic layer thickness in exchange bias: Case study of Co/CoO with Kerr microscopy10.1088/2053-1591/ab0ca7 ↗
87. Effect of interface roughness on exchange coupling in polycrystalline Co/CoO bilayer structure: An in-situ investigation10.1063/1.4961521 ↗
88. On the origin of positive exchange bias and coercivity enhancement in proximity to the blocking temperature10.1016/j.jmmm.2020.166707 ↗
89. Unraveling the origin of training in granular Co-CoO exchange bias systems with buried antiferromagnetic constituents10.1016/j.jmmm.2019.01.104 ↗
90. Exchange bias beyond the superparamagnetic blocking temperature of the antiferromagnet in a Ni-NiO nanoparticulate system10.1063/1.4866196 ↗
91. Tiny Ni–NiO nanocrystals with exchange bias induced room temperature ferromagnetism10.1016/j.ssc.2016.01.006 ↗
92. Exchange bias coupling in NiO/Ni bilayer tubular nanostructures synthetized by electrodeposition and thermal oxidation10.1016/j.jmmm.2016.12.136 ↗
93. Effect of electric field on magnetism of Ni thin films via antiferromagnetic NiO10.1380/ejssnt.2018.186 ↗
94. Characterization of Ni thin films following thermal oxidation in air10.1116/1.4895846 ↗
95. Thermal annealing induced competition of oxidation and grain growth in nickel thin films10.1016/j.tsf.2019.04.034 ↗
96. Thickness-dependent thermal oxidation of Ni into NiO thin films10.1007/s10948-018-4651-6 ↗
97. Thickness dependent ferromagnetism in thermally decomposed NiO thin films10.1016/j.jmmm.2016.02.091 ↗
98. Control of exchange bias by modifying the antiferromagnet and ferromagnet-antiferromagnet interface10.1209/0295-5075/130/67006 ↗
99. Unexpected development of perpendicular magnetic anisotropy in Ni/NiO multilayers after mild thermal annealing10.1109/LMAG.2019.2925315 ↗
100. Ferroelectric strain modulation of antiferromagnetic moments in Ni/NiO ferromagnet/antiferromagnet heterostructures10.1103/PhysRevB.95.174420 ↗