Carbazole‐Based Molecular Glasses as Hole‐Transporting Materials in Solid State Dye‐Sensitized Solar Cells
Source abstract
Abstract
Abstract Three 3,6‐di(4‐methoxyphenyl)amino N‐alkylated carbazoles were synthesized, characterized and incorporated in solid state dye‐sensitized solar cells. Devices using these compounds as solid hole conductors showed relative high Voc thanks to good energy level matching between them and D102 dye. However, they yield relatively low Jsc and FF compared to spiro‐OMeTAD‐based control devices, which is due to an order of magnitude lower mobility and conductivity with respect to spiro‐OMeTAD. Maximum PCEs for N‐ethyl and N‐hexyl 3,6‐di(4‐methoxyphenyl)amino carbazoles (2 a, 2 b) are 1.6 %, and 1.8 % respectively, whereas spiro‐OMeTAD devices gave 4.4 %. Stability tests in air under continuous illumination have been reported.
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Research context
OpenAlex topics: TiO2 Photocatalysis and Solar Cells · Organic Electronics and Photovoltaics · Perovskite Materials and Applications
SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.
Affiliations
Laboratoire de Physicochimie des Polymères et des Interfaces Université de Cergy-Pontoise 5 Gay Lussac 95000 Neuville-sur-Oise France
Univ. Bordeaux IMS, UMR 5218 33607 Pessac France
CNRS IMS, UMR 5218 33607 Pessac France
Department of Physics Abdul Wali Khan University Mardan Khyber Pakhtunkhwa 23200 Pakistan
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