journal article·2016-11Open access

Cover Picture: Direct Correlation between Molecular Cross‐linking and Macroscopic Mechanical Properties for Green Solids of Deoxyribonucleic Acids (ChemNanoMat 11/2016)

Yuma Morimitsu, Hisao Matsuno, Noboru Ohta, Hiroshi Sekiguchi, Keiji Tanaka

ChemNanoMat· Volume 2· Issue 11

Abstract

Double-stranded deoxyribonucleic acids (DNAs) were intermolecularly cross-linked using 2,5-hexanedione based on reductive amination induced by 2-picoline borane in aqueous phase. Atomic force microscopy revealed that while DNA chains near cross-linking points were denatured to single-strands, DNA chains not near cross-linking points maintained B-form double-strands, which is the most typical conformation. A transparent, self-supported, and mechanically toughened solid film was obtained from the cross-linked DNAs by a simple solvent-casting method. More information can be found in the Communication by H. Matsuno, K. Tanaka et al. on page 1023 in Issue 11, 2016 (DOI: 10.1002/cnma.201600222).
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Research context

OpenAlex topics: Biopolymer Synthesis and Applications

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Affiliations

Department of Applied Chemistry Kyushu University 744 Motooka Nishi-ku Fukuoka 819-0395 Japan

Japan Synchrotron Radiation Research Institute (JASRI) 1-1-1 Kouto Sayo-cho, Sayo-gun Hyogo 679-5198 Japan

International Institute for Carbon-Neutral Energy Research (WPI-I2CNER) Kyushu University 744 Motooka Nishi-ku Fukuoka 819-0395 Japan

References

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