journal article·2017-04

Confining for Stability: Heterogeneous Catalysis with Transition Metal (Oxide) Nanoparticles Confined in the Secondary Pore Network of Mesoporous Scaffolds

Carmen Ciotonea, Irina Mazilu, Brindusa Dragoi, Cezar Catrinescu, Emil Dumitriu, Adrian Ungureanu, Houshang Alamdari, Sabine Petit, Sébastien Royer

ChemNanoMat· Volume 3· Issue 4
Publisher page

Abstract

Abstract A melt infiltration strategy allows the encapsulation of transition metal (oxide) nanoparticles in the intra‐wall pores of SBA‐15 supports, providing ultrafine particles that are stable at high temperatures (up to 900 °C, oxidizing–reducing atmospheres). Selective localization of transition metal (oxide) precursor in the secondary pores is achieved in the presence of organic structure‐directing agent occluded in the intra‐wall pores, and by applying an intermediate diffusion step during preparation.
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Research context

OpenAlex topics: Mesoporous Materials and Catalysis · Catalytic Processes in Materials Science · Catalysis and Hydrodesulfurization Studies

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

Affiliations

CNRS UMR 7285 CNRS Université de Poitiers 6 Rue Michel Brunet—TSA 51106 86073 Poitiers Cedex 9 France

Faculty of Chemical Engineering and Environmental Protection “Gheorghe Asachi” Technical University of Iasi 73 D. Mangeron Bvd. 700050 Iasi Romania

Univ. Lille, CNRS, Centrale Lille, ENSCL, Univ. Artois, UMR 8181 UCCS—Unité de Catalyse et de Chimie du Solide F-59000 Lille France

Department of Mining, Metallurgical and Materials Engineering Laval University Québec (Québec) G1V 0A6 Canada

Funding

Ministère des Affaires Étrangères

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