journal article·2024-01-21Open access

Overview of Surface Modification Techniques for Titanium Alloys in Modern Material Science: A Comprehensive Analysis

Kang Gao, Yun Zhang, Junhao Yi, Fang Dong, Pinghu Chen

Coatings· Volume 14· Issue 1

Abstract

Titanium alloys are acclaimed for their remarkable biocompatibility, high specific strength, excellent corrosion resistance, and stable performance in high and low temperatures. These characteristics render them invaluable in a multitude of sectors, including biomedicine, shipbuilding, aerospace, and daily life. According to the different phases, the alloys can be broadly categorized into α-titanium and β-titanium, and these alloys demonstrate unique properties shaped by their respective phases. The hexagonal close-packed structure of α-titanium alloys is notably associated with superior high-temperature creep resistance but limited plasticity. Conversely, the body-centered cubic structure of β-titanium alloys contributes to enhanced slip and greater plasticity. To optimize these alloys for specific industrial applications, alloy strengthening is often necessary to meet diverse environmental and operational demands. The impact of various processing techniques on the microstructure and metal characteristics of titanium alloys is reviewed and discussed in this research. This article systematically analyzes the effects of machining, shot peening, and surface heat treatment methods, including surface quenching, carburizing, and nitriding, on the structure and characteristics of titanium alloys. This research is arranged and categorized into three categories based on the methods of processing and treatment: general heat treatment, thermochemical treatment, and machining. The results of a large number of studies show that surface treatment can significantly improve the hardness and friction mechanical properties of titanium alloys. At present, a single treatment method is often insufficient. Therefore, composite treatment methods combining multiple treatment techniques are expected to be more widely used in the future. The authors provide an overview of titanium alloy modification methods in recent years with the aim of assisting and promoting further research in the very important and promising direction of multi-technology composite treatment.
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Research context

OpenAlex topics: Titanium Alloys Microstructure and Properties · High Entropy Alloys Studies · Additive Manufacturing Materials and Processes

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

Affiliations

School of Mechanical Engineering, Hunan University of Science and Technology, Xiangtan 411201, China

State Key Laboratory of Precision Manufacturing for Extreme Service Performance, Light Alloy Research Institute, Central South University, Changsha 410083, China

College of Mechanical Engineering, Key Laboratory of Hunan Province of Equipment Safety Service Technology under Extreme Environment, University of South China, Hengyang 421001, China

Funding

Education Department of Hunan Province · National Natural Science Foundation of China

References (100+)

