Adsorption behavior of amino functionalized MCM-41 on chlorogenic acid from Eucommia ulmoides leaves
Source abstract
Abstract
In this study, an amino-functionalized MCM-41 mesoporous material was prepared via hydrothermal method for the adsorption of chlorogenic acid from Eucommia ulmoides leaf extracts. The as prepared NH2-MCM-41 was characterized by X-ray diffraction, FT-IR spectroscopy and N2 adsorption–desorption isotherms. The results show that have good mesoporous structure. The batch experiments showed that adsorption process was more in line with the pseudo-second order kinetic model, which indicated the chemisorption played an important role in the adsorption process; Isothermal adsorption results showed that the adsorption of chlorogenic acid by NH2-MCM-41 was more consistent with Langmuir model, indicating that multilayer adsorption process occurred. Thermodynamic analyses demonstrated that the chlorogenic acid adsorption on NH2-MCM-41 abided by a spontaneous and exothermic procedure with entropy decreased. The purity of chlorogenic acid could be increased from 17.36 to 85.60% under the optimal conditions t = 9 h, temperature = 333 K, pH 6. These results indicated that NH2-MCM-41 is a promising adsorbent for the separation and purification of chlorogenic acid from Eucommia ulmoides leaf extracts.
Source: expertdata · Quality: candidate unverified · Source record ↗
Research context
OpenAlex topics: Analytical Chemistry and Chromatography · Phytochemistry and Biological Activities · Mesoporous Materials and Catalysis
SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.
References (39)
Show source-provided references
1. M. Rutkowska, E. Balcerczak, R. Wiechowski, M. Dubicka, M.A. Olszewska, Seasonal variation in phenylpropanoid biosynthesis and in vitro antioxidant activity of Sorbus domestica leaves: harvesting time optimisation for medicinal application. Ind. Crop. Prod. 156, 112858 (2020). https://doi.org/10.1016/j.indcrop.2020.11285810.1016/j.indcrop.2020.112858 ↗
2. X. Chen, M. Liu, P.F. Zhang, S.S.Y. Leung, J. Xia, Membrane-permeable antibacterial enzyme against multidrug-resistant Acinetobacter baumannii. Acs. Infect. Dis. 7, 2192–2204 (2021). https://doi.org/10.1021/acsinfecdis.1c0022210.1021/acsinfecdis.1c00222 ↗
3. R. Li, R. Ouda, C. Kimura, R. Narita, T. Watanabe, Conversion of beech wood into antiviral lignin-carbohydrate complexes by microwave acidolysis. ACS Sustain. Chem. Eng. 9, 9248–9256 (2021). https://doi.org/10.1021/acssuschemeng.1c0145010.1021/acssuschemeng.1c01450 ↗
4. A.C.C.M. Castro, F.B. Oda, M.G.J. Almeida-Cincotto, M.G. Davanço, B.G. Chiari-Andreo, R.M.B. Cicarelli, R.G. Peccinini, G.J. Zocolo, P.R.V. Ribeiro, Green coffee seed residue: a sustainable source of antioxidant compounds. Food Chem. 246, 48–57 (2018). https://doi.org/10.1016/j.foodchem.2017.10.15310.1016/j.foodchem.2017.10.153 ↗
5. J. Alamed, W. Chaiyasit, D.J. Mcclements, E.A. Decker, Relationships between free radical scavenging and antioxidant activity in foods. J. Agric. Food. Chem. 57, 2969–2976 (2009). https://doi.org/10.1021/jf803436c10.1021/jf803436c ↗
