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journal article·2022-08Open access

N‐Substituted Carbazole Derivate Salts as Stable Organic Electrodes for Anion Insertion

Roberto Russo, Rajesh Murugesan, Arash Jamali, Jean‐Noël Chotard, Gwenaelle Toussaint, Christine Frayret, Philippe Stevens, Matthieu Becuwe

ChemNanoMat· Volume 8· Issue 8
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Abstract

Abstract Herein the design, synthesis and electrochemical characterization of a set of insoluble molecular carbazole derivatives for electrochemical energy storage is proposed. Two strategies, based on the incorporation of an insoluble fragment or dimerization, were carried out to avoid the dissolution of the active material in the organic carbonate‐based liquid electrolyte solvent. The synthesized compounds enable the reversible anion intercalation from electrolyte, around 4.0 V vs. Li, through a p‐type mechanism, and showed an improvement in cycling stability, making them suitable for application as metal‐free positive electrodes for electrochemical energy storage systems. A first investigation to determine the impact of the electrolyte composition on the anion insertion mechanism and complemented with understanding of the redox mechanism was also carried out.
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Research context

Energy storage

OpenAlex topics: Advanced Battery Materials and Technologies · Conducting polymers and applications · Advanced battery technologies research

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

Affiliations

Laboratoire de Réactivité et Chimie des Solides (LRCS), UMR CNRS 7374 Université de Picardie Jules Verne 15 rue Baudelocque 80000 Amiens France

Department Electric Equipment Laboratory (LME) EDF R&D Avenue des Renardières 77818 Morêt-sur-Loing Cedex France

Réseau sur le Stockage Electrochimique de l'Energie (RS2E) FR CNRS 3459 Amien France

Institut de Chimie de Picardie (ICP), FR CNRS 3085, 80039 Amiens France

Plateforme de Microscopie Électronique (PME) de l'Université de Picardie Jules Verne Hub de l'Énergie 15 rue Baudelocque 80000 Amiens France

Funding

Association Nationale de la Recherche et de la Technologie

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