journal article·2018-08Open access

Targetable Mechanical Properties by Switching between Self‐Sorting and Co‐assembly with In Situ Formed Tripodal Ketoenamine Supramolecular Hydrogels

Jamie S. Foster, Andrew W. Prentice, Ross S. Forgan, Martin J. Paterson, Gareth O. Lloyd

ChemNanoMat· Volume 4· Issue 8

Abstract

Abstract A new family of supramolecular hydrogelators are introduced in which self‐sorting and co‐assembly can be utilised in the tuneability of the mechanical properties of the materials, a property closely tied to the nanostructure of the gel network. The in situ reactivity of the components of the gelators allows for system chemistry concepts to be applied to the formation of the gels and shows that molecular properties, and not necessarily the chemical identity, determines some gel properties in these family of gels.
Source: crossref · Quality: baseline

Research context

OpenAlex topics: Supramolecular Self-Assembly in Materials · Photoreceptor and optogenetics research · Polydiacetylene-based materials and applications

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

Affiliations

Institute of Chemical Sciences, School of Engineering and Physical Sciences Heriot-Watt University William Perkin Building Edinburgh Scotland, United Kingdom EH11 4AS

WestCHEM, School of Chemistry University of Glasgow Joseph Black Building, University of Glasgow, University Avenue Glasgow United Kingdom G12 8QQ.

Funding

Royal Society of Edinburgh/Scottish Government Personal Research Fellowship (GOL) · Royal Society University Research Fellowship (RSF)

References (100+)

