journal article·2023-09-01Open access

Corrosion and Protection of Magnesium Alloys: Recent Advances and Future Perspectives

Tao Wu, Kemin Zhang

Coatings· Volume 13· Issue 9

Abstract

Magnesium alloys are of significant importance for lightweight manufacturing and weight-saving applications due to their high weight-to-strength ratio and good mechanical properties. However, the poor corrosion resistance of Mg alloys limits their large-scale practical application. An essential theoretical foundation for the development of corrosion-resistant magnesium alloys and their surface protection technologies can be elucidated via the investigation of the corrosion mechanism of the magnesium surface and the alteration of the corrosion rate after surface conversion and coating. This paper discusses some typical corrosion behaviors by originally describing the corrosion mechanism of magnesium alloys with and without different coatings and surface treatments. In order to predict the future theoretical investigation and research directions for the surface protection of magnesium alloys, some techniques and preventative measures to enhance the corrosion resistance of magnesium alloys are reviewed, and these protection techniques are intercompared for better understanding.
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Research context

OpenAlex topics: Magnesium Alloys: Properties and Applications · Aluminum Alloys Composites Properties · Corrosion Behavior and Inhibition

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

Affiliations

School of Materials Science and Engineering, Shanghai University of Engineering Science, Shanghai 201620, China

Funding

National Natural Science Foundation of China

References (100+)

