journal article·2022-04

Magnetic composite sponges based on chitosan and whey protein modified magnetite nanoparticles for dye removal from water

Kwandee Chamchoy, Apichaya Thiangtrong, Penwisa Pisitsak, Chutima Vanichvattanadecha

Journal of Porous Materials· Volume 29· Issue 2
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Abstract

In this work, a novel application of whey protein isolate (WPI) for surface coating of magnetic nanoparticles (MNPs) is demonstrated. WPI-modified MNPs (WPI-MNPs) were prepared via chemical co-precipitation of ferrous and ferric salts. A mixture of chitosan and MNPs (or WPI-MNPs) was subject to lyophilization to produce magnetic composite sponges (designated as Chi-MNPs, and Chi-WPI-MNPs, respectively). Scanning electron microscopy (SEM) images clearly show improvement in dispersibility of WPI-MNPs on Chi-WPI-MNPs compared to the uncoated samples. The saturation magnetization profiles of all MNP samples, which were measured by a vibrating sample magnetometer (VSM), show superparamagnetic properties. The pore structure determined by mercury intrusion porosimeter (MIP) reveals a larger average pore size for Chi-WPI-MNPs compared to Chi-MNPs. The percentages for methylene blue (MB) dye removal of Chi-WPI-MNPs increased by 23.3% and 12.7% when compared to those of neat and Chi-MNPs sponges, respectively. The adsorption isotherms of all sponges can be described by both Langmuir and Freundlich models. The sponge containing WPI-MNPs could be reused with a 23.7% reduction in adsorption efficiency after 4 cycles of use.
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Research context

OpenAlex topics: Pickering emulsions and particle stabilization · Adsorption and biosorption for pollutant removal · Nanomaterials for catalytic reactions

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

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