Enhanced Carbon Capture Behavior of Carbon Fibers via Ionic Liquid Modification

Abstract Carbon‐based materials are widely deployed in carbon capture but are only limited to physisorption procedures. Further extending functionalized carbon materials to CO₂ chemisorption under low CO₂ concentration is highly desirable yet challenging. Herein, a carbon fiber composed of solely ultra‐micropores (∼0.45 nm) was deployed as the precursor to avoid the pore blocking effect, which was modified by superbase‐derived ionic liquids (ILs) containing strong interaction sites with CO₂. By forming a thin coating layer on the surface, the as‐afforded surface‐functionalized fiber materials demonstrated enhanced CO₂ uptake capacity and improved CO₂ sorption kinetics, as evaluated by both the volumetric method and thermogravimetric analysis, as well as the calculated energy distribution curves. The achievements made in this work provide guidance on the functionalization of carbon‐based materials towards enhanced CO₂ chemisorption by forming a thin layer of selected IL coating.