journal article·1992-03-01

Pre-tinning and Flux Considerations on the Reliability of Solder Surfaces

A.J. Sunwoo, J.W. Morris, G.K. Lucey

Circuit World· Volume 18· Issue 4
Publisher page

Abstract

The kinetics of wetting were studied on several different prepared surfaces of copper (Cu) to simulate the microstructure observed in pre-tinned Cu-clad printed circuit boards. The results illustrate the effectiveness of pre-tinning in maintaining the solderability of Cu surfaces. Pre-tinning with Pb-rich solder (95Pb-5Sn) is particularly effective since solderability is preserved even after a relatively long ageing treatment. On the other hand, pre-tinning with eutectic solder risks the loss of solderability during ageing or baking due to surface exposure of an ε-phase intermetallic with poor wetting properties. The results also confirm the presence of carbon in pre-tinned specimens due to the use of flux. The effect of carbon on solderability is not yet known.
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Research context

OpenAlex topics: Electronic Packaging and Soldering Technologies · 3D IC and TSV technologies · Aluminum Alloys Composites Properties

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

Affiliations

Lawrence Livermore National Laboratory, Livermore, California, USA

Center for Advanced Materials, Lawrence Berkeley Laboratory, and Department of Materials Science, University of California, Berkeley, California, USA

Harry Diamond Laboratories, US Army, Adelphi, Maryland, USA

References (13)

Show source-provided references
1. Davis, P. E., Kay, P. J. and Muckett, S. J. 'Intermetallic Compound Growth and Solderability,' Plating & Surface Finishing, Vol.69, pp.72-76 (1982).
2. Unsworth, D. A. and Mackay, C. A.' A Preliminary Report on Growth of Compound Layers on Various Metal Bases Plated with Tin and its Alloys,' Transactions Institute of Metal Finishing, Vol.51, pp.85-90 (1973).
3. 10.1149/1.212742510.1149/1.2127425 ↗
4. Ohriner E. K. · 1987 · 66 · 191s
5. Zakraysek, L., The Effect of Temperature and Stress on Tin-Rich Solder Alloys,' Welding Journal, Vol.36, pp.522s-527s (1971).
6. Zakraysek, L. 'Intermetallic Growth in Tin-Rich Solders,' Welding Journal, Vol.37, pp.536s-541s (1972).
7. Warwick M. E. · 9
8. Saunders, N. and Miodownik, A. P. 'The Cu-Sn System,' Bulletin ofAlloy Phase Diagrams, Vol.11, pp.278-287 (1990).10.1007/BF03029299 ↗
9. Sunwoo A. J. · Transactions A · 1992 · 23 · 1323
10. Reed J. R. · 1991 · 16
11. Sunwoo, A. J., Morris, Jr, J. W. and Lucey, Jr, G. K. 'Preliminary Observation of Carbon in Pre-tinned Specimens.' The Metal Science of Joining, Conference Proceedings, The Materials Society, pp.325-329 (1992).
12. Tench D.
13. Chang, C.A. 'High-temperature Interaction Studies of C/Cu/SiO2/Si and Related Structures, 'Journal of AppliedPhysics, Vol.66,pp.1163-1169 (1989).10.1063/1.344454 ↗