Show source-provided references
1. Severe plastic deformation induced precipitation of the ordered α2-Ti3Al phase in Ti-5Al-2Sn-2Zr-4Mo-4Cr10.1016/j.jallcom.2020.157277 ↗
2. Improvement of mechanical properties and microstructural refining of cast titanium alloys by coupling of electropulsing and temporary alloying element hydrogen10.1016/j.msea.2022.144176 ↗
3. Effect of Fe content on microstructure and hardness of Ti-4.5Mo–5Al-1.8Zr-2.5Cr-1.1Sn titanium alloy based on high-throughput diffusion couple10.1016/j.msea.2022.143089 ↗
4. Recent advances in silicon containing high temperature titanium alloys10.1016/j.jmrt.2021.08.117 ↗
5. Enhanced strength and ductility in Ti46Al4Nb1Mo alloys via boron addition10.1016/j.jmst.2021.06.037 ↗
6. Kolli, P.R., and Devaraj, A. (2018). A Review of Metastable Beta Titanium Alloys. Metals, 8.10.3390/met8070506 ↗
7. A review on alloy design, biological response, and strengthening of β-titanium alloys as biomaterials
8. A state-of-the-art review of the fabrication and characteristics of titanium and its alloys for biomedical applications
9. Effects of direct aging on near-alpha Ti–6Al–2Sn–4Zr–2Mo (Ti-6242) titanium alloy fabricated by selective laser melting (SLM)10.1016/j.msea.2020.139533 ↗
10. Towards customized heat treatments and mechanical properties in the LPBF-processed Ti-6Al-2Sn-4Zr-6Mo alloy10.1016/j.matdes.2022.110512 ↗
11. Strong correlation between high temperature oxidation resistance and nitrogen mass gain during near alpha titanium alloys exposure in air10.1016/j.corsci.2023.111547 ↗
12. Evaluation of tribocorrosion performance of Ti6Al4V alloy in simulated inflammatory and hyperglycemic microenvironments10.1016/j.wear.2023.205077 ↗
13. Microstructure and property evaluation of TA15 titanium alloy fabricated by selective laser melting after heat treatment10.1016/j.optlastec.2021.107422 ↗
14. Effect of shot peening on high-frequency fatigue properties of TC11 titanium alloy
15. Effect of nitrogen ion implantation dose on torsional fretting wear behavior of titanium and its alloy10.1016/S1003-6326(17)60037-2 ↗
16. A review on heat treatment efficiency in metastable β titanium alloys: The role of treatment process and parameters10.1016/j.jmrt.2020.10.088 ↗
17. Mechanisms of macrozone elimination and grain refinement of near α Ti alloy via the spheroidization of the Widmannstätten structure10.1016/j.actamat.2023.119339 ↗
18. Formation mechanism of titanium solid solution and its influence on equiaxed behavior of α phase of Ti–5Al–5Mo–5Cr–2Zr-xNb alloys10.1016/j.jmrt.2023.07.173 ↗
19. Current status and development trend of low-temperature titanium alloy materials
20. Research progress on microstructure evolution and hot processing maps of high strength β titanium alloys during hot deformation10.1016/S1003-6326(22)66062-X ↗
21. Comparison of flow behaviors of near beta Ti-55511 alloy during hot compression based on SCA and BPANN models10.1016/S1003-6326(21)65606-6 ↗
22. Zhang, H., Zhang, S., Zhang, S., Liu, X.J., Wu, X.X., Zhang, S.Q., and Zhou, G. (2023). High Temperature Deformation Behavior of Near-β Titanium Alloy Ti-3Al-6Cr-5V-5Mo at α+β and β Phase Fields. Crystals, 13.10.3390/cryst13030371 ↗
23. Newly developed Ti–Nb–Zr–Ta–Si–Fe biomedical beta titanium alloys with increased strength and enhanced biocompatibility10.1016/j.msec.2015.11.043 ↗
24. Hot deformation behavior and mechanism of a new metastable β titanium alloy Ti–6Cr–5Mo–5V–4Al in single phase region10.1016/j.msea.2021.141231 ↗
25. Unveiling the dynamic softening mechanism via micromechanical behavior for a near-β titanium alloy deformed at a high strain rate10.1016/j.jmrt.2023.09.150 ↗
26. Role of grain boundaries in the high-temperature performance of a highly stabilized beta titanium alloy II: Creep behavior10.1016/j.msea.2012.07.115 ↗
27. High strain rate compression behavior of a heavily stabilized beta titanium alloy: Kink deformation and adiabatic shearing10.1016/j.jallcom.2017.02.284 ↗
28. Titanium and titanium alloy grades and applications in foreign aerospace industry
29. Improvement of microstructure and mechanical properties of TC4 titanium alloy GTAW based wire arc additive manufacturing by using interpass milling10.1016/j.jmrt.2023.10.006 ↗
30. Influence of heat treatment parameters on microstructure and mechanical performance of titanium alloy in LPBF: A brief review10.1016/j.jmrt.2023.04.090 ↗
31. Improved seawater corrosion resistance of electron beam melting Ti6Al4V titanium alloy by plasma nitriding10.1016/j.vacuum.2023.112463 ↗
32. The Molecular Orbital Approach to Titanium Alloy Design10.4028/www.scientific.net/KEM.770.217 ↗
33. Effect of alloying elements on corrosion properties of high corrosion resistant titanium alloys in high concentrated sulfuric acid
34. Stress corrosion cracking of TC4 ELI alloy with different microstructure in 3.5% NaCl solution10.1016/j.matchar.2022.112357 ↗
