DataVXChemNanoMatPaper
journal article·2019-01

Orthogonal Molecular Recognition of Chaotropic and Hydrophobic Guests Enables Supramolecular Architectures

Wenjing Wang, Xiaoqiang Wang, Changjun Xiang, Xiaohai Zhou, Detlef Gabel, Werner M. Nau, Khaleel I. Assaf, Haibo Zhang

ChemNanoMat· Volume 5· Issue 1
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Source abstract

Abstract

Abstract The hydrophobic and chaotropic effects can be used as orthogonal assembly motifs in water. Cucurbit[7]uril, a water‐soluble macrocyclic host, and a ditopic guest molecule, carrying an organic‐hydrophobic (adamantane) and an inorganic‐chaotropic (dodecahydro‐closo‐dodecaborate dianion) binding site, have been used to construct hybrid supramolecular architectures. The hydrophobic effect drives the adamantane moiety into the host cavity, while the chaotropic effect allows the association of the dodecaborate cluster onto the host exterior surface. This new strategy facilitates potential applications in surface modification, separation, and purification.
Source: crossref · Quality: baseline

Research context

OpenAlex topics: Supramolecular Chemistry and Complexes · Crystallography and molecular interactions · Boron Compounds in Chemistry

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

Affiliations

School of Chemistry and Chemical Engineering Wuhan University of Science and Technology Wuhan 430081 China

College of Chemistry and Molecular Sciences Wuhan University Wuhan 430072 China

Engineering Research Center of Organosilicon Compounds & Materials Ministry of Education Wuhan University Wuhan 430072 China

Department of Life Sciences and Chemistry Jacobs University Bremen Campus Ring 1 28759 Bremen Germany

Department of Chemistry, Faculty of Science Al-Balqa Applied University P.O. Box 19117 Al-Salt Jordan

National Demonstration Center for Experimental Chemistry Wuhan University Wuhan 430072 China

Funding

Fundamental Research Funds for the Central Universities · Wuhan University Experiment Technology Project Funding

References (44)

Show source-provided references
1.
2. 10.1126/science.120596210.1126/science.1205962 ↗
3. 10.1126/science.285.5430.104910.1126/science.285.5430.1049 ↗
4. 10.1021/acs.chemrev.5b0036910.1021/acs.chemrev.5b00369 ↗
5. 10.1039/b703092b10.1039/b703092b ↗
6. 10.1039/B616752G10.1039/B616752G ↗
7.
8. 10.1021/acs.chemrev.5b0034110.1021/acs.chemrev.5b00341 ↗
9. 10.1039/C4CS00327F10.1039/C4CS00327F ↗
10. 10.1021/ar500055s10.1021/ar500055s ↗
11. 10.1039/C3MH00057E10.1039/C3MH00057E ↗
12. 10.1002/chem.20130163510.1002/chem.201301635 ↗
13.
14. 10.1002/ange.20131095810.1002/ange.201310958 ↗
15. 10.1002/anie.20131095810.1002/anie.201310958 ↗
16. 10.1002/ange.1993105110310.1002/ange.19931051103 ↗
17. 10.1002/anie.19931545110.1002/anie.199315451 ↗
18. 10.1002/ange.1991103110410.1002/ange.19911031104 ↗
19. 10.1002/anie.19911417110.1002/anie.199114171 ↗
20.
21. Assaf K. I. · Angew. Chem. · 2018 · 10
22. Angew. Chem. Int. Ed. · 2018 · 10
23. 10.1039/C6OB01161F10.1039/C6OB01161F ↗
24. 10.1039/C7CC01507K10.1039/C7CC01507K ↗
25. 10.1021/acs.orglett.5b0361110.1021/acs.orglett.5b03611 ↗
26. 10.1002/ange.20141248510.1002/ange.201412485 ↗
27. 10.1002/anie.20141248510.1002/anie.201412485 ↗
28. 10.1039/C7CC08078F10.1039/C7CC08078F ↗
29. 10.1021/jacs.7b0731710.1021/jacs.7b07317 ↗
30. 10.1021/ja01497a06910.1021/ja01497a069 ↗
31. 10.1039/C7CP01074E10.1039/C7CP01074E ↗
32.
33. 10.1002/chem.20170339210.1002/chem.201703392 ↗
34. 10.1039/c2ob06915f10.1039/c2ob06915f ↗
35. Nekvinda J. · Chem. Eur. J. · 2018 · 10
36. 10.1039/C4CS00273C10.1039/C4CS00273C ↗
37.
38. 10.1021/ja807751b10.1021/ja807751b ↗
39. 10.1039/C6CC02613C10.1039/C6CC02613C ↗
40. 10.1021/acs.jpcb.7b0917510.1021/acs.jpcb.7b09175 ↗
41. 10.1021/ja055013x10.1021/ja055013x ↗
42. 10.1002/ange.20130963510.1002/ange.201309635 ↗
43. 10.1002/anie.20130963510.1002/anie.201309635 ↗
44. 10.1016/0021-9797(68)90272-510.1016/0021-9797(68)90272-5 ↗