journal article·2018-01Open access

Copper Nanoparticles on Controlled Pore Glass and TEMPO for the Aerobic Oxidation of Alcohols

Ismail Ibrahem, Muhammad Naeem Iqbal, Oscar Verho, Alireza Eivazihollagh, Peter Olsén, Håkan Edlund, Cheuk‐Wai Tai, Magnus Norgren, Eric V. Johnston

ChemNanoMat· Volume 4· Issue 1

Abstract

Abstract Herein, we report on the facile synthesis of a heterogeneous copper nanocatalyst and its combination with 2,2,6,6‐tetramethyl‐1‐piperidinyloxy (TEMPO) for the aerobic oxidation of alcohols to their corresponding carbonyl compounds. This low cost copper nanocatalyst was found to exhibit excellent recyclability, making it a highly attractive catalytic system from an economical and environmental point of view. Extensive characterization of the catalyst by a number of techniques revealed that it was comprised of well‐dispersed Cu(I/II) nanoparticles with an average size of around 6 nm.
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Research context

OpenAlex topics: Oxidative Organic Chemistry Reactions · Catalytic Processes in Materials Science · Mesoporous Materials and Catalysis

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

Affiliations

FSCN, Surface and Colloid Engineering Mid Sweden University SE-851 70 Sundsvall Sweden

Department of Organic Chemistry, Arrhenius Laboratory Stockholm University SE-106 91 Stockholm Sweden

Department of Materials and Environmental Chemistry, Arrhenius Laboratory Stockholm University SE-106 91 Stockholm Sweden

Sigrid Therapeutics Universitetsvägen 8 (Villa Bellona) SE-106 91 Stockholm Sweden

Funding

Swedish Foundation for Strategic Research

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