Intimate Interfacial Interaction between Amino‐Modified Ti5 Clusters and BiVO4 towards Efficient Photoelectrochemical Water Splitting
Source abstract
Abstract
Abstract In this work, a novel series of amino‐modified Ti5 clusters (NH2‐TOCs) with a Janus surface were synthesized. Then, a facile hydrolysis self‐assembly strategy was adopted to fabricate a well‐defined monolayer of NH2‐TOCs on BiVO4 with intimate interaction at low temperature. The as‐formed NH2‐TOCs/BiVO4 heterojunction electrode exhibited high performance on photoelectrochemical water‐splitting, which was ascribed to strong M−O−Ti (M=Bi, V) bonding at the interface. It is anticipated that this work could boost new insights for cluster‐support interaction and corresponding applications.
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Research context
OpenAlex topics: Advanced Photocatalysis Techniques · Quantum Dots Synthesis And Properties · Nanocluster Synthesis and Applications
SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.
Affiliations
State Key Laboratory for Physical Chemistry of Solid Surfaces Collaborative Innovation Center of Chemistry for Energy Materials Engineering Research Center for Nano-Preparation Technology of Fujian Province College of Chemistry and Chemical Engineering Pen-Tung Sah Institute of Micro-Nano Science and Technology Xiamen University Xiamen 361005 China
Funding
National Natural Science Foundation of China
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