Show source-provided references
1. Novel Magnesium Based Materials: Are They Reliable Drone Construction Materials? A Mini Review10.3389/fmats.2021.575530 ↗
2. Research on the optimal scheme of 3E game for lightweight body-in-white under environmental protection policy10.1177/16878140211037822 ↗
3. Approaching “stainless magnesium” by Ca micro-alloying10.1039/D0MH01380C ↗
4. Salaha, Z.F.M., Ammarullah, M.I., Abdullah, N., Aziz, A.U.A., Gan, H.S., Abdullah, A.H., Abdul Kadir, M.R., and Ramlee, M.H. (2023). Biomechanical Effects of the Porous Structure of Gyroid and Voronoi Hip Implants: A Finite Element Analysis Using an Experimentally Validated Model. Materials, 16.10.3390/ma16093298 ↗
5. Insight into synergetic effects of serum albumin and glucose on the biodegradation behavior of WE43 alloy in simulated body fluid10.1088/1748-605X/aca3e8 ↗
6. Development and Application of Plastic Processing Technologies of Magnesium Alloys
7. Numerical investigations of cutting temperature and cutting forces in cryogenic assisted turning of magnesium alloy10.1007/s00170-021-06989-5 ↗
8. Research advances of magnesium and magnesium alloys worldwide in 202110.1016/j.jma.2022.04.001 ↗
9. Enrichment efficiency of noble alloying elements on magnesium and effect on hydrogen evolution10.1016/j.corsci.2019.02.026 ↗
10. Latest research advances on magnesium and magnesium alloys worldwide10.1016/j.jma.2020.02.003 ↗
11. Fundamentals and advances in magnesium alloy corrosion10.1016/j.pmatsci.2017.04.011 ↗
12. Ammarullah, M.I., Afif, I.Y., Maula, M.I., Winarni, T.I., Tauviqirrahman, M., Akbar, I., Basri, H., van der Heide, E., and Jamari, J. (2021). Tresca Stress Simulation of Metal-on-Metal Total Hip Arthroplasty during Normal Walking Activity. Materials, 14.10.3390/ma14247554 ↗
13. Fervent Hype behind Magnesium Batteries: An Open Call to Synthetic Chemists-Electrolytes and Cathodes Needed10.1002/anie.201700673 ↗
14. Li, Y.G., Wei, Y.H., and Yang, S.Q. (2019). De-alloying Behavior of Mg-Al alloy in Sulphuric Acid and Acetic Acid Aqueous Solutions. Materials, 12.10.3390/ma12132046 ↗
15. Characterisation of Li in the surface film of a corrosion resistant Mg-Li(-Al-Y-Zr) alloy10.1016/j.apsusc.2019.07.167 ↗
16. Effect of pH on corrosion behavior of Al-Mg-Si alloy in NaCl solution
17. Understanding pitting corrosion behavior of AZ91 alloy and its MAO coating in 3.5% NaCl solution by cyclic potentiodynamic polarization10.1016/j.jma.2020.12.005 ↗
18. The effect of addition of hardystonite on the strength, ductility and corrosion resistance of WE43 magnesium alloy10.1016/j.jmrt.2021.05.027 ↗
19. Effect of heat treatment on microstructure and corrosion behavior of Mg-5Al-1Zn-1Sn magnesium alloy10.1016/j.corsci.2021.109759 ↗
20. Influence of indentation size on the corrosion behaviour of a phosphate conversion coated AZ80 magnesium alloy10.1016/j.jmrt.2021.07.091 ↗
21. Enhancing grain refinement and corrosion behavior in AZ31B magnesium alloy via stationary shoulder friction stir processing10.1016/j.jmrt.2022.02.059 ↗
22. Effect of yttrium modification on the corrosion behavior of AZ63 magnesium alloy in sodium chloride solution10.1016/j.jma.2020.02.027 ↗
23. Li, Z., Peng, Z., Qi, K., Li, H., Qiu, Y., and Guo, X. (2020). Microstructure and Corrosion of Cast Magnesium Alloy ZK60 in NaCl Solution. Materials, 13.10.3390/ma13173833 ↗
24. Chloride-induced filiform corrosion of organic-coated magnesium10.1016/j.electacta.2010.09.005 ↗
25. Real-time in situ observation of the corrosion process of die-cast AZ91D magnesium alloy in NaCl solutions under galvanostatic polarization10.1016/j.corsci.2021.109834 ↗
26. Galvanic Corrosion Behaviors of A508-III/304L Couples in Boric Acid Solution10.20964/2020.04.40 ↗
27. Correlation between the microstructure and corrosion behaviour of copper/316 L stainless-steel dissimilar-metal welded joints10.1016/j.corsci.2021.109729 ↗
28. Galvanic corrosion based on wire beam electrode technique: Progress and prospects10.1515/corrrev-2021-0100 ↗
29. Understanding Magnesium Corrosion—A Framework for Improved Alloy Performance10.1002/adem.200310405 ↗
30. Effect of Area Ratio on the Galvanic Corrosion of AZX611 Magnesium Alloy/A6N01 Aluminum Alloy Joint10.2320/matertrans.MT-L2021011 ↗
31. alpha-Mg/LPSO (Long-Period Stacking Ordered) phase interfaces as obstacles against dislocation slip in as-cast Mg-Zn-Y alloys10.1016/j.ijplas.2022.103294 ↗
32. Effect of long period stacking ordered structure on the biocorrosion resistance and osteogenesis ability of Mg–Zn–Y-Mn alloys10.1016/j.matlet.2023.134606 ↗
33. Tailoring the microstructural characteristic and improving the corrosion rate of Mg-Gd-Ni alloy by heat treatment with different volume fraction of LPSO phase10.1016/j.corsci.2022.110806 ↗
34. Corrosion, stress corrosion cracking and corrosion fatigue behavior of magnesium alloy bioimplants10.1515/corrrev-2021-0088 ↗
