journal article·2017-02

Having it both ways: delicate hierarchical structure and robust mechanical stability on micro/nanomaterials with mesoporous silica coating

Zhi-Min Cui, Jing Hao, Chang-Yan Cao, Weiguo Song

Journal of Porous Materials· Volume 24· Issue 1
Publisher page

Abstract

Mesoporous silica (meso-SiO2) was coated on the micro/nanomaterials with hierarchical structure such as flowerlike Fe2O3, flowerlike MgO, SnO2 nanospheres, Co3O4 nanosheets and nanowires from a simple solution method. The structure of the nanomaterials and the silica coating before and after stirring in solution were characterizated by SEM and TEM. The results show that meso-SiO2 coating was an ideal method to enhance the structural stability of fragile nanomaterials. The catalysis stability of flowerlike MgO was also enhanced by the meso-SiO2 coating.
Source: openaire · Quality: candidate unverified · Source record ↗

Research context

OpenAlex topics: Gas Sensing Nanomaterials and Sensors · ZnO doping and properties · Magnesium Oxide Properties and Applications

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

References (24)

Show source-provided references
1. B.Z. Fang, J.H. Kim, M. Kim, J.S. Yu, Ordered hierarchical nanostructured carbon as a highly efficient cathode catalyst support in proton exchange membrane fuel cell. Chem. Mater. 21(5), 789–796 (2009)10.1021/cm801467y ↗
2. J.H. Lee, Gas sensors using hierarchical and hollow oxide nanostructures: overview. Sens. Actuator B Chem. 140(1), 319–336 (2009)10.1016/j.snb.2009.04.026 ↗
3. Y.F. Zhao, M. Wei, J. Lu, Z.L. Wang, X. Duan, Biotemplated hierarchical nanostructure of layered double hydroxides with improved photocatalysis performance. ACS Nano 3(12), 4009–4016 (2009)10.1021/nn901055d ↗
4. L.Y. Jiang, X.L. Wu, Y.G. Guo, L.J. Wan, SnO2-based hierarchical nanomicrostructures: facile synthesis and their applications in gas sensors and lithium-ion batteries. J. Phys. Chem. C 113(32), 14213–14219 (2009)10.1021/jp904209k ↗
5. L.S. Zhong, J.S. Hu, H.P. Liang, A.M. Cao, W.G. Song, L.J. Wan, Self-assembled 3D flowerlike iron oxide nanostructures and their application in water treatment. Adv. Mater. 18(18), 2426–2431 (2006)10.1002/adma.200600504 ↗
6. S.W. Bian, Z. Ma, Z.M. Cui, L.S. Zhang, F. Niu, W.G. Song, Synthesis of micrometer-sized nanostructured magnesium oxide and its high catalytic activity in the Claisen-Schmidt condensation reaction. J. Phys. Chem. C 112(30), 11340–11344 (2008)10.1021/jp802863j ↗
7. L.S. Zhong, J.S. Hu, A.M. Cao, Q. Liu, W.G. Song, L.J. Wan, 3D flowerlike ceria micro/nanocomposite structure and its application for water treatment and CO removal. Chem. Mater. 19(7), 1648–1655 (2007)10.1021/cm062471b ↗
8. M.V. Walter, N. Cheval, O. Liszka, M. Malkoch, A. Fahmi, Hybrid one-dimensional nanostructures: one-pot preparation of nanoparticle chains via directed self-assembly of in situ synthesized discrete Au nanoparticles. Langmuir 28(14), 5947–5955 (2012). doi: 10.1021/la300052610.1021/la3000526 ↗
9. Z. Chen, J. Moore, G. Radtke, H. Sirringhaus, S. O’Brien, Binary nanoparticle superlattices in the semiconductor–semiconductor system: CdTe and CdSe. J. Am. Chem. Soc. 129(50), 15702–15709 (2007). doi: 10.1021/ja076698z10.1021/ja076698z ↗
10. F.L. Yap, P. Thoniyot, S. Krishnan, S. Krishnamoorthy, Nanoparticle cluster arrays for high-performance SERS through directed self-assembly on flat substrates and on optical fibers. ACS Nano 6(3), 2056–2070 (2012). doi: 10.1021/nn203661n10.1021/nn203661n ↗
