Emerging Corrosion Inhibitors for Interfacial Coating
Source abstract
Abstract
Corrosion is a deterioration of a metal due to reaction with environment. The use of corrosion inhibitors is one of the most effective ways of protecting metal surfaces against corrosion. Their effectiveness is related to the chemical composition, their molecular structures and affinities for adsorption on the metal surface. This review focuses on the potential of ionic liquid, polyionic liquid (PIL) and graphene as promising corrosion inhibitors in emerging coatings due to their remarkable properties and various embedment or fabrication strategies. The review begins with a precise description of the synthesis, characterization and structure-property-performance relationship of such inhibitors for anti-corrosion coatings. It establishes a platform for the formation of new generation of PIL based coatings and shows that PIL corrosion inhibitors with various heteroatoms in different form can be employed for corrosion protection with higher barrier properties and protection of metal surface. However, such study is still in its infancy and there is significant scope to further develop new structures of PIL based corrosion inhibitors and coatings and study their behaviour in protection of metals. Besides, it is identified that the combination of ionic liquid, PIL and graphene could possibly contribute to the development of the ultimate corrosion inhibitor based coating.
Source: crossref · Quality: baseline
Research context
OpenAlex topics: Ionic liquids properties and applications · Corrosion Behavior and Inhibition · Polymer composites and self-healing
SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.
Affiliations
Future Industries Institute, University of South Australia, Mawson Lakes Campus, Mawson Lakes, Adelaide, SA 5095, Australia
School of Chemical Engineering, University of Adelaide, Adelaide, SA 5005, Australia
Funding
Australian Research Council
References (100+)
Show source-provided references
1. Microencapsulation: An emerging technique in the modern coating industry10.1039/C6RA13237E ↗
2. Aliofkhazraei, M. (2014). Corrosion inhibitors–principles, mechanisms and applications. Developments in Corrosion Protection, INTECH.10.5772/57010 ↗
3. Adsorption and corrosion inhibition of new synthesized pyridazinium-based ionic liquid on carbon steel in 0.5MH2SO4
4. A review on recent patents in corrosion inhibitors10.2174/1877610801002010006 ↗
5. Bardal, E. (2007). Corrosion and Protection, Springer Science & Business Media.
6. Apricot juice as green corrosion inhibitor of mild steel in phosphoric acid10.1016/j.aej.2012.11.001 ↗
7. Effects of 2-amino-5-(ethylthio)-1,3,4-thiadiazole on copper corrosion as a corrosion inhibitor in 3% NaCl solutions10.1016/j.apsusc.2005.11.082 ↗
8. Revie, R.W. (2008). Corrosion and Corrosion Control, John Wiley & Sons. [4th ed.].10.1002/9780470277270 ↗
9. Electrochemical and XPS studies of decylamides of α-amino acids adsorption on carbon steel in acidic environment10.1016/j.apsusc.2005.04.040 ↗
10. Synthesis and corrosion inhibition of α-amino acids alkylamides for mild steel in acidic environment10.1016/j.matchemphys.2008.02.010 ↗
11. Some pyridine derivatives as corrosion inhibitors for carbon steel in acidic medium10.1016/j.matchemphys.2005.02.020 ↗
12. Evaluation of inhibitive action of some quaternary N-heterocyclic compounds on the corrosion of Al–Cu alloy in hydrochloric acid10.1016/j.matchemphys.2008.09.065 ↗
13. Evaluation of corrosion inhibitors synthesized from fatty acids and fatty alcohols isolated from sugar cane wax10.5006/1.3299242 ↗
14. Electrochemistry and XPS study of an imidazoline as corrosion inhibitor of mild steel in an acidic environment10.1002/maco.200805044 ↗
15. Effect of the molecular structure on the inhibitor properties of azoles on mild steel corrosion in 1 m hydrochloric acid10.1016/j.corsci.2006.10.021 ↗
16. Films formed on copper surface in chloride media in the presence of azoles10.1016/j.corsci.2009.03.026 ↗
17. Electroactive conducting polymers for corrosion control10.1007/s100080100212 ↗
18. A review on the use of graphene as a protective coating against corrosion
19. Martínez-Palou, R., and Sánche, P.F. (2011). Perspectives of Ionic Liquids Applications for Clean Oilfield Technologies, INTECH Open Access Publisher.10.5772/14529 ↗
20. Corrosion inhibition of mild steel by alkylimidazolium ionic liquids in hydrochloric acid10.1016/j.electacta.2008.10.025 ↗
21. Poly(ionic liquid)s: Polymers expanding classical property profiles10.1016/j.polymer.2011.01.043 ↗
22. Applications of ionic liquids in the chemical industry10.1039/B006677J ↗
