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journal article·2024-11

First Example of Single‐Crystal Nanodiamonds Immobilized in Porous SiO2‐Aerogel Matrix: Synthesis and Characterization

Irina G. Fomina, Inna O. Gozhikova, Nataliya A. Sipyagina, Elena A. Straumal, Gennady P. Kopitsa, Andrey A. Mazilkin, Andrei A. Eliseev, Nikolay N. Efimov, Yury S. Zavorotny, Alexander V. Shvidchenko, Alexander Y. Vul', Igor L. Eremenko, Sergey A. Lermontov

ChemNanoMat· Volume 10· Issue 11
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Source abstract

Abstract

Abstract A first composite material containing uniformly dispersed disaggregated detonation nanocrystalline diamonds (DNDs) in SiO2 aerogel matrix was prepared. The synthetic protocol included hydrolysis of tetramethyl orthosilicate (Si(OMe)4, TMOS) by hydrosol of surface carboxylated DNDs with a typical size of 4–5 nm with DMSO serving as a cosolvent and a stabilizer of DND single crystals. Composite samples containing DNDs in silica aerogel matrix in concentration 1.0, 0.1 and 0.01 % w/w were prepared at ambient temperature. HRTEM data revealed that DNDs nanocrystals were uniformly distributed in aerogel and did not form aggregates. Textural and optical composites’ properties were determined.
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Research context

NanomaterialsComposites

OpenAlex topics: Diamond and Carbon-based Materials Research · Aerogels and thermal insulation · Laser-Ablation Synthesis of Nanoparticles

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

Affiliations

Kurnakov Institute of General and Inorganic Chemistry of the Russian Academy of Sciences 31 Leninsky prosp. Moscow 119991 Russia

Institute of Physiologically Active Compounds at Federal Research Center of Problems of Chemical Physics and Medicinal Chemistry Russian Academy of Sciences 1 Severnij pr. Chernogolovka 142432 Russia

Institute of Silicate Chemistry of Russian Academy of Sciences 2 Adm. Makarova nab. St. Petersburg 199155 Russia

Petersburg Nuclear Physics Institute named by B.P.Konstantinov of NRC «Kurchatov Institute» 1 Orlova roshcha Gatchina 188300 Russia

Osipyan Institute of Solid-State Physics of the Russian Academy of Sciences 2 Academician Osipyan str. 142432 Chernogolovka Russia

Department of Materials Science Lomonosov Moscow State University 1–73 Leninskiye gory Moscow 119991 Russia

Skobeltsyn Institute of Nuclear Physics Lomonosov Moscow State University 1/2 Leninskie Gory 119991 Moscow Russia

Ioffe Institute 26 Polytechnicheskaya st. 194021 St. Petersburg Russia

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