journal article·2011-08Open access

SBA-15 mesoporous silica modified with rhodium by MDD method and its catalytic role for N2O decomposition reaction

Lucjan Chmielarz, Piotr Kuśtrowski, Marek Drozdek, Małgorzata Rutkowska, Roman Dziembaj, Marek Michalik, Pegie Cool, Etienne F. Vansant

Journal of Porous Materials· Volume 18· Issue 4

Abstract

SBA-15 mesoporous silicas modified with rhodium were studied as catalysts for the N 2 O decomposition reaction. Rhodium was deposited on SBA-15 by the Molecular Designed Dispersion (MDD) method using Rh(acac) 3 as a precursor of active phase. The same method was used for the deposition of Cu, Fe, Al and Ti. The SBA-15 support modified with metals were characterized with respect to metal loading (EPMA), structure (XRD), texture (BET), morphology (SEM), Rh dispersion (oxygen chemisorption), surface acidity (pyridine adsorption) and chemical nature of introduced copper and iron species (UV–vis-DRS). The rhodium-containing SBA-15 samples were found to be active catalysts for the N 2 O decomposition reaction. Deposition of Al on the Rh-loaded catalyst increased its activity. An opposite effect was observed for the samples modified with Cu and Fe.
Source: openalex_inverted_index · Quality: baseline

Research context

OpenAlex topics: Catalytic Processes in Materials Science · Mesoporous Materials and Catalysis · Catalysis and Oxidation Reactions

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

References (35)

