journal article·2025-07-22

Superconducting Vacancy-Ordered Rock-Salt NbO Films

Jeong Rae Kim, Sandra Glotzer, Evan Krysko, Matthew R. Barone, Jinkwon Kim, Salva Salmani-Rezaie, Adrian Llanos, Joseph Falson

Chemistry of Materials· Volume 37· Issue 14
Publisher page

Abstract

We report molecular beam epitaxy synthesis of vacancy-ordered rock-salt NbO thin films that display superconductivity. The unique lattice structure and Nb 2+ oxidation state trigger structural and chemical instabilities in the epitaxial growth process. A comparative study of substrates identifies Al 2 O 3 (0001) as the optimal platform for realizing high-quality, single-phase films when growing at temperatures exceeding 1000 °C. The controlled NbO films exhibit superconductivity with critical temperatures up to T c = 1.37 K, comparable to bulk single crystals. This work addresses the fundamental bottlenecks encountered in the high-temperature epitaxy of transition-metal suboxide compounds while expanding the scope of available thin-film superconductors.
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Research context

OpenAlex topics: Physics of Superconductivity and Magnetism · Magnetic and transport properties of perovskites and related materials · Advanced Condensed Matter Physics

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

Affiliations

Department of Applied Physics and Materials Science

California Institute of Technology

Institute for Quantum Information and Matter

Department of Materials Science and Engineering

Cornell University

Platform for the Accelerated Realization, Analysis, and Discovery of Interface Materials (PARADIM)

The Ohio State University

Funding

Gordon and Betty Moore Foundation · Division of Materials Research · Division of Physics

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