Review of the Application of Graphene-Based Coatings as Anticorrosion Layers
Source abstract
Abstract
Due to the excellent properties of graphene, including flexibility that allows it to adjust to the curvature of the substrate surface, chemical inertness, and impermeability, graphene is used as an anticorrosion layer. In this review, we present the current state-of-the-art in the application of graphene in the field of protective coatings. This review provides detailed discussions about the protective properties of graphene coatings deposited by different methods, graphene-based organic coatings, the modification of graphene-based coatings, and the effects of graphene functionalization on the corrosion resistance of protective coatings.
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Research context
OpenAlex topics: Graphene research and applications · Supercapacitor Materials and Fabrication · Corrosion Behavior and Inhibition
SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.
Affiliations
Department of Process Engineering and Chemical Technology, Faculty of Chemistry, Gdansk University of Technology, 11/12 Gabriela Narutowicza Street, 80-233 Gdansk, Poland
References (100+)
Show source-provided references
1. Multifunctional biocomposites based on polyhydroxyalkanoate and graphene/carbon nanofiber hybrids for electrical and thermal applications10.1021/acsapm.0c00539 ↗
2. Oil-in-water separation with graphene-based nanocomposite membranes for produced water treatment10.1016/j.memsci.2020.118007 ↗
3. Highly permeable polyaniline–graphene oxide nanocomposite membranes for CO2 separations10.1021/acsapm.9b00426 ↗
4. Immobilized piperazine on the surface of graphene oxide as a heterogeneous bifunctional acid-base catalyst for the multicomponent synthesis of 2-amino-3-cyano-4: H -chromenes10.1039/D0GC01274B ↗
5. Graphene oxide-polybenzimidazolium nanocomposite anion exchange membranes for electrodialysis10.1039/C8TA09160A ↗
6. Graphene-based advanced nanoplatforms and biocomposites from environmentally friendly and biomimetic approaches10.1039/C9GC02266J ↗
7. Robust covalently cross-linked polybenzimidazole/graphene oxide membranes for high-flux organic solvent nanofiltration10.1021/acsami.8b03591 ↗
8. Supercapacitor devices based on graphene materials10.1021/jp902214f ↗
9. Uptake of H2 and CO2 by graphene10.1021/jp805802w ↗
10. Ang, P.K., Chen, W., and Loh, K.P. (2008). Wee ATS solution-gated epitaxial graphene as pH sensor. J. Am. Chem. Soc., 14392–14393.10.1021/ja805090z ↗
11. Corrosion study of electrophoretically deposited graphene oxide coatings on copper metal10.1016/j.tsf.2016.09.036 ↗
12. A hydrothermal anvil made of graphene nanobubbles on diamond10.1038/ncomms2579 ↗
13. Graphene as an anti-corrosion coating layer10.1039/C4FD00259H ↗
14. Electric field in atomically thin carbon films10.1126/science.1102896 ↗
15. Synthesis of graphene10.1007/s40089-015-0176-1 ↗
16. Xu, Y., Cao, H., Xue, Y., Li, B., and Cai, W. (2018). Liquid-phase exfoliation of graphene: An overview on exfoliation media, techniques, and challenges. Nanomaterials, 8.10.3390/nano8110942 ↗
17. Review of chemical vapor deposition of graphene and related applications10.1021/ar300203n ↗
18. Hydrothermal dehydration for the “green” reduction of exfoliated graphene oxide to graphene and demonstration of tunable optical limiting properties10.1021/cm9006603 ↗
19. Hydrazine-reduction of graphite- and graphene oxide10.1016/j.carbon.2011.02.071 ↗
20. Efficient reduction of graphite oxide by sodium borohydride and its effect on electrical conductance10.1002/adfm.200900167 ↗
21. Vitamin C is an ideal substitute for hydrazine in the reduction of graphene oxide suspensions10.1021/jp100603h ↗
22. Influence of the reduction of graphene oxide with hydroiodic acid on the structure and photoactivity of CdS–rGO hybrids10.1007/s11244-017-0799-8 ↗