Show source-provided references
1. J. Perez-Ramirez, G. Kapteijn, J.A. Moulijn, Appl. Catal. B 44, 117 (2003)10.1016/S0926-3373(03)00026-2 ↗
2. A. Takigawa, A. Matsunami, N. Arai, Y.Z. Peng, Energy 30, 475 (2005)10.1016/j.energy.2004.04.015 ↗
3. R.F. Weiss, J. Geophys. Res. 86, 7185 (1981)10.1029/JC086iC08p07185 ↗
4. G.M. Marnellos, E.A. Efthimiadis, I.A. Vasalos, Appl. Catal. B 46, 523 (2003)10.1016/S0926-3373(03)00292-3 ↗
5. E.V. Kondratenko, R. Kraehnert, J. Radnik, M. Baerns, J. Perez-Ramirez, Appl. Catal. B 298, 73 (2006)10.1016/j.apcata.2005.09.022 ↗
6. J. Oi, A. Obuchi, G.R. Bamwenda, A. Ogata, H. Yagita, S. Kushiyama, K. Mizuno, Appl. Catal. B 12, 277 (1997)10.1016/S0926-3373(96)00079-3 ↗
7. S. Tanaka, K. Yuzaki, S. Ito, H. Uetsuka, S. Kameoka, K. Kunimori, Catal. Today 63, 413 (2000)10.1016/S0920-5861(00)00486-7 ↗
8. K. Doi, Y.Y. Wu, R. Takeda, A. Matsunami, N. Arai, T. Tagawa, S. Goto, Appl. Catal. B 35, 43 (2001)10.1016/S0926-3373(01)00231-4 ↗
9. J. Haber, M. Nattich, T. Machej, Appl. Catal. B 77, 278 (2008)10.1016/j.apcatb.2007.07.028 ↗
10. Y. Chen, Y. Huang, J. Xiu, X. Han, X. Bao, Appl. Catal. A 273, 85 (2004)10.1016/j.apcata.2004.02.049 ↗
11. E. Zhao, J. Feng, Q. Huo, N. Melosh, G.H. Fredrickson, B.F. Chmelka, G.D. Stucky, Science 279, 548 (1988)10.1126/science.279.5350.548 ↗
12. P. Van Der Voort, M. Baltes, E.F. Vansant, J.M.G. White, Interface Sci. 5, 209 (1997)
13. P. Kuśtrowski, L. Chmielarz, R. Dziembaj, P. Cool, E.F. Vansant, J. Phys. Chem. B 109, 11552 (2005)10.1021/jp050696o ↗
14. E. Van Bavel, P. Cool, K. Aerts, E.F. Vansant, J. Phys. Chem. B 108, 5263 (2004)10.1021/jp049815a ↗
15. L. Chmielarz, P. Kuśtrowski, R. Dziembaj, P. Cool, E.F. Vansant, Appl. Catal. B 62, 369 (2006)10.1016/j.apcatb.2005.09.004 ↗
16. Y. Segura, L. Chmielarz, P. Kuśtrowski, P. Cool, R. Dziembaj, E.F. Vansant, Appl. Catal. B 61, 73 (2005)10.1016/j.apcatb.2005.04.011 ↗
17. L. Chmielarz, P. Kuśtrowski, R. Dziembaj, P. Cool, E.F. Vansant, Micropor. Mesopor. Mater. 127, 133 (2010)10.1016/j.micromeso.2009.07.003 ↗
18. P. Kuśtrowski, L. Chmielarz, R. Dziembaj, P. Cool, E.F. Vansant, J. Phys. Chem. A 109, 9808 (2005)10.1021/jp0535442 ↗
19. P. Kuśtrowski, L. Chmielarz, J. Surman, E. Bidzińska, R. Dziembaj, P. Cool, E.F. Vansant, J. Phys. Chem. A 109, 330 (2005)10.1021/jp0455881 ↗
20. J.C. Kenvin, M.G. White, M.B. Mitchell, Langmuir 7, 1198 (1991)10.1021/la00054a030 ↗
21. L. Chmielarz, P. Kuśtrowski, A. Rafalska-Łasocha, R. Dziembaj, Thermochim. Acta 395, 225–236 (2003)10.1016/S0040-6031(02)00214-9 ↗
22. T. Paryjczak, K.W. Jozwiak, J. Goralski, J. Chromatogr. 166, 65 (1978)10.1016/S0021-9673(00)92250-7 ↗
23. S.E. Wanke, N.A. Dougharty, J.Catal. 24, 367 (1972)10.1016/0021-9517(72)90122-4 ↗
24. I.V. Babich, Y.V. Plyuto, P. Van Der Voort, E.F. Vansant, J. Coll. Interface Sci. 189, 144 (1997)10.1006/jcis.1997.4798 ↗
25. S. Chylit, L. Haugland, E.A. Blekkan, Micropor. Mesopor. Mater. 111, 134 (2008)10.1016/j.micromeso.2007.07.020 ↗
26. R.S. Mulukutla, T. Shido, K. Asakura, T. Kogure, T. Iwasawa, Appl. Catal. A 228, 305 (2002)10.1016/S0926-860X(01)00992-9 ↗
27. R.T. Hughes, H.T. White, J. Phys. Chem. 71, 2192 (1967)10.1021/j100866a035 ↗
28. L. Chmielarz, P. Kustrowski, M. Kruszec, R. Dziembaj, P. Cool, E.F. Vansant, J. Por. Mat. 12, 18 (2005)
29. A.K. Aboul-Gheit, Solid State Ionics 101–103, 893 (1997)10.1016/S0167-2738(97)00218-X ↗
30. D.S. Muggli, J.F. Falconer, J. Catal. 191, 318 (2007)10.1006/jcat.2000.2821 ↗
31. E.P. Parry, J. Catal. 2, 371 (1963)10.1016/0021-9517(63)90102-7 ↗
32. M. Ramakrishna Prasad, G. Kamalakar, S.J. Kulkarni, K.V. Raghavan, J. Mol. Catal. A 180, 109 (2002)10.1016/S1381-1169(01)00412-5 ↗
33. S. Velu, K. Suzuki, M. Okazaki, M.P. Kapoor, T. Osaki, F. Ohashi, J. Catal. 194, 373 (2000)10.1006/jcat.2000.2940 ↗
34. M.V. Landau, E. Dafa, L.M. Kaliya, T. Sen, M. Hereskowitz, Micropor. Mesopor. Mater. 49, 65 (2001)10.1016/S1387-1811(01)00404-8 ↗
35. R.A. Reimer, S.C. Slaten, M. Seapan, M.W. Lower, P.E. Tomlinson, Environ. Progr. 13, 134 (1994)10.1002/ep.670130217 ↗