journal article·2023-07Open access

Front Cover: Synthesis of Ce‐Doped MIL‐125‐NH2 for Promoting Catalytic H2O2 Production from Water and O2 under Visible Light Irradiation (ChemNanoMat 7/2023)

Baolin Yan, Shen Hu, Chunyan Bu, Yi'an Peng, Huaize Han, Xinghang Xu, Yihan Liu, Jianxiang Yu, Yuhua Dai

ChemNanoMat· Volume 9· Issue 7

Abstract

Ce-doped MIL-125-NH2 photocatalysts (Ce/TiMOFs) were synthesized by a facile impregnation-coordination method, during which the doped Ce species could not only extend the visible-light absorption edge but also provide new reactive sites for promoting the charge transfer and selectivity of two-electron O2 reduction. The optimal Ce/TiMOFs-0.010 achieved a rate of H2O2 yield of 2464 μM h-1 g-1 with ∼3.4-fold improvement compared to TiMOFs, attributed to the faster conversion rate of the main reactive oxygen intermediates (⋅O2-) and improved average transfer electron number. More information can be found in the Research Article by Baolin Yan et al.
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Research context

OpenAlex topics: Advanced Photocatalysis Techniques · Advanced Nanomaterials in Catalysis · Catalytic Processes in Materials Science

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Affiliations

Beijing Key Laboratory of Special Elastomer Composite Materials College of New Materials and Chemical Engineering Beijing Institute of Petrochemical Technology Beijing 102617 China

References

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