journal article·2018-09

Platinum Deposited on Carbon Supports for the Complete Detoxification of Formaldehyde at Room Temperature under Humid Conditions

Elke Schade, Florian M. Wisser, Markus Franke, Alexander Weiz, Matthias Werheid, Jan R. Martin, Stefan Kaskel, Julia Grothe

ChemNanoMat· Volume 4· Issue 9
Publisher page

Abstract

Abstract Uniform platinum nanoparticles are deposited on porous carbon supports using a polymeric precursor method. The presented approach has a high potential since hydrophilic and hydrophobic carbon supports are homogeneously impregnated without any preliminary treatment. The platinum nanoparticles on porous carbon composites show a high catalytic activity in the complete detoxification of formaldehyde. Catalysts with platinum loading as low as 0.75 wt.% enable a complete conversion of 700 ppm formaldehyde into carbon dioxide at a relative humidity up to 60% at room temperature. We assign this remarkable catalytic acitivty to a symbiotic effect of the platinum nanoparticles with the carbon support in terms of an oversolubility of formaldehyde in water confined in the pores of the support material.
Source: crossref · Quality: baseline

Research context

OpenAlex topics: Catalytic Processes in Materials Science · Catalysis and Oxidation Reactions · Gas Sensing Nanomaterials and Sensors

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

Affiliations

Inorganic Chemistry I Technische Univeristät Dresden Bergstraße 66 01069 Dresden Germany

Univ. Lyon Université Claude Bernard Lyon 1, C NRS IRCELYON – UMR 5256 2 Avenue Albert Einstein 69626 Villeurbanne Cedex France

Microsystems Technische Universität Dresden Nöthnitzer Straße 64 01187 Dresden, Germany

Inorganic Chemistry II Technische Universität Dresden Bergstraße 66 01069 Dresden Germany

Physical Chemistry Technische Universität Dresden Bergstraße 66 01069 Dresden Germany

References (60)