23. Ionic liquids and catalysis: Recent progress from knowledge to applications10.1016/j.apcata.2009.10.008 ↗
24. Ionic liquids in separations10.1021/ar700044y ↗
25. Guide to CO2 separations in imidazolium-based room-temperature ionic liquids10.1021/ie8016237 ↗
26. Ionic liquids in analytical chemistry10.1021/ac069394o ↗
27. Friction and wear behaviors of ionic liquid of alkylimidazolium hexafluorophosphates as lubricants for steel/steel contact10.1016/S0043-1648(03)00255-2 ↗
28. Stable mesoscopic dye-sensitized solar cells based on tetracyanoborate ionic liquid electrolyte10.1021/ja061714y ↗
29. The effect of ionic liquids with imidazolium and pyridinium cations on the corrosion inhibition of mild steel in acidic environment10.1016/j.corsci.2010.02.030 ↗
30. Self-organization of imidazolium ionic liquids in aqueous solution10.1016/j.colsurfa.2008.07.012 ↗
31. Surface interactions, corrosion processes and lubricating performance of protic and aprotic ionic liquids with ofhc copper10.1016/j.apsusc.2013.02.083 ↗
32. Some surfactants in the series of 2-(alkyldimethylammonio) alkanol bromides as inhibitors of the corrosion of iron in acid chloride solution10.1016/0010-938X(94)00134-R ↗
33. Corrosion inhibition of aluminium in acid solutions by some imidazoline derivatives10.1007/s10800-007-9379-0 ↗
34. In situ studies of imidazole and its derivatives as copper corrosion inhibitors. I. Activation energies and thermodynamics of adsorption10.1149/1.1393230 ↗
35. Inhibition of copper corrosion by bis-(1,1′-benzotriazoly)-α,ω-diamide compounds in aerated sulfuric acid solution10.1016/j.apsusc.2005.07.010 ↗
36. Corrosion inhibition of aluminum in hydrochloric acid solution by alkylimidazolium ionic liquids10.1016/j.matchemphys.2009.07.035 ↗
37. Synthesis of new ionic liquids and corrosion inhibition performance of its cationic imidazoline group
38. Bare surface reaction rates and their relation to environment controlled cracking of aluminum alloys I. Bare surface reaction rates on aluminum-7 weight percent magnesium in aqueous solutions10.1149/1.2129893 ↗
39. Corrosion behaviour of ionic liquids10.1039/b419320m ↗
40. Corrosion inhibition of mild steel in acidic media by [BMIm]Br ionic liquid10.1016/j.matchemphys.2008.09.019 ↗
41. Synergistic corrosion inhibition of mild steel in aqueous chloride solutions by an imidazolinium carboxylate salt10.1021/acssuschemeng.5b01725 ↗
42. Synthesis of block copolymers of styrene and methyl methacrylate by conventional free radical polymerization in room temperature ionic liquids10.1021/ma025518x ↗
43. Propagation kinetics of free-radical polymerizations in ionic liquids10.1002/pola.22485 ↗
44. Synthesis and electric field actuation of an ionic liquid polymer10.1021/ja064264i ↗
45. The design of polymeric ionic liquids for the preparation of functional materials10.1080/15583720903291116 ↗
46. Imidazole- and imidazolium-containing polymers for biology and material science applications10.1016/j.polymer.2010.02.006 ↗
47. Designing imidazole-based ionic liquids and ionic liquid monomers for emerging technologies10.1080/15583720903288914 ↗
48. Thiol-ene click chemistry as a tool for a novel family of polymeric ionic liquids10.1002/macp.201200081 ↗
49. Ionic IPNs as novel candidates for highly conductive solid polymer electrolytes10.1002/pola.23478 ↗
50. Tailoring charge density and hydrogen bonding of imidazolium copolymers for efficient gene delivery10.1021/bm2003303 ↗
51. Bis-imidazolium-based anion-exchange membranes for alkaline fuel cells10.1016/j.jpowsour.2012.06.041 ↗
52. Polymeric ionic liquids: Broadening the properties and applications of polyelectrolytes10.1016/j.progpolymsci.2011.05.007 ↗
53. The inhibition of aluminum corrosion in sulfuric acid by poly (1-vinyl-3-alkyl-imidazolium hexafluorophosphate)10.3390/ma7085711 ↗
54. Poly (ionic liquid) based on modified ionic polyacrylamide for inhibition steel corrosion in acid solution10.1016/S1452-3981(23)11266-1 ↗
55. Nanocontainer-based anticorrosive coatings: Effect of the container size on the self-healing performance10.1002/adfm.201203715 ↗
56. 1,2,3-triazolium-based poly(ionic liquid)s obtained through click chemistry polyaddition10.1002/macp.201400182 ↗
57. Dispersity in polymer science (IUPAC recommendations 2009)10.1351/PAC-REC-08-05-02 ↗
58. Synthesis of gel-type polymer beads from ionic liquid monomers10.1002/pola.20299 ↗
59. Synthesis and characterization of new polymeric ionic liquid microgels10.1002/pola.21483 ↗
60. Poly(ionic liquid) latexes prepared by dispersion polymerization of ionic liquid monomers10.1021/ma102858b ↗