35. Corrosion Behavior of Severely Deformed Pure and Single-Phase Materials10.2320/matertrans.MF201935 ↗
36. Study of mechanical properties and corrosive resistance of ultrafine-grained α-titanium alloy Ti-5Al-2V10.1016/j.jallcom.2017.06.220 ↗
37. Recent Trends in the Characterization and Application Progress of Nano-Modified Coatings in Corrosion Mitigation of Metals and Alloys10.3390/app13020730 ↗
38. In-Situ fabrication of novel (Ti, Cr)-N/aluminide multilayer coatings by plasma nitriding Ti-Cr coated Al alloy10.1016/j.ceramint.2018.01.182 ↗
39. Wear and corrosion studies of duplex surface-treated AISI-304 steel by a combination of cathodic cage plasma nitriding and PVD-TiN coating10.1016/j.ceramint.2022.04.115 ↗
40. Rapid Nitriding of Titanium Alloy with Fine Grains at Room Temperature
41. Comparison of auxiliary cathode and conventional plasma nitriding of gamma-TiAl alloy10.1016/j.vacuum.2016.06.006 ↗
42. High temperature oxidation behavior and research status of modifications on improving high temperature oxidation resistance of titanium alloys and titanium aluminides: A review10.1016/j.jallcom.2016.06.212 ↗
43. Design of near-α Ti alloys via a cluster formula approach and their high-temperature oxidation resistance10.1016/j.jmst.2018.12.013 ↗
44. Cyclic oxidation behaviour of the titanium alloys Ti-6242 and Ti-17 with Ti–Al–Cr–Y coatings at 600 and 700 °C in air10.1016/j.surfcoat.2013.02.021 ↗
45. Effects of tungsten addition on the microstructural stability and properties of Ti-6.5Al-2Sn-4Hf-2Nb-based high temperature titanium alloys10.1016/j.jmst.2021.02.057 ↗
46. Experimentally validated dwell and cyclic fatigue crack nucleation model for α–titanium alloys10.1016/j.scriptamat.2016.08.031 ↗
47. On the influence of ageing on the onset of plastic slip in Ti-6Al-4V at room temperature: Insight on dwell fatigue behavior
48. Interaction between Al and other alloying atoms in α-Ti for designing high temperature titanium alloy10.1016/j.commatsci.2021.110620 ↗
49. Development of Ti-Al-Ta-Nb-(Re) near-α high temperature titanium alloy: Microstructure, thermal stability and mechanical properties10.1016/j.jmst.2021.08.066 ↗
50. First-principles investigation of interaction between surface oxygen and other alloy atoms in α-Ti (0001) for designing high-temperature titanium alloy10.1016/j.apsusc.2022.154535 ↗
51. Research progress of low-temperature titanium alloy
52. Microstructure and mechanical properties of new high strength beta-titanium alloy Ti-130010.1016/j.msea.2014.10.072 ↗
53. Tuning the scale of α precipitates in β-titanium alloys for achieving high strength10.1016/j.scriptamat.2018.05.040 ↗
54. Effect of annealing temperature on mechanical properties of TC21 titanium alloy with multilevel lamellar microstructure10.1016/j.msea.2023.144788 ↗
55. A novel low-cost high-strength β titanium alloy: Microstructure evolution and mechanical behavior10.1016/j.jallcom.2023.170497 ↗
56. Functionalization of the Implant Surface Made of NiTi Shape Memory Alloy10.3390/ma16041609 ↗
57. Investigation of chemical analysis methods of niobium-titanium alloys for superconductivity
58. Effect of introducing manganese as additive on microstructure, hydrogen storage properties and rate limiting step of Ti–Cr alloy10.1016/j.ijhydene.2021.10.029 ↗
59. Surface antibacterial properties enhanced through engineered textures and surface roughness: A review10.1016/j.colsurfb.2023.113584 ↗
60. 3D surface topography analysis and functionality-related performance of the machined surface in slot micro-milling titanium alloy Ti6Al4V10.1007/s00170-023-11644-2 ↗
61. Investigations on surface modification of nickel-based superalloy subjected to ultrasonic surface rolling process10.1007/s00170-023-12299-9 ↗
62. Novel hybrid machining process of titanium alloy for texturing high-quality microstructure array surfaces10.1016/j.surfcoat.2023.129494 ↗
63. Machinability of titanium alloy through electric discharge machining10.1080/10426914.2018.1532092 ↗
64. Performance and wear mechanisms of PCD and pcBN cutting tools during machining titanium alloy Ti6Al4V
65. Grindability of titanium alloy using cryogenic nanolubricant minimum quantity lubrication10.1016/j.jmapro.2022.06.003 ↗
66. The influence of additive manufacturing on the micromilling machinability of Ti6Al4V: A comparison of SLM and commercial workpieces10.1016/j.jmapro.2020.10.006 ↗
67. Machinability improvement of titanium alloy (Ti–6Al–4V) via LAM and hybrid machining10.1016/j.ijmachtools.2009.10.013 ↗
68. Experimental investigation with respect to the performance of deep submillimeter-scaled textured tools in dry turning titanium alloy Ti-6Al-4V10.1016/j.apsusc.2017.01.166 ↗
69. Effect of material anisotropy on ultra-precision machining of Ti-6Al-4V alloy fabricated by selective laser melting10.1016/j.jallcom.2020.156457 ↗
