journal article·2015-05

Water Soluble CuInSe2 Nanoplates: Controlled Synthesis, Photoelectric Response and Electrocatalytic Reduction of Polysulfides

Qi Zhu, Wenlong Chen, Fang Dai, Yanping Yuan, Xiangyang Wu, Jiantao Zai, Rongrong Qi, Xuefeng Qian

ChemNanoMat· Volume 1· Issue 1
Publisher page

Abstract

Abstract Hexagonal CuInSe2 (CISe) nanoplates with a size of about 200 nm have been synthesized by a two‐step solvothermal method, in which Sex2− precursor stabilized by HCO(CH3)2NH+ cations (hydrolysis product of the solvent) was prepared from Se powder and vitamin C. Further study indicated that the pre‐reduction process of Se powder could control the concentration of Sex2− ions, which played a key role in the phase formation and morphologies of CISe. Furthermore, poly(vinyl pyrrolidone) was beneficial to form CISe nanoplates and could help CISe nanoplates disperse in ethanol and water to form stable inks. CISe films prepared by drop‐coating showed a good photoelectric response under visible light irradiation and better electrocatalytic activity for the reduction of polysulfides than Pt.
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Research context

OpenAlex topics: Chalcogenide Semiconductor Thin Films · Quantum Dots Synthesis And Properties · Advanced Photocatalysis Techniques

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

Affiliations

Shanghai Electrochemical Energy Devices Research Center School of Chemistry and Chemical Engineering and State Key Laboratory of Metal Matrix Composites Shanghai Jiao Tong University Shanghai 200240 P.R. China

Global Research & Development General Motors Warren MI 48090 USA

Shanghai Key Laboratory of Catalysis of Poly Olefin Shanghai Research Institute of Chemical Industry Shanghai 200062 P.R. China

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