journal article·2016-01-21

Chiral Analysis Using Broadband Rotational Spectroscopy

V. Alvin Shubert, David Schmitz, Cristóbal Pérez, Chris Medcraft, Anna Krin, Sérgio R. Domingos, David Patterson, Melanie Schnell

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Abstract

broadband microwave spectroscopy is a proven tool to precisely determine molecular properties of gas-phase molecules. Recent developments make it applicable to investigate chiral molecules. Enantiomers can be differentiated, and the enantiomeric excess and, indirectly, the absolute configuration can be determined in a molecule-selective manner. The resonant character and high resolution of rotational spectroscopy provide a unique mixture compatibility. Future directions, such as extending the technique to chemical analysis, are discussed.
Source: openalex_inverted_index · Quality: baseline

Research context

OpenAlex topics: Molecular Spectroscopy and Structure · Advanced Chemical Physics Studies · Spectroscopy and Laser Applications

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

Affiliations

Max-Planck-Institut für Struktur und Dynamik der Materie, Luruper Chaussee 149, D-22761 Hamburg, Germany

Center for Free-Electron Laser Science, Luruper Chaussee 149, D-22761 Hamburg, Germany

The Hamburg Centre for Ultrafast Imaging, Universität Hamburg, Luruper Chaussee 149, D-22761 Hamburg, Germany

Department of Physics, Harvard University, Cambridge, Massachusetts 02138, United States

Funding

Deutsche Forschungsgemeinschaft · Verband der Chemischen Industrie

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