Show source-provided references
1.
2. 10.1002/1521-4095(200009)12:17<1237::AID-ADMA1237>3.0.CO;2-B10.1002/1521-4095(200009)12:17<1237::AID-ADMA1237>3.0.CO;2-B ↗
3. 10.1039/b417081b10.1039/b417081b ↗
4. 10.1021/ar200195210.1021/ar2001952 ↗
5.
6. 10.1039/C4TC00744A10.1039/C4TC00744A ↗
7. 10.1002/anie.20110676710.1002/anie.201106767 ↗
8.
9. 10.1002/anie.20030164710.1002/anie.200301647 ↗
10. 10.1016/j.jconrel.2007.09.01410.1016/j.jconrel.2007.09.014 ↗
11. 10.1039/C2SM06923G10.1039/C2SM06923G ↗
12.
13. 10.1039/C2CC37428E10.1039/C2CC37428E ↗
14. 10.1002/anie.20035239610.1002/anie.200352396 ↗
15. 10.1021/ja305187610.1021/ja3051876 ↗
16.
17. 10.1021/la901105810.1021/la9011058 ↗
18. 10.1039/c2sm25673h10.1039/c2sm25673h ↗
19.
20. 10.1002/anie.20110358410.1002/anie.201103584 ↗
21. 10.1002/1521-3765(20011015)7:20<4328::AID-CHEM4328>3.0.CO;2-S10.1002/1521-3765(20011015)7:20<4328::AID-CHEM4328>3.0.CO;2-S ↗
22.
23. 10.1039/c2sm25981h10.1039/c2sm25981h ↗
24. 10.1021/ja050809h10.1021/ja050809h ↗
25. 10.1002/anie.20060506710.1002/anie.200605067 ↗
26. 10.1021/la902663z10.1021/la902663z ↗
27.
28. 10.1039/c1sm05827d10.1039/c1sm05827d ↗
29. 10.1021/la204426q10.1021/la204426q ↗
30.
31. 10.1038/nchem.161710.1038/nchem.1617 ↗
32. 10.1073/pnas.050166310210.1073/pnas.0501663102 ↗
33.
34. 10.1002/ejoc.20040072310.1002/ejoc.200400723 ↗
35. 10.1021/cr970028210.1021/cr9700282 ↗
36. 10.1039/B507416A10.1039/B507416A ↗
37.
38. 10.1039/C4CC08626K10.1039/C4CC08626K ↗
39. 10.1039/c1sm05316g10.1039/c1sm05316g ↗
40. 10.1038/ncomms249910.1038/ncomms2499 ↗
41. 10.1002/chem.20130315310.1002/chem.201303153 ↗
42. 10.1002/chem.20130311610.1002/chem.201303116 ↗
43. 10.1039/c3nj00450c10.1039/c3nj00450c ↗
44. 10.1021/la303761710.1021/la3037617 ↗
45. 10.1021/jacs.5b0698810.1021/jacs.5b06988 ↗
46. 10.1021/acs.langmuir.6b0352710.1021/acs.langmuir.6b03527 ↗
47. 10.1021/jacs.5b0969110.1021/jacs.5b09691 ↗
48. 10.1021/la000163110.1021/la0001631 ↗
49. 10.1021/jo061273110.1021/jo0612731 ↗
50. 10.1039/C0CS00105H10.1039/C0CS00105H ↗
51. 10.1021/la102990510.1021/la1029905 ↗
52.
53. 10.1039/C4CS00305E10.1039/C4CS00305E ↗
54. 10.1002/anie.20140883110.1002/anie.201408831 ↗
55. 10.1038/s41565-017-0026-610.1038/s41565-017-0026-6 ↗
56. 10.1038/s41598-017-08644-010.1038/s41598-017-08644-0 ↗
57. 10.1002/chem.20160577110.1002/chem.201605771 ↗
58. 10.1038/nchem.252610.1038/nchem.2526 ↗
59.
60. 10.1038/ncomms800910.1038/ncomms8009 ↗
61. 10.1002/advs.20170055210.1002/advs.201700552 ↗
62. 10.1021/acsnano.7b0229810.1021/acsnano.7b02298 ↗
63. 10.1021/jacs.7b0400610.1021/jacs.7b04006 ↗
64. 10.1038/s41598-017-02524-310.1038/s41598-017-02524-3 ↗
65. 10.1021/acs.langmuir.7b0032610.1021/acs.langmuir.7b00326 ↗
66. 10.1021/jacs.7b0283510.1021/jacs.7b02835 ↗
67. 10.1021/acs.chemmater.6b0313710.1021/acs.chemmater.6b03137 ↗
68. 10.1021/acs.langmuir.5b0438410.1021/acs.langmuir.5b04384 ↗
69. 10.1016/j.actbio.2016.04.03810.1016/j.actbio.2016.04.038 ↗
70. 10.1021/acs.langmuir.5b0322710.1021/acs.langmuir.5b03227 ↗
71. Singh N. · Chem. Sci. · 2016 · 7
72. 10.1021/acs.chemmater.5b0058010.1021/acs.chemmater.5b00580 ↗
73. 10.1002/bip.2243510.1002/bip.22435 ↗
74. 10.1021/bm100047y10.1021/bm100047y ↗
75.
76. 10.1021/ja049596710.1021/ja0495967 ↗
77. 10.1016/j.tetlet.2010.06.12410.1016/j.tetlet.2010.06.124 ↗
78. 10.1021/ol035271410.1021/ol0352714 ↗
79. 10.1039/b901556f10.1039/b901556f ↗
80. 10.1039/b921863g10.1039/b921863g ↗
81. 10.1039/C4NR04039B10.1039/C4NR04039B ↗
82. 10.1021/la102059x10.1021/la102059x ↗
83.
84. 10.1021/la202113j10.1021/la202113j ↗
85. 10.1021/la900653q10.1021/la900653q ↗
86. 10.1021/la301371q10.1021/la301371q ↗
87.
88. 10.1063/1.141560910.1063/1.1415609 ↗
89. 10.1021/ja065720610.1021/ja0657206 ↗
90. 10.1021/ja801804c10.1021/ja801804c ↗
91. 10.1002/1521-4095(20020318)14:6<421::AID-ADMA421>3.0.CO;2-710.1002/1521-4095(20020318)14:6<421::AID-ADMA421>3.0.CO;2-7 ↗
92. 10.1021/ja042654410.1021/ja0426544 ↗
93. 10.1063/1.175038010.1063/1.1750380 ↗
94. 10.1063/1.175063110.1063/1.1750631 ↗
95. 10.1063/1.141560910.1063/1.1415609 ↗
96. 10.1002/andp.20059000810.1002/andp.200590008 ↗
97. 10.1002/andp.20059003110.1002/andp.200590031 ↗
98. 10.1002/anie.20110329710.1002/anie.201103297 ↗
99.
100. 10.1039/C7SC03301J10.1039/C7SC03301J ↗