journal article·1997-12-01

Titanium Dioxide−Surfactant Mesophases and Ti-TMS1

R. L. Putnam, N. Nakagawa, K. M. McGrath, N. Yao, I. A. Aksay, S. M. Gruner, A. Navrotsky

Chemistry of Materials· Volume 9· Issue 12
Publisher page

Abstract

Several attempted syntheses of Ti-TMS1, a hexagonal mesoporous TiO2 reported by Antonelli and Ying, have resulted in a lamellar structure as determined by two-dimensional powder X-ray diffraction and transmission electron microscopy (TEM). Regions of partially calcined lamellar materials, when observed by TEM can be mistaken for hexagonal material. In no cases are specimens produced that were unambiguously hexagonal. It is concluded that the hexagonal material exists, if at all, only as a minor component of a larger lamellar structure when phosphate surfactants are used. Ti-TMS1 therefore remains elusive.
Source: openalex_inverted_index · Quality: baseline

Research context

OpenAlex topics: Mesoporous Materials and Catalysis · Polyoxometalates: Synthesis and Applications · Zeolite Catalysis and Synthesis

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

Affiliations

Departments of Geosciences, Chemical Engineering, and Physics, and Princeton Materials Institute Princeton University Princeton, New Jersey 08544-5263

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