journal article·2021-12Open access

Front Cover: An Efficient Method for Covalent Surface Functionalization of Ultrasmall Metallic Nanoparticles by Surface Azidation Followed by Copper‐Catalyzed Azide‐Alkyne Cycloaddition (Click Chemistry) (ChemNanoMat 12/2021)

Kai Klein, Kateryna Loza, Marc Heggen, Matthias Epple

ChemNanoMat· Volume 7· Issue 12

Abstract

Ultrasmall gold nanoparticles can be conveniently surface-functionalized by azidation of surface-bound glutathione. A subsequent click reaction leads to covalently attached molecules in high yield with up to 50 mg per synthesis. The nature of the particle surface can be probed in detail by both 1H and 13C NMR spectroscopy, as well as by two-dimensional NMR spectroscopy. More information can be found in the Full Paper by Matthias Epple et al.
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Research context

OpenAlex topics: Machine Learning in Materials Science · Nanocluster Synthesis and Applications · Quantum Dots Synthesis And Properties

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Affiliations

Inorganic Chemistry and Centre for Nanointegration Duisburg-Essen (CeNIDE) University of Duisburg-Essen Universitaetsstr. 5–7 45117 Essen Germany

Ernst Ruska Centre for Microscopy and Spectroscopy with Electrons Forschungszentrum Jülich GmbH 52428 Jülich Germany

References

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