11. L. Shi, C.J. Plumley, C. Berkland, Biodegradable nanoparticle flocculates for dry powder aerosol formulation. Langmuir 23(22), 10897–10901 (2007). doi: 10.1021/la702009810.1021/la7020098 ↗
12. W.M. Zhang, X.L. Wu, J.S. Hu, Y.G. Guo, L.J. Wan, Carbon coated Fe3O4 nanospindles as a superior anode material for lithium-ion batteries. Adv. Funct. Mater. 18(24), 3941–3946 (2008). doi: 10.1002/adfm.20080138610.1002/adfm.200801386 ↗
13. W.M. Zhang, J.S. Hu, Y.G. Guo, S.F. Zheng, L.S. Zhong, W.G. Song, L.J. Wan, Tin-nanoparticles encapsulated in elastic hollow carbon spheres for high-performance anode material in lithium-ion batteries. Adv. Mater. 20(6), 1160–1164 (2008). doi: 10.1002/adma.20070136410.1002/adma.200701364 ↗
14. Z.M. Cui, Z. Chen, C.Y. Cao, W.G. Song, L. Jiang, Coating with mesoporous silica remarkably enhances the stability of the highly active yet fragile flower-like MgO catalyst for dimethyl carbonate synthesis. Chem. Commun. 49(54), 6093–6095 (2013). doi: 10.1039/c3cc42504e10.1039/c3cc42504e ↗
15. C.Q. Chen, J. Qu, C.Y. Cao, F. Niu, W.G. Song, CuO nanoclusters coated with mesoporous SiO2 as highly active and stable catalysts for olefin epoxidation. J. Mater. Chem. 21(15), 5774–5779 (2011). doi: 10.1039/c0jm04568c10.1039/c0jm04568c ↗
16. L.H. Hu, Q. Peng, Y.D. Li, Selective synthesis of Co3O4 nanocrystal with different shape and crystal plane effect on catalytic property for methane combustion. J. Am. Chem. Soc. 130(48), 16136–16137 (2008)10.1021/ja806400e ↗
17. A.J. Paula, D. Stefani, A.G. Souza, Y.A. Kim, M. Endo, O.L. Alves, Surface chemistry in the process of coating mesoporous SiO2 onto carbon nanotubes driven by the formation of Si–O–C bonds. Chem. Eur. J. 17(11), 3228–3237 (2011). doi: 10.1002/chem.20100245510.1002/chem.201002455 ↗
18. P.J.E. Harlick, A. Sayari, Applications of pore-expanded mesoporous silica. 5. Triamine grafted material with exceptional CO(2) dynamic and equilibrium adsorption performance. Ind. Eng. Chem. Res. 46(2), 446–458 (2007). doi: 10.1021/ie060774+10.1021/ie060774+ ↗
19. C.S. Gill, B.A. Price, C.W. Jones, Sulfonic acid-functionalized silica-coated magnetic nanoparticle catalysts. J. Catal. 251(1), 145–152 (2007). doi: 10.1016/j.jcat.2007.07.00710.1016/j.jcat.2007.07.007 ↗
20. Z. Chen, Z.-M. Cui, F. Niu, L. Jiang, W.-G. Song, Pd nanoparticles in silica hollow spheres with mesoporous walls: a nanoreactor with extremely high activity. Chem. Commun. 46(35), 6524–6526 (2010). doi: 10.1039/c0cc01786h10.1039/c0cc01786h ↗
21. J. Lee, J.C. Park, H. Song, A nanoreactor framework of a Au@SiO2 yolk/shell structure for catalytic reduction of p-nitrophenol. Adv. Mater. 20(8), 1523 (2008). doi: 10.1002/adma.20070233810.1002/adma.200702338 ↗
22. Z.F. Dou, C.Y. Cao, Y. Chen, W.G. Song, Fabrication of porous Co3O4 nanowires with high CO sensing performance at a low operating temperature. Chem. Commun. 50(94), 14889–14891 (2014). doi: 10.1039/c4cc05498a10.1039/c4cc05498a ↗
23. X.L. Xiao, X.F. Liu, H. Zhao, D.F. Chen, F.Z. Liu, J.H. Xiang, Z.B. Hu, Y.D. Li, Facile shape control of Co3O4 and the effect of the crystal plane on electrochemical performance. Adv. Mater. 24(42), 5762–5766 (2012). doi: 10.1002/adma.20120227110.1002/adma.201202271 ↗
24. G. Stoica, S. Abello, J. Perez-Ramirez, Synthesis of dimethyl carbonate by transesterification of ethylene carbonate over activated dawsonites. ChemSusChem 2(4), 301–304 (2009)10.1002/cssc.200800195 ↗