journal article·2024-03Open access

Gold Microstructures by Thermolysis of Gold(III) Di‐isopropyldithiocarbamate Complexes

A. Angeloski, K. Flower‐Donaldson, F. Matar, D. C. Hayes, M. N. Duman, D. T. Oldfield, M. T. Westerhausen, A. M. McDonagh

ChemNanoMat· Volume 10· Issue 3

Abstract

Abstract Elemental gold was formed by thermolysis of gold(III) dithiocarbamate single‐source precursors, which exist as two complexes. The complexes were readily synthesised from the reaction between chloroauric acid and sodium di‐isopropyldithiocarbamate and could be isolated from each other. The thermal decomposition processes were evaluated using thermogravimetry and electrical resistance measurements. The structure and purity of the resultant gold was examined using scanning electron microscopy. The resultant gold materials were drastically different and dependent on the thermolysed complex.
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Research context

OpenAlex topics: Chemical Thermodynamics and Molecular Structure · Thermal and Kinetic Analysis · Organometallic Compounds Synthesis and Characterization

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

Affiliations

National Deuteration Facility Australian Nuclear Science Technology Organisation Sydney NSW Australia

School of Mathematical and Physical Sciences University of Technology Sydney NSW Australia

Minerals Australian Nuclear Science Technology Organisation Sydney NSW Australia

Nuclear Materials Development and Characterisation Australian Nuclear Science Technology Organisation Sydney NSW Australia

Hyphenated Mass Spectrometry Laboratory University of Technology Sydney NSW Australia

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