6. J.P. Cejas, A.S. Rosa, M.A. Nazareno, E.A. Disalvo, M.A. Frias, Interaction of chlorogenic acid with model lipid membranes and its influence on antiradical activity. BBA Biomembr. 1863, 183484 (2021). https://doi.org/10.1016/j.bbamem.2020.18348410.1016/j.bbamem.2020.183484 ↗
7. H.J. Kwon, J.Y. Chung, J.Y. Kim, O. Kwon, Comparison of 1-deoxynojirimycin and aqueous mulberry leaf extract with emphasis on postprandial hypoglycemic effects: in vivo and in vitro studies. J. Agric. Food. Chem. 59, 3014–3019 (2011). https://doi.org/10.1021/jf103463f10.1021/jf103463f ↗
8. A. Rodriguez-Mateos, T. Cifuentes-Gomez, S. Tabatabaee, C. Lecras, J.P.E. Spencer, Procyanidin, anthocyanin, and chlorogenic acid contents of highbush and lowbush blueberries. J. Agric. Food. Chem. 60, 5772–5778 (2012). https://doi.org/10.1021/jf203812w10.1021/jf203812w ↗
9. H. Jiang, J. Li, L. Chen, Z. Wang, Adsorption and desorption of chlorogenic acid by macroporous adsorbent resins during extraction of Eucommia ulmoides leaves. Ind. Crop. Prod. 149, 112336 (2020). https://doi.org/10.1016/j.indcrop.2020.11233610.1016/j.indcrop.2020.112336 ↗
10. G.T. Qin, J. Ma, W. Wei, J.J. Li, F.Q. Yue, The enrichment of chlorogenic acid from Eucommia ulmoides leaves extract by mesoporous carbons. J. Chromatogr. B 6, 1087–1088 (2018). https://doi.org/10.1016/j.jchromb.2018.04.03610.1016/j.jchromb.2018.04.036 ↗
11. Y.L. Liu, J. Guo, Z.B. Xiao, K. Song, Adsorption of Chelerythrine from Toddalia asiatica (L.) Lam by ZSM-5. Adv. Polym. Technol. 2020, 1–9 (2020). https://doi.org/10.1155/2020/940892110.1155/2020/9408921 ↗
12. N.A. Atiyah, T.M. Albayati, M.A. Atiya, Functionalization of mesoporous MCM-41 for the delivery of curcumin as an anti-inflammatory therapy. Adv. Powder. Technol. 33, 103417 (2022). https://doi.org/10.1016/j.apt.2021.10341710.1016/j.apt.2021.103417 ↗
13. H.J. Al-Jaaf, N.S. Ali, S.M. Alardhi, T.M. Albayati, Implementing eggplant peels as an efficient bio-adsorbent for treatment of oily domestic wastewater. Desalin. Water Treat. 245, 226–237 (2022). https://doi.org/10.5004/dwt.2022.2798610.5004/dwt.2022.27986 ↗
14. W.Y. Lin, Q. Cai, W.Q. Pang, Y. Yue, Preparation of aluminosilicate MCM-41 in desirable forms via a novel co-assemble route. Chem. Commun. 22, 2473–2474 (1998). https://doi.org/10.1039/a807786j10.1039/a807786j ↗
15. V. Kocherbitov, V. Alfredsson, Hydration of MCM-41 studied by sorption calorimetry. J. Phys. Chem. C. 111, 12906–12913 (2007). https://doi.org/10.1021/jp072474r10.1021/jp072474r ↗
16. B. Zhang, T. Wu, D.J. Sun, W.X. Chen, G.R. Li, Y.J. Li, NH2-MCM-41 supported on nitrogen-doped graphene as bifunctional composites for removing phenol compounds: synergistic effect between catalytic degradation and adsorption. Carbon 147, 312–322 (2019). https://doi.org/10.1016/j.Carbon.2019.02.08410.1016/j.Carbon.2019.02.084 ↗
17. S.O. Akpotu, B. Moodley, Application of as-synthesised MCM-41 and MCM-41 wrapped with reduced graphene oxide/graphene oxide in the remediation of acetaminophen and aspirin from aqueous system. J. Environ. Manag. 209, 205–215 (2017). https://doi.org/10.1016/j.jenvman.2017.12.03710.1016/j.jenvman.2017.12.037 ↗
