journal article·2007-06-21Open access

Temperature programmed desorption of n-hexane and n-heptane from MFI and FAU zeolites

Wacław Makowski, Dorota Majda

Journal of Porous Materials· Volume 14· Issue 1

Abstract

TPD studies of n-hexane and n-heptane from NaX, Y and ZSM-5 (Na+ or H+ exchanged) in the experimental system with a TCD detector were performed, using pure He or He/n-alkane mixture as a carrier gas. The TPD profiles with one desorption peak for Y and two peaks for ZSM-5, measured using He/hydrocarbon mixture, were similar to the previously reported equilibrated thermodesorption results. TPD profiles were accurately fitted with a model based on the equilibrium control of the desorption and the adsorption functions derived from the Langmuir or dual site Langmuir isotherms.
Source: openaire · Quality: candidate unverified · Source record ↗

Research context

OpenAlex topics: Zeolite Catalysis and Synthesis · Catalysis and Oxidation Reactions · Phase Equilibria and Thermodynamics

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

References (23)

Show source-provided references
1. H. Du, M. Kalyanaraman, M.A. Camblor, D.H. Olson, Micropor. Mesopor. Mater. 40, 305 (2000)10.1016/S1387-1811(00)00269-9 ↗
2. O. Inel, D. Topaloglu, A. Askin, F. Tumsek, Chem. Eng. J. 88, 255 (2002)10.1016/S1385-8947(02)00026-8 ↗
3. F. Tumsek, O. Inel, Chem. Eng. J. 94, 57 (2003)10.1016/S1385-8947(03)00046-9 ↗
4. D.H. Olson, M.A. Camblor, L.A. Villaescusa, G.H. Kuehl, Micropor. Mesopor. Mater. 67, 27 (2004)10.1016/j.micromeso.2003.09.025 ↗
5. R.E. Richards, L.V.C. Rees, Langmuir 3, 335 (1987)10.1021/la00075a009 ↗
6. W.J.M. van Well, J.P. Wolthuizen, B. Smit, J.H.C. van Hooff, R.A. van Santen, Angew. Chem. Int. Ed. Engl. 34, 2543 (1995)10.1002/anie.199525431 ↗
7. F. Eder, J.A. Lercher, Zeolites 18, 75 (1997)10.1016/S0144-2449(96)00127-3 ↗
8. W. Zhu, F. Kapteijn, B. van der Linden, J.A. Moulijn, Phys. Chem. Chem. Phys. 3, 1755 (2001)10.1039/b100941i ↗
9. D.H. Olson, P.T. Reischman, Zeolites 17, 434 (1996)10.1016/S0144-2449(96)00087-5 ↗
10. B. Smit, T. L. M. Maesen, Nature 374, 42 (1995)10.1038/374042a0 ↗
11. B. Millot, A. Methivier, H. Jobic, J. Phys. Chem. 102, 3210 (1998)10.1021/jp972578+ ↗
12. B. Millot, A. Methivier, H. Jobic, I. Clemencon, B. Rebours, Langmuir 15, 2534 (1999)10.1021/la981344u ↗
13. W. Makowski, D. Majda, Thermochim. Acta 412, 131 (2004)10.1016/j.tca.2003.09.003 ↗
14. R.J. Cvetanovic, Y. Amenomiya, Adv. Catal. 17, 103 (1967)10.1016/S0360-0564(08)60686-0 ↗
15. R.J. Gorte, Catal. Today 28, 405 (1996)10.1016/S0920-5861(96)00249-0 ↗
16. W. Makowski, D. Majda, Appl. Surf. Sci. 252, 707–715 (2005)10.1016/j.apsusc.2005.02.052 ↗
17. D. Majda, W. Makowski, Stud. Surf. Sci. Catal. 158, 1161 (2005)10.1016/S0167-2991(05)80461-6 ↗
18. Y. Yang, L.V.C. Rees, Micropor. Mater. 12, 117 (1997)10.1016/S0927-6513(97)00071-0 ↗
19. S. Calero, D. Dubbeldam, R. Krishna, B. Smit, T.J.H. Vlugt, J.F.M. Denayer, J.A. Martens, T.L.M. Maesen, J. Am. Chem. Soc. 126, 11377 (2004)10.1021/ja0476056 ↗
20. W. Zhu, F. Kapteijn, J.A. Moulijn, Micropor. Mesopor. Mater. 47, 157 (2001)10.1016/S1387-1811(01)00372-9 ↗
21. E. García-Pérez, I.M. Torrens, S. Lago, R. Krishna, B. Smit, S. Calero, Stud. Surf. Sci. Catal. 158, 1097 (2005)10.1016/S0167-2991(05)80453-7 ↗
22. I.C. Arik, J.F. Denayer, G.V. Baron, Micropor. Mesopor. Mater. 60, 111 (2003)10.1016/S1387-1811(03)00332-9 ↗
23. A.G. Stepanov, T.O. Shegai, M.V. Luzgin, H. Jobic, Eur. Phys. J. E12, 57 (2003)