70. Reduction of tool tip vibration in single-point diamond turning using an eddy current damping effect10.1007/s00170-019-03457-z ↗
71. Microstructural effects of Ti6Al4V alloys modified by electropulsing treatment on ultraprecision diamond turning10.1016/j.jmapro.2019.02.005 ↗
72. Multi-characteristics optimization in EDM of NiTi alloy, NiCu alloy and and BeCu alloy using Taguchi’s approach and utility concept
73. Surface and Subsurface Quality of Titanium Grade 23 Machined by Electro Discharge Machining10.3390/ma15010164 ↗
74. Influences of tool electrodes on machinability of titanium α-β alloy with ISO energy pulse generator in EDM process10.1016/j.aej.2022.07.059 ↗
75. Effects of conventional shot peening, severe shot peening, re-shot peening and precised grinding operations on fatigue performance of AISI 1050 railway axle steel10.1016/j.ijfatigue.2021.106613 ↗
76. Effect of Shot Peening on the Strength and Corrosion Properties of 6082-T651 Aluminium Alloy10.3390/ma16144976 ↗
77. Novel experimental methods for the determination of the boundaries between conventional, severe and over shot peening processes10.1016/j.surfin.2018.09.003 ↗
78. Investigation of slip transfer across HCP grain boundaries with application to cold dwell facet fatigue10.1016/j.actamat.2017.01.021 ↗
79. Anti-fatigue strengthening mechanism of conventional shot peening and micro-shot peening on bare and micro-arc oxidation coated 6082-T6 aluminum alloy10.1016/j.matlet.2022.133442 ↗
80. Surface layer strengthening mechanism of 2060 aluminum–lithium alloy after shot-peening10.1016/j.jmrt.2023.02.064 ↗
81. Effect of shot peening and vibration finishing on the fatigue behavior of TC17 titanium alloy at room and high temperature10.1016/j.ijfatigue.2021.106391 ↗
82. Surface Severe Plastically Deformed Nanostructured AA7075 Alloy: Assessment on Tribological and Axial Fatigue Behaviors10.1007/s11665-020-04892-w ↗
83. Enhancement of Mechanical Properties and Corrosion Resistance of HVOF-Sprayed NiCrBSi Coatings Through Mechanical Attrition Treatment (SMAT)10.1007/s11666-020-01092-9 ↗
84. Neutral Molten Salt-Bath Carburizing of Ti6Al4V Alloy with Nanocrystalline Surface Layer at Low Temperature Assisted by Surface Mechanical Attrition Treatment10.4028/www.scientific.net/KEM.727.1001 ↗
85. Effect of high-speed ultrasonic vibration cutting on the microstructure, surface integrity, and wear behavior of titanium alloy10.1016/j.jmrt.2023.04.036 ↗
86. Improvement in tribological behavior of commercial pure titanium (CP-Ti) by surface mechanical attrition treatment (SMAT)10.1016/j.triboint.2017.11.044 ↗
87. Surface self-nanocrystallization of α+β titanium alloy by surface mechanical grinding treatment10.1007/s12540-017-6567-2 ↗
88. Microstructure design to improve the corrosion and cavitation corrosion resistance of a nickel-aluminum bronze10.1016/j.corsci.2018.04.043 ↗
89. Study on fast gas forming with in-die quenching for titanium alloys and the strengthening mechanisms of the components10.1016/j.jmrt.2022.04.084 ↗
90. Microstructure modification and improving corrosion resistance of laser surface quenched nickel–aluminum bronze alloy10.1016/j.corsci.2020.108744 ↗
91. Gradient microstructure and mechanical properties of Ti-6Al-4V titanium alloy fabricated by high-frequency induction quenching treatment10.1016/j.matdes.2022.111031 ↗
92. Simulation of coupled temperature, microstructure and internal stresses evolutions during quenching of a β-metastable titanium alloy10.1016/j.msea.2015.11.010 ↗
93. Analysis of the state of the modified nanotitanium surface with the use of the mathematical model of a cyclic random process10.3103/S8756699015030073 ↗
94. Effect of cold rolling reduction on grain growth kinetics of TB8 titanium alloy during annealing heat treatment10.1088/2053-1591/ab4af2 ↗
95. Static globularization and grain morphology evolution of α and β phases during annealing of hot-rolled TC21 titanium alloy10.1016/S1003-6326(21)65683-2 ↗
96. Effects of different annealing cooling methods on the microstructure and properties of TA10 titanium alloys10.1016/j.jmrt.2022.04.149 ↗
97. Kumar, U., Chattopadhyaya, S., Das, K.A., Seikh, A., Sharma, S., Dwivedi, P.S., Nagai, K., Kumar, A., Agrawal, A., and Singh, S. (2023). Effect of Pulsation in Microstructure and Mechanical Properties of Titanium Alloy-Annealed Welded Joints at Different Temperatures. Photonics, 10.10.3390/photonics10040372 ↗
98. Effect of annealing process on the organization and impact properties of TC10 titanium alloy
99. Effect of solid carburization on surface microstructure and hardness of Ti-6Al-4V alloy and (TiB+La2O3)/Ti-6Al-4V composite10.1016/S1003-6326(16)64301-7 ↗
100. Comparison of Different Thermo-Chemical Treatments Methods of Ti-6Al-4V Alloy in Terms of Tribological and Corrosion Properties10.3390/ma13225192 ↗