Show source-provided references
1. 10.1021/es981240610.1021/es9812406 ↗
2. 10.1016/S1352-2310(02)00670-210.1016/S1352-2310(02)00670-2 ↗
3. 10.1021/cr800399g10.1021/cr800399g ↗
4. 10.1039/C7RA06598A10.1039/C7RA06598A ↗
5. 10.1111/j.1600-0668.1995.t01-2-00003.x10.1111/j.1600-0668.1995.t01-2-00003.x ↗
6. 10.1021/es00050a02010.1021/es00050a020 ↗
7. 10.1021/cr300174a10.1021/cr300174a ↗
8. Zendehdel R. · Toxicol. Environ. Chem. · 2017 · 1
9. Lui K.-H. · Environ. Sci. Pollut. Res. Int. · 2017 · 21
10. IARC “IARC classifies formaldehyde as carcinogenic to humans ” can be found under http://www.iarc.fr/en/media-centre/pr/2004/pr153.html 2004.
11. 10.1016/j.jhazmat.2015.07.07810.1016/j.jhazmat.2015.07.078 ↗
12. 10.1016/j.buildenv.2009.07.01910.1016/j.buildenv.2009.07.019 ↗
13. 10.1016/j.cej.2010.11.10610.1016/j.cej.2010.11.106 ↗
14. 10.1016/S1352-2310(00)00465-910.1016/S1352-2310(00)00465-9 ↗
15. 10.1016/j.mspro.2016.03.02510.1016/j.mspro.2016.03.025 ↗
16. 10.1039/C6DT01696K10.1039/C6DT01696K ↗
17. 10.1016/j.microc.2017.01.03210.1016/j.microc.2017.01.032 ↗
18. 10.1016/j.jssc.2017.04.02410.1016/j.jssc.2017.04.024 ↗
19. 10.1016/j.apcatb.2013.05.05610.1016/j.apcatb.2013.05.056 ↗
20. 10.1016/S0009-2509(02)00636-X10.1016/S0009-2509(02)00636-X ↗
21. 10.1016/j.ceramint.2012.06.02710.1016/j.ceramint.2012.06.027 ↗
22. 10.1021/es104146v10.1021/es104146v ↗
23. 10.1016/j.micromeso.2010.09.02210.1016/j.micromeso.2010.09.022 ↗
24. 10.1016/j.apcatb.2013.10.03910.1016/j.apcatb.2013.10.039 ↗
25. 10.1021/jp208947e10.1021/jp208947e ↗
26. 10.1016/j.apsusc.2017.07.09610.1016/j.apsusc.2017.07.096 ↗
27. 10.1021/acs.est.5b0053210.1021/acs.est.5b00532 ↗
28. 10.1016/j.apsusc.2017.02.01010.1016/j.apsusc.2017.02.010 ↗
29. 10.1002/cnma.20140001310.1002/cnma.201400013 ↗
30. 10.1016/j.cej.2012.06.10310.1016/j.cej.2012.06.103 ↗
31. 10.1016/j.apcatb.2007.12.00710.1016/j.apcatb.2007.12.007 ↗
32. 10.1016/j.cej.2006.02.00210.1016/j.cej.2006.02.002 ↗
33. 10.1016/j.catcom.2013.03.00710.1016/j.catcom.2013.03.007 ↗
34. 10.1016/0584-8539(78)80047-610.1016/0584-8539(78)80047-6 ↗
35. 10.1016/j.jcat.2011.03.00310.1016/j.jcat.2011.03.003 ↗
36. 10.1016/j.cattod.2007.06.01010.1016/j.cattod.2007.06.010 ↗
37. 10.1007/s10562-009-9939-510.1007/s10562-009-9939-5 ↗
38. 10.1016/j.catcom.2004.12.01210.1016/j.catcom.2004.12.012 ↗
39. 10.1039/C6RA02569B10.1039/C6RA02569B ↗
40. 10.1006/jcat.2002.363710.1006/jcat.2002.3637 ↗
41. S. D. E. Lecea H. Yamashita K. Words-metal-support 1995 33 3–13.10.1016/0008-6223(94)00096-I ↗
42. 10.1016/j.carbon.2003.09.02210.1016/j.carbon.2003.09.022 ↗
43. 10.1007/s10853-006-0936-410.1007/s10853-006-0936-4 ↗
44. 10.1016/j.matlet.2005.12.05010.1016/j.matlet.2005.12.050 ↗
45. 10.1016/j.jpowsour.2005.10.00210.1016/j.jpowsour.2005.10.002 ↗
46. Pechini M. P. · Ceramic Dielectric Materials · 1967 · 1090361
47. 10.1039/c3tc00826f10.1039/c3tc00826f ↗
48. 10.1039/c2tc00247g10.1039/c2tc00247g ↗
49. 10.1038/srep2798210.1038/srep27982 ↗
50. 10.1016/j.jhazmat.2010.12.01810.1016/j.jhazmat.2010.12.018 ↗
51. Motyl E. · Fibres Text. East. Eur. · 2006 · 14 · 39
52. 10.4209/aaqr.2013.02.005710.4209/aaqr.2013.02.0057 ↗
53. 10.1016/j.carbon.2017.08.02410.1016/j.carbon.2017.08.024 ↗
54. 10.1039/C6CY00062B10.1039/C6CY00062B ↗
55. 10.1016/S1872-2067(15)61007-510.1016/S1872-2067(15)61007-5 ↗
56. Moulder J. F. · 1992
57. 10.1021/jp108670310.1021/jp1086703 ↗
58. G. National Institute of Standards and Technology “NIST X-ray Photoelectron Spectroscopy Database Version 4.1 ” can be found under http://srdata.nist.gov/xps/ 2012.
59. 10.1021/acs.est.5b0208510.1021/acs.est.5b02085 ↗
60. 10.1039/C4NJ00076E10.1039/C4NJ00076E ↗