journal article·2023-05

Preparation and Properties of Pyrotechnic Binder Encapsulated α‐AlH3 Composites by Solvent/Anti‐solvent Method

Zhe Shi, Taojie Lu, Yinghui Hu, Yidong Xu, Xuwen Wang, Zhuo Wu, Jian Zheng, Jian Zhang, Zhaoyang Zhu, Kaifeng Lin, Yulin Yang

ChemNanoMat· Volume 9· Issue 5
Publisher page

Abstract

Abstract Alpha‐aluminum hydride (α‐AlH3) is an ideal energetic combustion agent, but its poor stability and safety limit its application. Therefore, we prepare different composites by using the solvent/anti‐solvent method to coat different pyrotechnic binders on the surface of α‐AlH3. The vacuum stability test show that the minimum outgassing of Shellac‐coated α‐AlH3 composite is only 1.2 mL/g at 50 °C for 6 days. Due to the good electrical insulation properties of Viton, Viton‐coated α‐AlH3 composite have the highest E50 value of electrostatic sensitivity. In addition, the pyrotechnic binders coating not only protects the activity of the α‐AlH3 but also effectively increases its burning rate. Viton‐coated α‐AlH3 composite have more gaseous products and maximum flame area during combustion. This study illustrates that α‐AlH3 coated with pyrotechnic binders is a means to address its stability and safety, laying the foundation for its application in solid propellants.
Source: crossref · Quality: baseline

Research context

OpenAlex topics: Energetic Materials and Combustion · Combustion and Detonation Processes · Rocket and propulsion systems research

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

Affiliations

MIIT Key Laboratory of Critical Materials Technology for New Energy Conversion and Storage School of Chemistry and Chemical Engineering Harbin Institute of Technology Harbin 150001 P. R. China

Science and Technology on Aerospace Chemical Power Laboratory Hubei Institute of Aerospace Chemotechnology Xiangyang 441003 Hubei P. R. China

China Aerospace Science and Technology Corporation 16 Fucheng Road, Haidian District Beijing 100048 P. R. China

Funding

National Natural Science Foundation of China · China Postdoctoral Science Foundation

References (45)

Show source-provided references
1. 10.1134/S001050822005001910.1134/S0010508220050019 ↗
2. 10.1016/j.cej.2018.06.05110.1016/j.cej.2018.06.051 ↗
3. 10.1002/prep.20160002110.1002/prep.201600021 ↗
4. 10.1002/prep.20210027910.1002/prep.202100279 ↗
5. 10.1016/j.cej.2020.12420910.1016/j.cej.2020.124209 ↗
6. 10.1016/j.jallcom.2010.11.11510.1016/j.jallcom.2010.11.115 ↗
7. 10.1016/j.jechem.2020.02.00810.1016/j.jechem.2020.02.008 ↗
8. 10.3390/ma1411289810.3390/ma14112898 ↗
9. 10.1016/j.vacuum.2013.05.00910.1016/j.vacuum.2013.05.009 ↗
10. 10.2514/1.2292010.2514/1.22920 ↗
11. 10.1016/j.ast.2006.08.01010.1016/j.ast.2006.08.010 ↗
12. 10.1002/prep.20180038010.1002/prep.201800380 ↗
13. 10.1016/j.jallcom.2010.11.11010.1016/j.jallcom.2010.11.110 ↗
14. 10.1016/j.cej.2021.12975310.1016/j.cej.2021.129753 ↗
15. 10.1002/prep.20190000310.1002/prep.201900003 ↗
16. 10.1002/adma.20200129110.1002/adma.202001291 ↗
17. 10.1016/j.matdes.2020.10866610.1016/j.matdes.2020.108666 ↗
18. 10.1016/j.apsusc.2021.15144810.1016/j.apsusc.2021.151448 ↗
19. 10.1016/j.dt.2020.12.00510.1016/j.dt.2020.12.005 ↗
20. 10.1038/s41598-022-16424-810.1038/s41598-022-16424-8 ↗
21. 10.1016/j.fuel.2022.12574110.1016/j.fuel.2022.125741 ↗
22. 10.1116/1.498266110.1116/1.4982661 ↗
23. 10.1016/j.jallcom.2021.16350410.1016/j.jallcom.2021.163504 ↗
24. 10.1080/07370652.2016.118625210.1080/07370652.2016.1186252 ↗
25. 10.1016/j.cej.2019.12298710.1016/j.cej.2019.122987 ↗
26. 10.1038/s41598-022-12949-010.1038/s41598-022-12949-0 ↗
27. 10.1080/0737065080240526510.1080/07370650802405265 ↗
28. 10.1007/s10973-022-11370-z10.1007/s10973-022-11370-z ↗
29. 10.1016/j.cej.2021.13447810.1016/j.cej.2021.134478 ↗
30. 10.1023/A:102503471907010.1023/A:1025034719070 ↗
31. Test Method of Loading Material for Initiating Explosive Device-Part 27: Electrostatic Spark Sensitivity Test GJB5891.27-2006 Military Standardization of P. R. China Beijing P. R. China 2007.
32. 10.1016/j.jiec.2020.07.02810.1016/j.jiec.2020.07.028 ↗
33. Zhu Z. · Russ. J. Phys. Chem. A · 2020 · 93 · 2798
34. 10.1016/j.jallcom.2006.11.20510.1016/j.jallcom.2006.11.205 ↗
35. 10.1039/D1NJ05582H10.1039/D1NJ05582H ↗
36. 10.1016/j.ejps.2011.01.00610.1016/j.ejps.2011.01.006 ↗
37. 10.1021/acsnano.2c0527110.1021/acsnano.2c05271 ↗
38. 10.1016/j.tca.2005.08.02910.1016/j.tca.2005.08.029 ↗
39. 10.1134/S003602441507025010.1134/S0036024415070250 ↗
40. 10.1016/j.fuel.2022.12588310.1016/j.fuel.2022.125883 ↗
41. 10.1016/j.actaastro.2020.11.03910.1016/j.actaastro.2020.11.039 ↗
42. 10.1016/j.combustflame.2020.07.00610.1016/j.combustflame.2020.07.006 ↗
43. 10.1002/prep.20170007410.1002/prep.201700074 ↗
44. 10.1016/j.jhazmat.2009.03.11710.1016/j.jhazmat.2009.03.117 ↗
45. 10.1002/prep.20150007010.1002/prep.201500070 ↗