23. Deoxygenation of exfoliated graphite oxide under alkaline conditions: A green route to graphene preparation10.1002/adma.200801306 ↗
24. The electrocapacitive properties of graphene oxide reduced by urea10.1039/C1EE02478G ↗
25. Reduction of graphene oxide by thiourea10.1166/jnn.2011.4985 ↗
26. Reducing graphene oxide via hydroxylamine: A simple and efficient route to graphene10.1021/jp202575j ↗
27. A brief review of corrosion protective films and coatings based on graphene and graphene oxide10.1016/j.jallcom.2018.06.133 ↗
28. A review on graphene-based polymer composite coatings for the corrosion protection of metals10.1515/corrrev-2018-0097 ↗
29. Ehsani, A., Heidari, A.A., and Sajedi, M. (2019). Graphene and graphene/polymer composites as the most efficient protective coatings for steel, aluminum and copper in corrosive media: A review of recent studies. Chem. Rec., 1–28.10.1002/tcr.201900021 ↗
30. A comprehensive review on graphene-based anti-corrosive coatings10.1016/j.cej.2019.05.034 ↗
31. Graphene: A multipurpose material for protective coatings10.1039/C5TA01010A ↗
32. A review on the use of graphene as a protective coating against corrosion
33. Protecting copper from electrochemical degradation by graphene coating10.1016/j.carbon.2012.04.048 ↗
34. Exploring graphene as a corrosion protection barrier10.1016/j.corsci.2011.12.003 ↗
35. Graphene: Corrosion-inhibiting coating10.1021/nn203507y ↗
36. Enhancement of seawater corrosion resistance in copper using acetone-derived graphene coating10.1039/C3NR05997A ↗
37. Synthesis of reduced graphene oxide (rGO) films onto carbon steel by cathodic electrophoretic deposition: Anticorrosive coating10.1016/j.carbon.2017.06.074 ↗
38. Electrophoretic deposition of graphene oxide on aluminum: Characterization, low thermal annealing, surface and anticorrosive properties10.1246/bcsj.20140402 ↗
39. Electrophoretic deposition of graphene oxide nanosheets on copper pipe for corrosion protection10.1007/s13369-019-03872-0 ↗
40. Al-Sammarraie, A.M.A., and Raheema, M.H. (2016). Reduced graphene oxide coating for corrosion protection enhancement of carbon steel in sea water. Iraqi J. Sci. Part B (Special Issue), 243–250.
41. Facile corrosion protection coating from graphene
42. Electrochemical and surface evaluation of the anti-corrosion properties of reduced graphene oxide10.1039/C5RA26948B ↗
43. Electrophoretic deposition of graphene oxide as a corrosion inhibitor for sintered NdFeB10.1016/j.apsusc.2013.04.130 ↗
44. Electrophoretic deposition of graphene oxide on mild carbon steel for anti-corrosion application10.1016/j.surfcoat.2014.06.007 ↗
45. Usha Kiran, N., Dey, S., Singh, B.P., and Besra, L. (2017). Graphene coating on copper by electrophoretic deposition for corrosion prevention. Coatings, 7.10.3390/coatings7120214 ↗
46. Graphene oxide coatings deposited on steel substrate using electrophoretic deposition and electrochemical evaluation of coatings in saline media10.4028/www.scientific.net/KEM.778.111 ↗
47. Electrochemical behavior of graphene coatings deposited on copper metal by electrophoretic deposition and chemical vapor deposition10.1016/j.surfcoat.2017.06.083 ↗
48. Anti-corrosion nickel/reduced graphene oxide-titanium dioxide coating for mild steel in organic acids
49. Corrosion resistance and micro-tribological properties of nickel hydroxide-graphene oxide composite coating10.1016/j.diamond.2017.04.015 ↗
50. Ni-graphene oxide composite coatings: Optimum graphene oxide for enhanced corrosion resistance10.1016/j.compositesb.2019.107145 ↗
51. Moshgi Asl, S., Afshar, A., and Yaghoubinezhad, Y. (2018). An Electrochemical Synthesis of Reduced Graphene Oxide/Zinc Nanocomposite Coating through Pulse-Potential Electrodeposition Technique and the Consequent Corrosion Resistance. Int. J. Corros., 2018.10.1155/2018/3028693 ↗