18. S.L. Wu, X.D. Zhao, Y.H. Li, C.T. Zhao, Q.J. Du, J.K. Sun, Y.H. Wang, X.J. Peng, Y.Z. Xia, Z.H. Wang, L.H. Xia, Adsorption of ciprofloxacin onto biocomposite fibers of graphene oxide/calcium alginate. Chem. Eng. J. 230, 389–395 (2013). https://doi.org/10.1016/j.cej.2013.06.07210.1016/j.cej.2013.06.072 ↗
19. E.H. Khader, T.J. Mohammed, T.M. Albayati, Comparative performance between rice husk and granular activated carbon for the removal of azo tartrazine dye from aqueous solution. Desalin. Water Treat. 229, 372–383 (2021). https://doi.org/10.5004/dwt.2021.2737410.5004/dwt.2021.27374 ↗
20. L.T. Tran, H.V. Tran, T.D. Le, G.L. Bach, L.D. Tran, Studying Ni (II) adsorption of magnetite/graphene oxide/chitosan nanocomposite. Adv. Polym. Technol. 2019, 1–9 (2019). https://doi.org/10.1155/2019/812435110.1155/2019/8124351 ↗
21. G.P. Hao, W.C. Li, S. Wang, S.F. Zhang, A.H. Lu, Tubular structured ordered mesoporous carbon as an efficient sorbent for the removal of dyes from aqueous solutions. Carbon 48, 3330–3339 (2019). https://doi.org/10.1016/j.carbon.2010.05.01110.1016/j.carbon.2010.05.011 ↗
22. F. Zhang, J. Lan, Z.S. Zhao, Y. Yang, R.Q. Tan, W.J. Song, Removal of heavy metal ions from aqueous solution using Fe3O4-SiO2-poly(1,2-diaminobenzene) core-shell sub-micron particles. J. Colloid. Interface Sci. 387, 205–212 (2012). https://doi.org/10.1016/j.jcis.2012.07.06610.1016/j.jcis.2012.07.066 ↗
23. W.P. Yang, L. Zhou, J.G. Yu, P. Ding, X.Q. Chen, F.P. Jiao, Preparation of diamine modified mesoporous silica on multiwalled carbon nanotubes for the adsorption of heavy metals in aqueous solution. Appl. Surf. Sci. 282, 38–45 (2013). https://doi.org/10.1016/j.apsusc.2013.05.02810.1016/j.apsusc.2013.05.028 ↗
24. M. Dinari, R. Soltani, G. Mohammadnezhad, Kinetics and thermodynamic study on novel modified-mesoporous silica MCM-41/polymer matrix nanocomposites: effective adsorbents for trace Cr VI removal. J. Chem. Eng. Data 62, 2316–2329 (2017). https://doi.org/10.1021/acs.jced.7b0019710.1021/acs.jced.7b00197 ↗
25. U.G. Singh, R.T. Williams, R.K. Hallam, G.C. Allen, Exploring the distributionof copper-Schiff base complex covalently anchored onto the surface of mesoporous MCM-41 silica. J. Solid. State. Chem. 178, 3405–3413 (2005). https://doi.org/10.1016/j.jssc.2005.08.02310.1016/j.jssc.2005.08.023 ↗
26. H.J. Wang, D.W. Rao, M.J. Meng, L. Liu, Y.H. Feng, Modulating depth of 1,2-propanediol oxidation over La (III) doped MCM-41 supported binary Pd and Bi nanoparticles for selective production of C3 carbonyl compounds. Appl. Surf. Sci. 554, 149528 (2021). https://doi.org/10.1016/j.apsusc.2021.14952810.1016/j.apsusc.2021.149528 ↗
27. S. Sert, M. Eral, Uranium adsorption studies on aminopropyl modified mesoporous sorbent (NH2-MCM-41) using statistical design method. J. Nucl. Mater. 406, 285–292 (2010). https://doi.org/10.1016/j.jnucmat.2010.08.02410.1016/j.jnucmat.2010.08.024 ↗
28. P. Pal, S.K. Rastogi, C.M. Gibson, D.E. Aston, A.L. Branen, T.B. Bitterwolf, Fluorescence sensing of zinc (II) using ordered mesoporous silica material (MCM-41) functionalized with N-(quinolin-8-yl)-2-[3-(triethoxysilyl) propylamino] acetamide. ACS Appl. Mater. Interfaces 3, 279–286 (2011). https://doi.org/10.1021/am100923x10.1021/am100923x ↗