35. Yang, M., Liu, X.B., Zhang, Z.Y., and Song, Y.L. (2019). Stress Corrosion Behavior of AM50Gd Magnesium Alloy in Different Environments. Metals, 9.10.3390/met9050616 ↗
36. In situ study on the effect of stress on corrosion behavior of AZ91 magnesium alloy10.1108/ACMM-09-2021-2542 ↗
37. Stress corrosion cracking behavior of an as-extruded Mg-1.8Zn-0.5Zr-1.5Gd magnesium alloy in a simulated body fluid
38. Effect of Mg17Al12 precipitates on the microstructural changes and mechanical properties of hot compressed AZ91 magnesium alloy10.1016/j.msea.2009.05.032 ↗
39. TEM study of continuous precipitation in Mg-9 wt%Al-1 wt%Zn alloy10.1016/S1359-6454(00)00004-5 ↗
40. Solid solution strengthening in concentrated Mg-Al alloys10.1016/S1471-5317(01)00008-6 ↗
41. Effect of ECAP processing on corrosion resistance of AE21 and AE42 magnesium alloys10.1016/j.apsusc.2012.12.096 ↗
42. Effect of Al Content on the Corrosion Behavior of Extruded Dilute Mg-Al-Ca-Mn Alloy10.1007/s40195-022-01451-1 ↗
43. Effects of rare earth neodymium (Nd) and heat treatment on anti-corrosion behaviors of the AZ80 magnesium alloy10.1007/s42114-021-00356-4 ↗
44. Effects of the second phases on corrosion resistance of AZ91-xGd alloys treated with ultrasonic vibration10.1016/j.jallcom.2019.01.002 ↗
45. Romzi, M.A.F., Alias, J., and Ramli, M.I.M. (2021, January 20). Effect of Zinc (Zn) on the Microstructure and Corrosion Behaviour of Magnesium (Mg). Proceedings of the 2nd Innovative Manufacturing, Mechatronics and Materials Forum (IM3F), Pekan, Malaysia.
46. Mechanical properties, degradation performance and cytotoxicity of Mg-Zn-Ca biomedical alloys with different compositions10.1016/j.msec.2011.07.015 ↗
47. Corrosion and Wear Behavior of Mg-x%Zn-0.8%Zr Alloy
48. Influence of Ca and Zn on the microstructure and corrosion of biodegradable Mg-Ca-Zn alloys10.1016/j.corsci.2015.01.027 ↗
49. Lu, Y., Bradshaw, A., Chiu, Y.L., and Jones, I. (2013, January 24–26). Investigation of the Microstructure and Bio-corrosion Behaviour of Mg-Zn and Mg-Zn-Ca Alloys. Proceedings of the 6th International Light Metals Technology Conference (LMT 2013), Brunel University, BCAST, Old Windsor, England.
50. Improved Corrosion Resistance in AZ61 Magnesium Alloys Induced by Impurity Reduction10.1007/s40195-019-00914-2 ↗
51. Quantitative analysis on surface potentials of impurities and intermetallic compounds dispersed in Mg alloys using scanning Kelvin probe force microscopy and ultraviolet photoelectron spectroscopy10.1016/j.matchemphys.2022.125760 ↗
52. Effect of impurity Fe on corrosion behavior of AM50 and AM60 magnesium alloys10.1016/j.corsci.2012.09.021 ↗
53. Effect of Mn addition and refining process on Fe reduction of Mg-Mn alloys made from magnesium scrap10.1016/S1003-6326(20)65433-4 ↗
54. Effect of Mn Modification on the Corrosion Susceptibility of Mg-Mn Alloys by Magnesium Scrap10.1007/s40195-020-01058-4 ↗
55. The relation between Mn additions, microstructure and corrosion behavior of new wrought Mg-5Al alloys10.1016/j.matchar.2018.08.033 ↗
56. Chen, J., Li, Q.A., Zhang, Q., and Zhang, X.Y. (2015, January 13–14). The Corrosion Behaviours of AZ61 Magnesium Alloy with the Ca Addition. Proceedings of the Asia-Pacific Energy Equipment Engineering Research Conference (AP3ER), Zhuhai, China.10.2991/ap3er-15.2015.21 ↗
57. Tailoring the corrosion behavior and mechanism of AZ31 magnesium alloys by different Ca contents for marine application10.1016/j.corsci.2021.109842 ↗
58. Texture evolution and their effects on the mechanical properties of duplex Mg-Li alloy10.1016/j.jallcom.2016.01.174 ↗
59. Composition and microstructure dependent corrosion behaviour of Mg-Li alloys10.1016/j.electacta.2017.11.091 ↗
60. Study on the Mg-Li-Zn ternary alloy system with improved mechanical properties, good degradation performance and different responses to cells10.1016/j.actbio.2017.08.021 ↗
61. Effect of Y addition on removal of Fe impurity from magnesium alloys10.1016/j.scriptamat.2018.11.046 ↗
62. Existing forms of Gd in AZ91 magnesium alloy and its effects on mechanical properties10.1088/2053-1591/ab090b ↗
63. Effects of Al, Zn, and rare earth elements on flammability of magnesium alloys subjected to sonic burner-generated flame by Federal Aviation Administration standards10.1177/0954410020987758 ↗
64. Wang, X.B., Yao, M.T., Li, J.S., Zhang, K.X., Zhu, H., and Zheng, M.S. (2017). China’s Rare Earths Production Forecasting and Sustainable Development Policy Implications. Sustainability, 9.10.3390/su9061003 ↗
65. Evolution of Entrainment Defects Formed in Mg-Y Alloy Castings10.1007/s11661-020-05943-6 ↗
66. Effect of Oxide Bifilms on the Fracture Behavior of AM60B Mg Alloy10.1007/s12666-019-01841-7 ↗
67. Hydrogen in-situ refining method for preparing high purity gadolinium10.1016/j.jallcom.2015.06.222 ↗
