journal article·2023-04-01Open access

Tuning the temperature range of superelastic Ni-Ti alloys for elastocaloric cooling via thermal processing

Takahiro Yamazaki, Andre L Montagnoli, Marcus L Young, Ichiro Takeuchi

Journal of Physics: Energy· Volume 5· Issue 2

Abstract

Abstract Caloric cooling enlisting solid-state refrigerants is potentially a promising eco-friendly alternative to conventional cooling based on vapor compression. The most common refrigerant materials for elastocaloric cooling to date are Ni-Ti based superelastic shape memory alloys. Here, we have explored tuning the operation temperature range of Ni50.8Ti49.2 for elastocaloric cooling. In particular, we have studied the effect of thermal treatments (a.k.a. aging) on the transformation temperature, superelasticity, and elastocaloric effects of Ni50.8Ti49.2 shape memory alloy tubes. The isothermal compressive test revealed that the residual strain of thermally-treated Ni-Ti tubes at room temperature approaches zero as aging time is increased. Short-time aging treatment at 400 °C resulted in good superelasticity and elastocaloric cooling performance with a large tunable austenite finish (A f) temperature range of 24.7 °C, as determined from the A f temperature of the samples that were aged 5–120 min. The main reason of the property change is the formation of a different amount of Ni4Ti3 precipitates in the NiTi matrix. Our findings show that it is possible to tailor the A f temperature range for development of cascade elastocaloric cooling systems by thermally treating a starting single composition Ni-Ti alloy.
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Research context

OpenAlex topics: Shape Memory Alloy Transformations · Titanium Alloys Microstructure and Properties · Magnetic and transport properties of perovskites and related materials

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

References (36)

Show source-provided references
1. From the elastocaloric effect towards an efficient thermodynamic cycle10.1088/2515-7655/ac92a5 ↗
2. Future prospects for elastocaloric devices10.1088/2515-7655/ab1573 ↗
3. Materials, physics and systems for multicaloric cooling10.1038/s41578-022-00428-x ↗
4. Elastocaloric heat pump with specific cooling power of 20.9 W g–1 exploiting snap-through instability and strain-induced crystallization10.1038/s41560-020-00770-w ↗
5. Experimental investigation of a staggered-tube active elastocaloric regenerator10.1016/j.ijrefrig.2022.09.006 ↗
6. Thermo-hydraulic evaluation of oscillating-flow shell-and-tube-like regenerators for (elasto) caloric cooling10.1016/j.applthermaleng.2021.116842 ↗
7. On the effect of alloy composition on martensite start temperatures and latent heats in Ni–Ti-based shape memory alloys10.1016/j.actamat.2015.02.029 ↗
8. Physical metallurgy of Ti-Ni-based shape memory alloys10.1016/j.pmatsci.2004.10.001 ↗
9. Influence of Ni on martensitic phase transformations in NiTi shape memory alloys10.1016/j.actamat.2010.02.019 ↗
10. High temperature shape memory alloys10.1179/095066010X12646898728363 ↗
11. Shape memory alloy actuator design: CASMART collaborative best practices and case studies10.1007/s10999-013-9227-9 ↗
12. Pseudoelasticity and shape memory effects in alloys10.1179/imtr.1986.31.1.93 ↗
13. Elastocaloric cooling processes: the influence of material strain and strain rate on efficiency and temperature span10.1063/1.4953433 ↗
14. Superelastic behavior of aged and thermomechanical treated NiTi alloy at Af+ 10 C10.1016/j.matdes.2010.06.022 ↗
15. Magnetocaloric energy conversion: from theory to applications10.1016/j.cmpb.2015.07.008 ↗
16. Precipitation processes in near-equiatomic TiNi shape memory alloys10.1007/BF02650086 ↗
17. Effect of annealing on strain-temperature response under constant tensile stress in cold-worked NiTi thin wire10.1155/2011/160927 ↗
18. The effect of low temperature aging and the evolution of R-phase in Ni-rich NiTi10.1007/s40830-018-0193-9 ↗
19. R-phase transformation in heterogeneous nanocrystalline Ni-rich TiNi alloy10.1063/5.0034951 ↗
20. Effect of ageing temperatures on pseudoelasticity of Ni-rich NiTi shape memory alloy10.1063/1.5034539 ↗
21. Effect of annealing on the transformation behavior and superelasticity of NiTi shape memory alloy10.1016/S1359-6462(01)01005-3 ↗
22. The effect of annealing and cold-drawing on the super-elasticity of the Ni-Ti shape memory alloy wire10.5539/mas.v4n12p109 ↗
23. Microstructural effect on the thermomechanical behavior of aged Ni-rich NiTi SMA10.1088/2053-1591/ab4d78 ↗
24. On the influence of the heat treatment temperature on the superelastic compressive behavior of the Ni-rich NiTi shape memory alloy10.1007/s11665-017-2974-2 ↗
25. Influence of annealing treatment on microstructure and properties of Ni-Rich NiTi alloy coating prepared by laser cladding10.3390/ma15093298 ↗
26. Adjustment of aging temperature for reaching superelasticity in highly Ni-rich Ti-51.5 Ni NiTi shape memory alloy10.1080/10426914.2015.1048468 ↗
27. Phase volume fractions and strain measurements in an ultrafine-grained NiTi shape-memory alloy during tensile loading10.1016/j.actamat.2009.12.021 ↗
28. Effect of Fe addition on microstructure and mechanical properties of as-cast Ti49Ni51 alloy10.3390/ma12193114 ↗
29. Review on phase transformation behavior of NiTi shape memory alloys10.1016/j.matpr.2018.03.051 ↗
30. The nature of reversible change in Ms temperatures of Ti-Ni alloys with alternating aging10.2320/matertrans1989.40.1367 ↗
31. Elastocaloric effect in heterophase TiNi single crystals10.1007/s40830-022-00388-9 ↗
32. Effect of disperse Ti3N4 particles on the martensitic transformations in titanium nickelide single crystals10.1134/S0031918X08120065 ↗
33. Demonstration of high efficiency elastocaloric cooling with large ΔT using NiTi wires10.1063/1.4746257 ↗
34. Large tunable elastocaloric effect in additively manufactured Ni–Ti shape memory alloys10.1016/j.actamat.2020.04.007 ↗
35. Elementary martensitic transformation processes in Ni-rich NiTi single crystals with Ni4Ti3 precipitates10.1016/j.actamat.2006.03.036 ↗
36. In-Situ TEM observations of martensitic transformations in Ni‐rich NiTi single crystals with coherent and aligned precipitates