journal article·2021-11-03Open access

Hybridization of MMT/Lignocellulosic Fiber Reinforced Polymer Nanocomposites for Structural Applications: A Review

Aisyah Humaira Alias, Mohd Nurazzi Norizan, Fatimah Athiyah Sabaruddin, Muhammad Rizal Muhammad Asyraf, Mohd Nor Faiz Norrrahim, Ahmad Rushdan Ilyas, Anton M. Kuzmin, Marwah Rayung, Siti Shazra Shazleen, Asmawi Nazrin, Shah Faisal Khan Sherwani, Muhammad Moklis Harussani, Mahamud Siti Nur Atikah, Mohamad Ridzwan Ishak, Salit Mohd Sapuan, Abdan Khalina

Coatings· Volume 11· Issue 11

Abstract

In the recent past, significant research effort has been dedicated to examining the usage of nanomaterials hybridized with lignocellulosic fibers as reinforcement in the fabrication of polymer nanocomposites. The introduction of nanoparticles like montmorillonite (MMT) nanoclay was found to increase the strength, modulus of elasticity and stiffness of composites and provide thermal stability. The resulting composite materials has figured prominently in research and development efforts devoted to nanocomposites and are often used as strengthening agents, especially for structural applications. The distinct properties of MMT, namely its hydrophilicity, as well as high strength, high aspect ratio and high modulus, aids in the dispersion of this inorganic crystalline layer in water-soluble polymers. The ability of MMT nanoclay to intercalate into the interlayer space of monomers and polymers is used, followed by the exfoliation of filler particles into monolayers of nanoscale particles. The present review article intends to provide a general overview of the features of the structure, chemical composition, and properties of MMT nanoclay and lignocellulosic fibers. Some of the techniques used for obtaining polymer nanocomposites based on lignocellulosic fibers and MMT nanoclay are described: (i) conventional, (ii) intercalation, (iii) melt intercalation, and (iv) in situ polymerization methods. This review also comprehensively discusses the mechanical, thermal, and flame retardancy properties of MMT-based polymer nanocomposites. The valuable properties of MMT nanoclay and lignocellulose fibers allow us to expand the possibilities of using polymer nanocomposites in various advanced industrial applications.
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Research context

OpenAlex topics: Polymer Nanocomposites and Properties · Natural Fiber Reinforced Composites · biodegradable polymer synthesis and properties

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

Affiliations

Institute of Tropical Forestry and Forest Products (INTROP), Universiti Putra Malaysia (UPM), Seri Kembangan 43400, Malaysia

Department of Mechanical and Manufacturing Engineering, Faculty of Engineering, Universiti Putra Malaysia (UPM), Seri Kembangan 43400, Malaysia

Centre for Defence Foundation Studies, Universiti Pertahanan Nasional Malaysia (UPNM), Kem Perdana Sungai Besi, Kuala Lumpur 57000, Malaysia

Faculty of Biotechnology and Biomolecular Sciences, Universiti Putra Malaysia (UPM), Seri Kembangan 43400, Malaysia

Department of Aerospace Engineering, Universiti Putra Malaysia (UPM), Seri Kembangan 43400, Malaysia

Research Centre for Chemical Defence, Universiti Pertahanan Nasional Malaysia (UPNM), Kem Perdana, Sungai Besi, Kuala Lumpur 57000, Malaysia

School of Chemical and Energy Engineering, Faculty of Engineering, Universiti Teknologi Malaysia (UTM), Skudai 81310, Malaysia

Centre for Advanced Composite Materials (CACM), Universiti Teknologi Malaysia, UTM Johor Bahru, Skudai 81310, Malaysia

Department of Mechanization and Agricultural Products Processing, Ogarev Mordovia State University, 430005 Saransk, Russia

Faculty of Science, Universiti Putra Malaysia (UPM), Seri Kembangan 43400, Malaysia

Department of Chemical and Environmental Engineering, Universiti Putra Malaysia (UPM), Seri Kembangan 43400, Malaysia

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