Solvothermal Synthesis and Characterization of a New 3-D Open Framework Aluminophosphate [Al2P3O12][C4N3H16]
Source abstract
Abstract
A new 3-D open framework aluminophosphate [Al2P3O12][C4N3H16] has been solvothermally synthesized from phenol medium using diethylenetriamine as a template. Its structure contains parallel 12- and 8-membered channels along the [001] direction.
Only a short abstract or summary was supplied by the source.
Source: openalex_inverted_index · Quality: short
Research context
OpenAlex topics: Metal-Organic Frameworks: Synthesis and Applications · Zeolite Catalysis and Synthesis · Chemical Synthesis and Characterization
SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.
Affiliations
Key Laboratory of Inorganic Synthesis and Preparative Chemistry, Department of Chemistry, Jilin University, Changchun 130023, P. R. China, and Department of Physics and CREST (JST), Tohoku University, Sendai 980-8578, Japan
References (32)
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31. A single crystal of the AlPO-DETA with dimensions of 0.2 × 0.1 × 0.06 mm3was glued to a fine glass fiber and mounted on the three-circle fixed Siemens diffractometer fitted with a Bruker SMART CCD detector. Cell dimensions and intensity data were collected on a Bruker SMART system using graphite monochromatic Mo Kα radiation generated by a rotating anode X-ray tube (λ = 0.71073 Å) at 298 K. The lattice constant was determined by the least-squares procedure applied to the θ values for 25 reflections (2.37−23.20 °). [Intensity data of 1531 independent reflections (−18 ≤h≤ 16, −8≤k≤ 9, −4 ≤l≤ 11) were collected in the ω scan mode, among which 969 [R(int) = 0.02861] reflections meet the conditionI> 2σ(Iobs).] Measured intensity data were corrected for Lorentz and polarization effects together with an absorption correction by means of a φ and ω scan algorithm. The structure was solved by directed methods and refined using a least-squares program package (SHELXL-97; Sheldrick, University of Göttingen, Germany, 1997). During the isotropic refinement for framework atoms and non-hydrogen atoms of the diethylene triamine molecule, the protonation of the DETA molecule is suggested so as to achieve the charge balance of the present compound. All H atoms are geometrically placed. AlPO-DETA: Al2P3O12·C4N3H16, Mr = 446.08,Z= 4,Dc= 1.970 Mg/m3,F(000) = 916. The refinement converged to give a finalR= 2.86% forI> 2σ(Iobs) and ωR2 = 8.14%.
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