journal article·2018-06

Molecular Arrangements of Corannulene and Sumanene in Single‐Walled Carbon Nanotubes

Yoko Iizumi, Zheng Liu, Kazu Suenaga, Susumu Okada, Shuhei Higashibayashi, Hidehiro Sakurai, Toshiya Okazaki

ChemNanoMat· Volume 4· Issue 6
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Abstract

Abstract Molecular arrangements of bowl‐shaped molecules, corannulene and sumanene, in single‐walled carbon nanotubes (SWCNTs) were investigated using high‐resolution transmission microscopy and near‐infrared photoluminescence spectroscopy. The results indicated that corannulenes are nested in SWCNTs with a random orientation, whereas sumanenes form stacked structures. The trends are consistent with the molecular orientations of corannulene and sumanene in single crystals.
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Research context

OpenAlex topics: Carbon Nanotubes in Composites · Fullerene Chemistry and Applications · Graphene research and applications

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

Affiliations

Department of Chemistry University of Tsukuba Tsukuba 305-8577 Japan

CNT-Application Research Centre National Institute of Advanced Industrial Science and Technology (AIST) Tsukuba 305-8565 Japan

Inorganic Function Materials Research Institute, AIST Nagoya 463-8560 Japan

Nanomaterials Research Institute, AIST Tsukuba 305-8565 Japan

Institute of Physics and Centre for Computational Sciences University of Tsukuba 1-1-1 Tennodai Tsukuba 305-8577 Japan

CREST, Japan Science and Technology Agency (JST) 4-1-8 Honcho Kawaguchi 332-0012 Japan

Faculty of Pharmacy Keio University 1-5-30 Shibakoen, Minato-ku Tokyo 105-8512 Japan

Department of Applied Chemistry, Graduate School of Engineering Osaka University 2-1 Yamada-oka Suita 565-0871 Japan

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