61. Self-assembly of poly(ionic liquid)s: Polymerization, mesostructure formation, and directional alignment in one step10.1021/ja207080j ↗
62. Effect of nanoscale morphology on the conductivity of polymerized ionic liquid block copolymers10.1021/ma201067h ↗
63. Synthesis of polymeric ionic liquid microsphere/Pt nanoparticle hybrids for electrocatalytic oxidation of methanol and catalytic oxidation of benzyl alcohol10.1002/pola.24895 ↗
64. Thermosensitive ionic microgels via surfactant-free emulsion copolymerization and in situ quaternization cross-linking10.1021/am500291n ↗
65. Functional, sub-100 nm polymer nanoparticles via thiol-ene miniemulsion photopolymerization10.1039/C4PY01449A ↗
66. Thiol–enes: Chemistry of the past with promise for the future10.1002/pola.20366 ↗
67. Thiol-click chemistry: A multifaceted toolbox for small molecule and polymer synthesis10.1039/b901979k ↗
68. Light-mediated thiol–ene polymerization in miniemulsion: A fast route to semicrystalline polysulfide nanoparticles10.1021/mz500458s ↗
69. Polymeric ionic liquid nanoparticle emulsions as a corrosion inhibitor in anticorrosion coatings10.1021/acsomega.6b00027 ↗
70. Preparation and electrochemical characterization of gel polymer electrolyte based on electrospun polyacrylonitrile nonwoven membranes for lithium batteries10.1016/j.jpowsour.2010.10.089 ↗
71. Use of floating alginate gel beads for stomach-specific drug delivery10.1016/S0939-6411(00)00110-7 ↗
72. Hydrogels for pharmaceutical and biomedical applications10.1615/CritRevTherDrugCarrierSyst.v22.i2.10 ↗
73. A facile one-step synthesis to cross-linked polymeric nanoparticles as highly active and selective catalysts for cycloaddition of CO2 to epoxides10.1039/b926901k ↗
74. Monodisperse polymeric ionic liquid microgel beads with multiple chemically switchable functionalities10.1021/la401613w ↗
75. Facile fabrication of polymerizable ionic liquid based-gel beads via thiol–ene chemistry10.1021/acsami.5b04405 ↗
76. (2017, October 24). Graphene. Available online: https://www.graphene-info.com/introduction.
77. Graphene: Corrosion-inhibiting coating10.1021/nn203507y ↗
78. Graphene and graphene oxide: Synthesis, properties, and applications10.1002/adma.201001068 ↗
79. Enhancing polymer performance through graphene sheets10.1002/app.33068 ↗
80. Measurement of the elastic properties and intrinsic strength of monolayer graphene10.1126/science.1157996 ↗
81. Superior thermal conductivity of single-layer graphene10.1021/nl0731872 ↗
82. New role of graphene oxide as active hydrogen donor in the recyclable palladium nanoparticles catalyzed ullmann reaction in environmental friendly ionic liquid/supercritical carbon dioxide system10.1039/c0jm02396e ↗
83. Graphene sheets decorated with SnO2 nanoparticles: In situ synthesis and highly efficient materials for cataluminescence gas sensors10.1039/c0jm04331a ↗
84. Efficient preparation of large-area graphene oxide sheets for transparent conductive films10.1021/nn1015506 ↗
85. Graphene-based electrode materials for rechargeable lithium batteries10.1039/b901551e ↗
86. Synthesis of nitrogen-doped graphene films for lithium battery application10.1021/nn101926g ↗
87. Graphene/polyaniline nanofiber composites as supercapacitor electrodes10.1021/cm902876u ↗
88. Graphene constructed carbon thin films as transparent electrodes for solar cell applications10.1039/c0jm01352h ↗
89. Functionalized graphene sheets for polymer nanocomposites10.1038/nnano.2008.96 ↗
90. Synthesis of poly(vinyl alcohol)/reduced graphite oxide nanocomposites with improved thermal and electrical properties10.1039/b904232f ↗
91. Recent advance in functionalized graphene/polymer nanocomposites10.1039/c0jm00530d ↗
92. Graphene production: New solutions to a new problem10.1038/nnano.2008.249 ↗
93. Novel anticorrosion coatings prepared from polyaniline/graphene composites10.1016/j.carbon.2012.06.043 ↗
94. Mechanical and thermal properties of graphite platelet/epoxy composites10.1016/j.polymer.2004.09.054 ↗
95. Enhanced mechanical properties of nanocomposites at low graphene content10.1021/nn9010472 ↗
96. Characterization of epoxy functionalized graphite nanoparticles and the physical properties of epoxy matrix nanocomposites10.1016/j.compscitech.2010.02.023 ↗
97. Synthesis, characterization and thermal properties of novel epoxy/expandable graphite composites10.1002/pi.2699 ↗
98. Epoxy-graphene UV-cured nanocomposites10.1016/j.polymer.2011.08.039 ↗
99. Anticorrosive coatings: A review10.1007/s11998-008-9144-2 ↗
100. In situ preparation of functionalized graphene oxide/epoxy nanocomposites with effective reinforcements10.1039/c1jm11434d ↗