68. Oxidation behavior of ignition-proof magnesium alloys with rare earth addition10.1016/j.jallcom.2010.10.168 ↗
69. Effects of Y Additions on the Microstructures and Mechanical Behaviours of as Cast Mg-xY-0.5Zr Alloys10.1002/adem.202101033 ↗
70. Effects of rare-earth elements Gd and Y on the solid solution strengthening of Mg alloys10.1016/j.jallcom.2009.02.131 ↗
71. Fabrication of a New Mg-50%Al4C3-6%Ce Master Alloy and Its Refinement Mechanism on AZ91D Alloy10.1016/S1875-5372(13)60032-6 ↗
72. Different grain refinement mechanisms of minor zirconium and cerium in magnesium alloys
73. Effect of the addition of low rare earth elements (lanthanum, neodymium, cerium) on the biodegradation and biocompatibility of magnesium10.1016/j.actbio.2014.09.041 ↗
74. Biodegradable magnesium alloys for orthopaedic applications: A review on corrosion, biocompatibility and surface modifications10.1016/j.msec.2016.06.020 ↗
75. Grain Refinement of As-Cast Mg-RE Alloys: Research Progress and Future Prospect
76. Microstructure modification and corrosion resistance enhancement of die-cast Mg-Al-Re alloy by Sr alloying10.1016/j.jma.2020.09.008 ↗
77. Degradation behaviour of magnesium-rare earth biomedical alloys10.1080/10667857.2016.1213550 ↗
78. Effect of Adding Rare Earth Elements Er and Gd on the Corrosion Residual Strength of Magnesium Alloy10.1515/phys-2019-0042 ↗
79. Physical foundations for surface treatment of materials with low energy, high current electron beams10.1016/S0257-8972(99)00604-0 ↗
80. Enhanced Surface Properties Induced by High Current Pulsed Electron Beam (HCPEB) Treatment10.4028/www.scientific.net/MSF.675-677.1205 ↗
81. Evolution of surface microstructure of Cu-50Cr alloy treated by high current pulsed electron beam10.1007/s11431-015-5774-7 ↗
82. Microstructure characteristics and properties of 40Cr steel treated by high current pulsed electron beam10.1179/175355511X13171168481358 ↗
83. Microstructural Modification of Brush-plated Nanocrystalline Cr by High Current Pulsed Electron Beam Irradiation10.4028/www.scientific.net/JNanoR.41.87 ↗
84. Microstructure and property modifications in surface layers of a Mg-4Sm-2Al-0.5Mn alloy induced by pulsed electron beam treatments10.1016/j.jma.2020.02.019 ↗
85. The features of the structural state and phase composition of the surface layer of aluminum alloy Al-Mg-Cu-Zn-Zr irradiated by the high current electron beam10.1016/j.nimb.2021.02.011 ↗
86. Improved corrosion resistance of Mg alloy AZ31B induced by selective evaporation of Mg using large pulsed electron beam irradiation10.1016/j.jmst.2018.12.004 ↗
87. Producing nano-grained and Al-enriched surface microstructure on AZ91 magnesium alloy by high current pulsed electron beam treatment10.1016/j.nimb.2016.03.035 ↗
88. Microstructure and corrosion resistance of a Mg2Sn-dispersed Mg alloy subjected to pulsed electron beam treatment10.1016/j.jma.2020.02.005 ↗
89. Surface microstructure and property modifications in a Mg-8Gd-3Y-0.5Zr magnesium alloy treated by high current pulsed electron beam10.1016/j.jallcom.2019.02.130 ↗
90. Surface microstructure modifications and in-vitro corrosion resistance improvement of a WE43 Mg alloy treated by pulsed electron beams10.1016/j.vacuum.2019.109132 ↗
91. Liu, B., Zheng, Y.Z., Xiao, G.Y., Chen, C.Z., and Lu, Y.P. (2021). Influence of Surface Post-Processing on Crystal Refinement and Characteristics of Hopeite Coating by Phosphating. Coatings, 11.10.3390/coatings11050541 ↗
92. Formation mechanisms of environmentally acceptable chemical conversion coatings for zinc: A review10.1007/s11998-018-0076-1 ↗
93. Alternative conversion coatings to chromate for the protection of magnesium alloys10.1016/j.corsci.2014.03.021 ↗
94. Hou, J.Y., Wang, B.J., Xu, D.K., Cui, L.J., and Sun, J. (2022). Effect of Surfactants on the Corrosion Protectability of Calcium Phosphate Conversion Coatings on Duplex Structured Mg-8Li (in Wt.%) Alloy. Coatings, 12.10.3390/coatings12081182 ↗
95. Phosphate chemical conversion coatings for magnesium alloys: A review10.1007/s11998-020-00335-2 ↗
96. Comparison of corrosion resistance and biocompatibility of magnesium phosphate (MgP), zinc phosphate (ZnP) and calcium phosphate (CaP) conversion coatings on Mg alloy10.1016/j.surfcoat.2020.125919 ↗
97. Corrosion behavior of molybdate conversion coatings on AZ31 magnesium alloy in NaCl solution10.1108/ACMM-01-2013-1232 ↗
98. Study of formation of molybdate conversion coatings on AZ31 magnesium alloy10.1179/0020296713Z.000000000132 ↗
99. Preparation of Antimony-doped Stannate Chemical Conversion Coating on AZ31B Mg Alloy10.1007/s12666-020-01996-8 ↗
100. Corrosion Behavior of Stannate Conversion Coatings on AZ31B Alloys and Their Initial Discharge Performance as Anodes for Seawater Batteries10.1149/1945-7111/ac1a56 ↗