52. Electrodeposition of Co–Ni–P/graphene oxide composite coating with enhanced wear and corrosion resistance10.1557/jmr.2019.15 ↗
53. Sodium functionalized graphene oxide coated titanium plates for improved corrosion resistance and cell viability10.1016/j.apsusc.2013.12.114 ↗
54. Amudha, A., Shashikala, H.D., Asiq Rahman, O.S., Keshri, A.K., and Nagaraja, H.S. (2019). Effect of graphene oxide loading on plasma sprayed alumina-graphene oxide composites for improved anticorrosive and hydrophobic surface. Surf. Topogr. Metrol. Prop., 7.10.1088/2051-672X/ab2707 ↗
55. Graphene dip coatings: An effective anticorrosion barrier on aluminum10.1016/j.apsusc.2014.11.187 ↗
56. A study on corrosion resistant graphene films on low alloy steel10.1007/s13204-016-0530-2 ↗
57. High corrosion resistance of metal-graphene oxide-metal multilayer coatings10.1080/14786435.2019.1663375 ↗
58. A graphene oxide oxygen barrier film deposited via a self-assembly coating method10.1016/j.synthmet.2012.02.016 ↗
59. Oxidation resistance of graphene-coated Cu and Cu Ni alloy10.1021/nn103028d ↗
60. Thin film fabrication and simultaneous anodic reduction of deposited graphene oxide platelets by electrophoretic deposition10.1021/jz100080c ↗
61. A cautionary note on graphene anti-corrosion coatings10.1038/nnano.2017.187 ↗
62. Reduced Graphene Oxide/Amorphous Carbon P-N Junctions: Nanosecond Laser Patterning10.1021/acsami.9b05374 ↗
63. Gupta, S., Joshi, P., and Narayan, J. (2020). Electron mobility modulation in graphene oxide by controlling carbon melt lifetime. Carbon N. Y.10.1016/j.carbon.2020.07.073 ↗
64. Reduction of graphite oxide to graphene with laser irradiation10.1016/j.carbon.2012.10.017 ↗
65. Atomically thin polymer layer enhances toughness of graphene oxide monolayers10.1016/j.matt.2019.04.005 ↗
66. The role of water in mediating interfacial adhesion and shear strength in graphene oxide10.1021/acsnano.8b02373 ↗
67. Fabrication of nitrogen doped graphene oxide coatings: Experimental and theoretical approach for surface protection10.1039/C4RA13470B ↗
68. Fabrication of anti-corrosion nitrogen doped graphene oxide coatings by electrophoretic deposition10.1016/j.apsusc.2019.143914 ↗
69. Ren, S., Cui, M., Li, W., Pu, J., Xue, Q., and Wang, L. (2018). N-doping of graphene: Toward long-term corrosion protection of Cu. J. Mater. Chem. A.10.1039/C8TA05421E ↗
70. Carboxylic acids as corrosion inhibitors for aluminium in acidic and alkaline solutions10.1108/eb007262 ↗
71. Functionalized graphene oxide coating on Ti6Al4V alloy for improved biocompatibility and corrosion resistance10.1016/j.msec.2018.10.046 ↗
72. Electrochemical deposition of Mg(OH)2/GO composite films for corrosion protection of magnesium alloys10.1016/j.jma.2015.08.004 ↗
73. Liu, S., Zhu, Y., Zheng, X., Lai, X., Jia, R., and Yuan, X. (2020). Graphene oxide modified by zirconium dioxide to enhance the corrosion resistance of Zinc/Aluminum coatings. Diam. Relat. Mater., 107868.10.1016/j.diamond.2020.107868 ↗
74. Ahmed, M.K., Shahid, M., Khan, Z.A., Ammar, A.U., Saboor, A., Khalid, A., Hayat, A., Saeed, A., and Koohgilani, M. (2018). Electrochemical comparison of SAN/PANI/FLG and ZnO/GO coated cast iron subject to corrosive environments. Materials, 11.10.3390/ma11112239 ↗
75. Graphene-based anticorrosive coatings for copper10.1039/C7RA10167H ↗
76. Assessment of graphene oxide/epoxy nanocomposite as corrosion resistance coating on carbon steel10.1179/1743278214Y.0000000232 ↗
77. Exploring corrosion protection properties of solvent based epoxy-graphene oxide nanocomposite coatings on mild steel10.1016/j.corsci.2016.11.008 ↗
78. The effect of varying carboxylic-group content in reduced graphene oxides on the anticorrosive properties of PMMA/reduced graphene oxide composites10.3144/expresspolymlett.2014.92 ↗
