An N‐Annulated, Rylene‐based Twistacene as Scaffold for Long Supramolecular Polymers
Source abstract
Abstract
Abstract The multistep synthesis of the N‐annulated rylenecarbodiimide 1 is reported. The large π‐surface and the operation of a fourfold array of H‐bonding interactions between the trialkoxybenzamide units yield highly stable supramolecular polymers, the stability of which has been quantified by applying the denaturation model. The operation of these non‐covalent interactions affords long 1D‐supramolecular polymers that have been visualized by atomic force microscopy (AFM).
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Research context
OpenAlex topics: Supramolecular Self-Assembly in Materials · Polydiacetylene-based materials and applications · Supramolecular Chemistry and Complexes
SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.
Affiliations
Departamento de Química Orgánica, Facultad de CC Químicas Universidad Complutense de Madrid Ciudad Universitaria, s/n 28040- Madrid Spain
Funding
Comunidad de Madrid · Universidad Complutense de Madrid
References (40)
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