29. A.A. Sabri, T.M. Albayati, R.A. Alazawi, Synthesis of ordered mesoporous SBA-15 and its adsorption of methylene blue. J. Korean Chem. Eng. 32, 1835–1841 (2015). https://doi.org/10.1007/s11814-014-0390-y10.1007/s11814-014-0390-y ↗
30. N. Li, W.Y. Cheng, Y.Z. Pan, Adsorption of naphthalene on modified zeolite from aqueous solution. J. Environ. Prot. Ecol. 4, 416–425 (2017). https://doi.org/10.4236/jep.2017.8403010.4236/jep.2017.84030 ↗
31. S. Sharma, G. Sharma, A. Kumar, T.S. AlGarni, M. Naushad, Z.A. ALOthman, F.J. Stadler, Adsorption of cationic dyes onto carrageenan and itaconic acid-based superabsorbent hydrogel: synthesis, characterization and isotherm analysis. J. Hazard Mater. 421, 126729 (2022). https://doi.org/10.1016/j.jhazmat.2021.12672910.1016/j.jhazmat.2021.126729 ↗
32. F. Zhou, S.H. Huang, X. Liu, J. Feng, Q. Liu, Z.W. Wang, C.C. Li, Y.L. Xu, Adsorption kinetics and thermodynamics of rare earth on modified Montmorillonite. Colloid. Surf. A 627, 127063 (2022). https://doi.org/10.1016/j.colsurfa.2021.12706310.1016/j.colsurfa.2021.127063 ↗
33. P.C. Sun, Y. Liu, Y.T. Yi, H.J. Li, P. Fan, C.H. Xia, Preliminary enrichment and separation of chlorogenic acid from Helianthus tuberosus L. leaves extract by macroporous resins. Food Chem. 168, 55–62 (2015). https://doi.org/10.1016/j.foodchem.2014.07.03810.1016/j.foodchem.2014.07.038 ↗
34. T.A. Khan, E.A. Khan, Shahjahan, removal of basic dyes from aqueous solution by adsorption onto binary iron-manganese oxide coated kaolinite: non-linear isotherm and kinetics modeling. Appl. Clay. Sci. 107, 70–77 (2015). https://doi.org/10.1016/j.clay.2015.01.00510.1016/j.clay.2015.01.005 ↗
35. R.B. Yu, Z.C. Wu, High adsorption for ofloxacin and reusability by the use of ZIF-8 for wastewater treatment. Micropor. Mesopor. Mat. 308, 110494 (2020). https://doi.org/10.1016/j.micromeso.2020.11049410.1016/j.micromeso.2020.110494 ↗
36. H. Javadian, M. Taghavi, Application of novel Polypyrrole/thiol-functionalized zeolite Beta/MCM-41 type mesoporous silica nanocomposite for adsorption of Hg2+ from aqueous solution and industrial wastewater: kinetic, isotherm and thermodynamic studies. Appl. Surf. Sci. 289, 487–494 (2014). https://doi.org/10.1016/j.apsusc.2013.11.02010.1016/j.apsusc.2013.11.020 ↗
37. E.C. Nnadozie, P.A. Ajibade, Adsorption, kinetic and mechanistic studies of Pb(II) and Cr(VI) ions using APTES functionalized magnetic biochar. Microporous Mesoporous Mater. 309, 110573 (2020). https://doi.org/10.1016/j.micromeso.2020.11057310.1016/j.micromeso.2020.110573 ↗
38. P.F. Li, L.T. Qin, T. Wang, L.X. Dai, H. Li, J.X. Jiang, J.Y. Zhou, H. Li, X.Q. Cheng, F.H. Lei, Preparation and adsorption characteristics of rosin-based polymer microspheres for berberine hydrochloride and separation of total alkaloids from coptidis rhizoma. Chem. Eng. J. 392, 123707 (2020). https://doi.org/10.1016/j.cej.2019.12370710.1016/j.cej.2019.123707 ↗
39. S.M. Alardhi, J.M. Alrubaye, T.M. Albayati, Removal of methyl green dye from simulated waste water using hollow fiber ultrafiltration membrane. M. S. E. 928, 052020 (2020). https://doi.org/10.1088/1757-899X/928/5/05202010.1088/1757-899X/928/5/052020 ↗