79. Investigation of the anticorrosion properties of graphene oxide doped thin organic anticorrosion films for hot-dip galvanized steel10.1016/j.apsusc.2019.02.199 ↗
80. Room-temperature cured hydrophobic epoxy/graphene composites as corrosion inhibitor for cold-rolled steel10.1016/j.carbon.2013.08.052 ↗
81. Corrosion resistance of graphene-reinforced waterborne epoxy coatings10.1016/j.jmst.2015.12.017 ↗
82. Self-aligned graphene as anticorrosive barrier in waterborne polyurethane composite coatings10.1039/C4TA02262A ↗
83. The multiscale effects of graphene oxide on the corrosion resistance properties of waterborne alkyd resin coatings10.1557/jmr.2018.486 ↗
84. Comparative corrosion resistance of graphene sheets with different structures in waterborne epoxy coatings10.1016/j.colsurfa.2018.08.045 ↗
85. A mechanistic study of corrosion of graphene and low zinc- rich epoxy coatings on carbon steel in salt environment10.20964/2019.07.17 ↗
86. Liu, J., Liu, T., Guo, Z., Guo, N., Lei, Y., Chang, X., and Yin, Y. (2018). Promoting barrier performance and cathodic protection of zinc-rich epoxy primer via single-layer graphene. Polymers, 10.10.3390/polym10060591 ↗
87. Preparation of graphene nanoplate added zinc-rich epoxy coatings for enhanced sacrificial anode-based corrosion protection10.1016/j.corsci.2019.108120 ↗
88. Influence of functionalized multi-layer graphene on adhesion improvement and corrosion resistance performance of zinc-rich epoxy primer10.1080/1478422X.2018.1495679 ↗
89. Designing reduced graphene oxide/zinc rich epoxy composite coatings for improving the anticorrosion performance of carbon steel substrate10.1016/j.matdes.2019.107694 ↗
90. Ghauri, F.A., Raza, M.A., Baig, M.S., and Ibrahim, S. (2017). Corrosion study of the graphene oxide and reduced graphene oxide-based epoxy coatings. Mater. Res. Express, 4.10.1088/2053-1591/aa9aac ↗
91. Investigating the effect of SiO2-graphene oxide hybrid as inorganic nanofiller on corrosion protection properties of epoxy coatings10.1016/j.surfcoat.2017.01.013 ↗
92. Fabrication of silica-decorated graphene oxide nanohybrids and the properties of composite epoxy coatings research10.1016/j.apsusc.2015.11.088 ↗
93. A facile route of making silica nanoparticles-covered graphene oxide nanohybrids (SiO2–GO); fabrication of SiO2–GO/epoxy composite coating with superior barrier and corrosion protection performance10.1016/j.cej.2016.06.028 ↗
94. Excellent corrosion protection performance of epoxy composite coatings filled with amino-silane functionalized graphene oxide10.1016/j.surfcoat.2017.03.050 ↗
95. Distinctive roles of silane coupling agents on the corrosion inhibition performance of graphene oxide in epoxy coatings10.1016/j.porgcoat.2017.05.008 ↗
96. The role of functionalized graphene oxide on the mechanical and anti-corrosion properties of polyurethane coating10.1016/j.jtice.2018.02.009 ↗
97. Calovi, M., Rossi, S., Deflorian, F., Dirè, S., and Ceccato, R. (2020). Effect of functionalized graphene oxide concentration on the corrosion resistance properties provided by cataphoretic acrylic coatings. Mater. Chem. Phys., 239.10.1016/j.matchemphys.2019.121984 ↗
98. Reinforcing the corrosion protection property of epoxy coating by using graphene oxide–poly(urea–formaldehyde) composites10.1016/j.corsci.2017.04.019 ↗
99. Polyaniline-modified graphene oxide nanocomposites in epoxy coatings for enhancing the anticorrosion and antifouling properties10.1007/s11998-018-00173-3 ↗
100. Impact of size-controlled p-phenylenediamine (PPDA)-functionalized graphene oxide nanosheets on the GO-PPDA/Epoxy anti-corrosion, interfacial interactions and mechanical properties enhancement: Experimental and quantum mechanics investigations10.1016/j.cej.2017.11.019 ↗