Nitrogen‐doped Binary Spinel CuCo₂O₄/C Nanocomposite: An Efficient Electrocatalyst for Oxygen Evolution Reaction

Abstract The oxygen evolution reaction (OER) on the anode side is one of the bottlenecks for electrochemical water splitting, and the search for cost‐effective and efficient catalysts for OER is highly pursued. Herein, through calcination and nitridation treatment of the Cu−Co based bimetallic metal‐organic framework precursor, nitrogen doped CuCo₂O₄/nitrogen‐doped carbon (N−CuCo₂O₄@N−C) are successfully synthesized. X‐ray photoelectron spectroscopy measurements reveal the evident change of electronic state after doping N atoms into CuCo₂O₄@N−C. When used as an OER electrocatalyst, N−CuCo₂O₄@N−C catalysts offer an overpotential of only 260 mV to reach 10 mA cm⁻², which is comparable to commercial RuO₂ catalyst. The N−CuCo₂O₄@N−C sample possesses a lower Tafel slope than pristine CuCo₂O₄@N−C sample. Moreover, a chronoamperometric study reveals that N−CuCo₂O₄@N−C displays excellent stability for at least 28 h. This work provides a promising heteroatom doping strategy to fabricate high‐performance OER electrocatalysts for water splitting.